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Refinement of the Structure of p-Dimethylaminobenzaldehyde 4-(p-Ethoxyphenyl) Thiosemicarbazone (p-Dimethylaminobenzaldehyde 4-(p-Ethoxyphenyl) Thiosemicarbazone구조의 정밀화)

  • Seo, Il-Hwan;Seo, Chu-Myeong;Park, Yeong-Ja
    • Korean Journal of Crystallography
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    • v.2 no.1
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    • pp.12-16
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    • 1991
  • C18H22N4OS, Mr=342.47, monoclinic, P2₁/c,a=11.802(2), b=31.962(2), c=9.829(2)A, β=100.12(1)˚, V=3694.8A3,F(000)=1472, Z=8, Dx=1.246 Mg m-3, Dm=1.17Mg m-3,λ=0.71073 A, μ=0.15mm-1, T=294 K. final R=0.0856 for 3718 observed reflection (Fo>3σ(Fo)) There are two molecules in an asymmetric unit and a major difference between these molecules is in the C(9)-N(1)-C(6)-C(7) torsion angles [58.8(8)˚and 1(1)˚]. Both molecules have intramolecular N(1)-H(10)'N(3) hydrogen bonds [ 2.613(7) and 2.566(7) A] and assume V-shaped conformation with N(2) atoms at the verices. The two independent molecules are linked by the two N(2)-H(11)'S' hydrogen bonds[3.367(5) A and 3.421(4)A] and the dimergen are held together by van der Waals forces.

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Toxic Effects and Distribution of Mercury in Barley Seedlings (보리 유식물에 처리한 수은의 분포 및 독성 연구)

  • 이춘환;장호식
    • Journal of Environmental Science International
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    • v.1 no.1
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    • pp.13-21
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    • 1992
  • The inhibitory effects of mercury ions on the growth of barley seedlings were studied and the distribution of metal elements in the organs of treated plants was investigated by using synchrotron radiation induced X-ray emission (SRIXE). Although the treatment of mercury ions caused growth inhibition, the mercury-specific increase in variable fluorescence and the abolishment of energy-dependent quenching in broken barley chloroplasts as shown by Moon et at. (1992) were not observed in the leaves of growth-inhibited seedlings. Instead the treatment of mercury decreased Fmax and Fo values. However, Fmax/Fo ratio and photochemical and nonphotochemical quenching coefficients were not affected significantly. By SRIXE analysis of $10\mu\textrm{m}$ mercury chloride treated seedlings, accumulation of mercury in roots was observed after 1 hour of treatment and similar concentration was sustained for 48 hours. Relative contents of mercury was high in roots and underground nodes where seeds were attachedl but was very low in leaves. Iron and zinc were also distributed mainly in the lower parts of the seedlings. However after 72 hours of treatment the contents of these metals in roots decreased and their distribution became more uniform, which may lead to death of the plants. These results suggest that the observed inhibitory effects on barley seedlings upto 48 hours after the treatment is not due to direct damages in the photosynthetic apparatus, but due to its accumulation in roots and the consequent retardation of the growth of barley seedlings. The decrease in Fmax and Fo is probably due to the decrease in chlorophyll and protein contents caused by the retardation of growth. The observed slow expansion of primary leaves could be also explained by the retardation of growth, but the fluorescence induction pattern from the leaves did not show characteristic symptoms of leaves under water stress.

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Growth Responses of South Korea Three Evergreen Woody Species according to Indoor Light Intensity Conditions (실내 광량조건에 따른 자생 상록 목본 3종의 생육반응)

  • Jang, Bo Kook;Lee, Cheol Hee;Oh, Chan-Jin;Cho, Ju Sung
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2019.10a
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    • pp.56-56
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    • 2019
  • 본 연구에서는 자생 상록 목본 3종의 실내도입을 위하여 몇 가지 광량조건에서의 식물생육 및 광화학 반응을 조사하였다. 식물재료는 황칠나무[Dendropanax trifidus (Thunb.) Makino ex H. Hara], 먼나무(Ilex rotunda Thunb.), 편백[Chamaecyparis obtusa (Siebold & Zucc.) Endl.]의 2년생 실생묘를 유리온실에 재배하면서 실험에 사용하였다. 실내에 조사되는 광환경을 측정하여 광량 10, 50, 100 및 200 PPFD(${\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$)를 처리구로 설정하였다. 실내환경은 광주기(12/12 h), 온도($25{\pm}1^{\circ}C$) 및 습도($55{\pm}3%$)를 유지하였으며, 1회/3일 간격으로 관수하였다. 유리온실에서 동일기간 동안 재배중인 식물을 대조구로 사용하였으며, 실험은 8주간 수행되었다. 황칠나무와 먼나무는 200 PPFD의 높은 광량에서 초장, 줄기직경, 엽장, 엽수 등의 생육수치가 우수하였다. 반면 두 종 모두 10 PPFD 광량에서는 재배기간 중 잎이 말라가는 현상이 관찰되었으며 8주차에 모든 식물체가 고사하였다. 이는 10 PPFD 광량에서 재배된 황칠나무와 먼나무의 광화학반응에서도 Fv/Fm (-0.10, -0.08) 및 Fm/Fo (0.91, 0.93)가 낮은 수치로 조사된 반응과 일치하였다. 한편 편백나무는 모든 광량조건에서 대조구에 비해 초장 및 줄기직경 등의 생육이 우수하였으나, 10 PPFD의 낮은 광량에서는 Fv/Fm (0.16) 및 Fm/Fo (1.60)가 타 처리구에 비해 낮은 수치로 조사되었다.

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Study on the Sexing of Mouse Embryos by Chromosomal Analysis (염색체 분석에 의한 생쥐초기부의 성 판별에 관한 연구)

  • 신현동;김정익
    • Korean Journal of Animal Reproduction
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    • v.10 no.1
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    • pp.27-35
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    • 1986
  • As a preliminary experiment to establish the process on the sexing of mouse embryos by chromosomal analysis, present studies were carried out with inbred (ICR, C57BL) and F1 hybrid [(ICR${\times}$C57BL) = F1 ${\times}$ ICR] mice to investigate the blastomere numbers and mitotic indices (M.I.) to the developmental stage of embryos recovered, the optimum periods of anti-mitotic agent administration, the successful rates of sexing and sex-ratio. The results obtained were summarized as follows: 1. The blastomere numbers (mean${\pm}$S.E.) of the morula and blastocyst were 18${\pm}$0.4 and 54${\pm}$0.7, respectively. 2. Whereas the M.I. of F1 hybrid (16${\pm}$0.2%) was higher than that fo inbred ICR (15${\pm}$0.1%) and C57BL (12${\pm}$0.6%) in the different strains, the morula (7${\pm}$0.6%) was higher than that of blastocyst (6${\pm}$0.4%) in the case of embryo stages. 3. Following to anti-mitotic agents treated, the M.I. of embryos cultured with Colcemid (17${\pm}$1.1%) was superior to that fo embryos cultured with Velban (12${\pm}$0.9%) and the Colcemid injection (7${\pm}$0.4%). 4. The successful rate of sexing in the blastocyst (38.7%; 124/320) was superior to the morula (35.9%; 52/145), and the F1 hybrid (48.1%) was higher than that of inbred ICR (42.4%) and C57 BL (28.2%). 5. In the successful rate of sexing to the methods of administration, the embryos cultured with Colcemid (46.0%) was superior to that of embryos cultured with Velban (39.0%) and the Colcemid injection (38.8%). 6. Of 98 embryos sexed after culture with Colcemid, 89(90.8%) were observed between 2 and 4 hrs. In the case of Velban treatment, 83.1% (74/89) was observed between 2$\frac{1}{2}$ and 4$\frac{1}{2}$ hrs. 7. Out of 761 prepared embryos it was possible to sex 311; 157 were male and 154 were female, i.e.a sex-ratio of 50% a, pp.oximately.

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Effect of Irrigation Starting Point of Soil on Chlorophyll Fluorescence, Stem Sap Flux Relative Rate and Leaf Temperature of Cucumber in Greenhouse (시설 토양 오이재배에서 관수개시점 처리가 광합성 형광반응, 줄기수액흐름 및 엽온에 미치는 영향)

  • An, Jin Hee;Jeon, Sang Ho;Choi, Eun Yong;Kang, Ho Min;Na, Jong Kuk;Choi, Ki Young
    • Journal of Bio-Environment Control
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    • v.30 no.1
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    • pp.46-55
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    • 2021
  • This experiment was conducted to investigate the effect on chlorophyll fluorescence, stem sap flux relative rate (SFRR) and leaf temperature of cucumber when irrigation is controlled using a soil moisture tensiometer. Cucumber (Cucumis sativus L.) 'Chungchun' was irrigated of 10-10-20 kPa and 20-10-10 kPa by soil starting point of irrigation at each growth stage. At the 66 days after treatment (DAT) of 736 to 854 W·m-2 and above 32℃, chlorophyll fluorescence variables (Fo, Fm, Fv/Fm) values showed significantly different between treatments. The Fo and Fv/Fm value in the daytime (10:30 am to 6:00 pm) at 66 DAT was higher in 20-10-10 kPa treatment than in 10-10-20 kPa treatment. The Fv/Fm value decreased when the leaf temperature was increased. There was no difference in leaf growth (length, width and area) at 28 and 66 DAT, but the chlorophyll content (SPAD value) was significantly higher in 20-10-10kPa treatment. SFRR and leaf temperature increased with light intensity and temperature increased. In both treatments, the SFRR started to increase sharply between 8 am and 9 am when the solar radiation is 170 W·m-2 or higher. The soil temperature of the treatments decreased after irrigation, that showed 31.0℃ at 10-10-20kPa and 28.5℃ at 20-10-10kPa on July 5 (820W·m-2 at 1 pm). However, there was no difference in SFRR, leaf temperature, temperature difference (leaf temperature - air temperature) and VPD between treatments. SFRR was significantly positive correlate with the leaf temperature (p < 0.01, r = 0.770). The SFRR and leaf temperature showed positive significant correlation with solar radiation, temperature, soil temperature, soil moisture content and VPD. There was a negative significant correlation with relative humidity and temperature difference.

CHLOROPHYLL FLUORESCENCE IN CUCUMBER (Cucumis safivus L.) AND PEA (Pisum sativum L.) LEAVES UNDER CHILLING STRESS IN THE LIGHT AND DURING THE SUBSEQUENT RECOVERY PERIOD

  • Ha, Suk-Bong;Eu, Young-Jae;Lee, Choon-Hwan
    • Journal of Photoscience
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    • v.3 no.1
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    • pp.15-21
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    • 1996
  • To investigate the chilling sensitivity related injuries in the photosynthetic apparatus of cucumber leaves, the light-chilling induced alterations of chlorophyll fluorescence transients in cucumber leaves were compared with those in pea leaves. As an early effect of light-chilling, an increase in Fp/Fm$^*$ was observed in both pea and cucumber leaves, which was saturated by about 6 h chilling. However, the saturated value of Fp/Fm was almost 1.0 in cucumber, in contrast to about 0.8 in pea. During the recovery period after 24 h chilling, the light-chilling induced changes in pea seemed to be reversed, but those in cucumber leaves were thought to be irreversible, because Fo was increased significantly. Light-chilling caused significant decreases in qQ and qE in cucumber leaves, but qR was increased until 6 h, and decreased thereafter. In both pea and cucumber leaves, Fm was increased by 2 h dark treatment. The Fm from the predarkened pea leaf discs was higher than the value from the preilluminated ones during the whole period of light-chilling (500 $\mu$mol m$^{-2}$s$^{-1}$ PAR). However, the predarkened cucumber leaf discs showed a reduction in Fm and an increase in Fo during the 2 h chilling in the light. These results indicate that the causes of chilling sensitivities in photosynthetic apparatus of cucumber leaves are possibly related with the damage in PSI reaction center and the ability of acidification of lumen by PSII.

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Comparison of Voice Characteristics Before and After High-Caffeine Intake (고카페인 섭취 전·후 음성 특성 비교)

  • Lee, Areum;Kim, Eunyun;Yoo, Hyunji;Choi, Yaelin
    • Phonetics and Speech Sciences
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    • v.7 no.4
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    • pp.59-65
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    • 2015
  • This study was conducted to identify the differences in voice characteristic variables before and after taking a certain amount of high-caffeine. Linear PCM-M10 Recorder (SONY) was used for the recorder and basic frequency of the voice (Fo), frequency fluctuation rate (jitter), amplitude fluctuation rate (shimmer) and Signal-to-Noise Ratio (SNR) were measured using TF-32(University of Wisconsin-Madison, USA). First, prolonged phonation analysis results of /ah/ by male subjects showed the shimmer values after taking high-caffeine increased statistically significantly(p<.05) compared with before the intake and SNR values significantly decreased. (p<.05). On the other hand, female subjects didn't show any statistically significant differences in all variables. Second, male subjects showed statistically significant increased shimmer values after the intake compared with before the intake at /ah/ of syllable 'na' and /ah/ in 'ra' in 'autumn' paragraph (p<.05), and jitter values significantly increased at /ah/ in 'ah' (p<.05). However, female subjects didn't show any statistically significant differences in all variables. Results of this study showed that high-caffeine intake more affects male subjects than female subjects. In male subjects, shimmer and SNR changed at vowel prolonged phonation, /ah/, and study results showed that shimmer and SNR in 'Autumn' paragraph /na/, /ra/ and jitter in /ah/ could be identified as the variables to show the voice change.

NUMERICAL FLOW VISUALIZATION ANALYSIS AROUND AN OSCILLATING SQUARE CYLINDER (정사각봉의 진동에 의한 유동해석)

  • Ju, M.K.;Ajith Kumar, R.;Sohn, C.H.;Gowda, R.H.L.
    • 한국전산유체공학회:학술대회논문집
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    • 2007.10a
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    • pp.115-119
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    • 2007
  • In this paper, a flow visualization analysis has been carried out on an oscillating square section cylinder, numerically, using a commercially available code CFD-ACE. In this study, the square cylinder is forced to oscillate at different frequencies of excitation, viz., fe/fo=0.5, 1.0 and 2.0 (where, fe is the excitation frequency provided to the cylinder and fo is the natural vortex shedding frequency from the stationary cylinder at a particular Reynolds number (=5200). In all the cases, the peak-to-peak amplitude of oscillation is kept at 32% of the side dimension of the square cylinder. These studies are conducted to understand the influence of frequency of oscillation on the flow field features around the cylinder, particularly the mode of vortex shedding. Results indicate that, the flow field around a square cylinder is very much influenced by the excitation frequency, in particular the vortex shedding mode. It is also found that, the vortex street parameters are significantly influence by the oscillation frequency. Comparison with earlier reported experimental studies has also been attempted in this paper. In appears that, such a numerical exercise (as performed in this paper) is first of its kind. It is believed that, these studies would enable one to understand the mechanisms underlying the flow-induced vibrations of a square section cylinder.

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Mechanical Properties and Microstructures of Alumina Composites Reinforced with SiC Whiskers and TiC Particles (SiC 휘스커 및 TiC 입자 강화 알루미나 복합재료의 기계적 성질과 미세조직)

  • 이영규;김준규;조원승;최상욱
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.792-798
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    • 2000
  • Alumina composites reinforced with SiC whiskers only or combinded with TiC particles were prepared by hot-pressing at 1850$^{\circ}C$ for 1h. The mechanical properties and microstructures of composites were investigated in this study. By of addition either 20 vol% SiC whiskers or 20 vol% TiC particles, the flexural strength fo alumina was increased from 360 MPa to 650 MPa or 730 MPa, respectively, and the KIC was also increased from 3.5 MPa$.$m1/2 to 5.5MPa$.$m1/2 or 4.4MPa$.$m1/2, respectively. In the case of composites with 20 vol% SiC whiskers and 2 vol% TiC particles. The flexural strength and KIC showed relatively high value of 800 MPa and 5.3MPa$.$m1/2, respectively. The improvement of mechanical properties was considered to be due to both the smaller average grain size and the crack deflection.

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Electrical Property of Polyvinylalcohol (Polyvinylalcohol의 전기적 특성)

  • 김현철;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.156-159
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    • 1994
  • The electrical property of polyvinylalcohol (PVA) films (several hundreds ∼ several $\mu\textrm{m}$ in thickness) formed by sphere bulb blowing technique, has been studied. The electrical conductivity of relatively thick films (>several thousands ) has been very high and enhanced by the exposure either to high humidity fo air or NH$_3$. which can be explained in terms of the role of ionic transport. The use of PVA film as NH$_3$ sensor is also proposed. In PVA films less than 1500 , two conducting states: high conducting and low conducting states, are observed.