• Title/Summary/Keyword: Fly Ash

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Degradation of Cement Mortar with Supplementary Cementitious Materials Submerged in Various Oils (각종 유지류에 침지된 혼화재 치환 시멘트 모르타르의 열화특성)

  • Han, Cheon-Goo;Hwang, Chan-Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.2
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    • pp.137-143
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    • 2017
  • There has been a number of research on concrete durability. specially, as a research on chemical ingression, the research on the degradation against acid, alkali, and sulfate has been conducted. On the other hand, for the research on oils, especially, the influence of various oils on cement mortar with Supplementary Cementitious Materials(SCMs) is not sufficiently studied. hence, in this research, the degradation of cement mortar incorporated fly ash and blast furnace slag is researched when the cement mortar is submerged in various oils. For the result of experiment, as the content of fatty acid in the oils, the degradation of cement mortar with SCMs was occurred more, and the cement mortar with SCMs suffered more degradation than the ordinary portland cement regarding the oil submerging.

Coal gasification and A new IGCC system (석탄가스화와 새로운 IGCC 시스템)

  • Kim, Hyun-Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.361-363
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    • 2008
  • 탄소 개질반응은 $1200^{\circ}C$(도1) 이상에서 모든 탄화물질과 수분 또는 $CO_2$ 사이에서 흡열/환원반응이 일어나서 합성가스를 생성한다. 개질반응로는 산화반응로와 연결되어, 수소가스와 CO 가스의 혼합인,합성가스가 산화반응로 내에서 산소가스와 연소하여 열과 $H_2O+CO_2$를 생성하여 환원 반응로 내로 유입되어, 환원 반응로를 $1200^{\circ}C$ 이상으로 유지하고, $H_2O$$CO_2$는 석탄 속의 모든 탄소를 CO로 개질한다(도2). 동시에 수소가스가 생성되어 합성가스를 생성하게 된다. 석탄 속의 비탄소 물질인 슬래그(Slag)는 개질로 내에 남게 되는데, 개질로를 슬래그 융점(non-fluid point) 이하에서 고체상태로 포집함으로서 Fly-ash로 처리된다. 개질로 내의 온도를 $1200{\sim}1300^{\circ}C$(석탄 슬래그 융점)로 유지함으로서 개질반응이 지속되어 합성가스가 생성된다. IGCC 시스템에서는 합성가스를 가스터빈 속에서 $O_2E가스와 연소하여 고온의 가스를 생성하여 터빈을 가동해 발전을 하고 배출가스를 $1500{\sim}1700^{\circ}C$에서 배출한다. 재래식 IGCC(도4)에서는 ${\sim}1500^{\circ}C$의 배출가스를 열교환 시스템에 의해 증기를 생성하여 Steam turbine(증기터빈)을 가동하여 추가 전력을 생산했다. 그러나 본 시스템에서는 배출가스(증기와 $CO_2E 가스)를 위의 개질로에 유입하여 개질로 온도를 $1200{\sim}1300^{\circ}C$로 유지함으로서 더 많은 합성가스를 생성 하게 된다(도3). 이렇게 하여 Oxidation-reduction cycle을 형성하게 된다. 새로운 IGCC 시스템에서 가스 터빈의 배출가스가 석탄 개질로에 연결되고 석탄개질로의 합성가스 출구가 가스터빈의 가스 입구에 연결됨으로서,외부에너지 주입 없이 지속 가능한 가스화 반응과 터빈 사이클(Cycle)을 완성하여 IGCC 시스템의 석탄 열효율을 1단계 상승시켰다. 이렇게 설계된 석탄가스화기는 Lurgi형 석탄가스화 기와 달리 석탄개질반응의 효율을 높일 수 있고, 슬래그 처리가 간단하기 때문에 석탄가스화기가 소형화 될 수 있으며 슬래그(Slag)용융에 따른 석탄가스화기의 외벽손상을 피할 수 있다.

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The Study on the Comparison of the ISCST3 Model and Receptor Model by Dispersion Tracing of Particulate Matter from Large Scale Pollution Sources (대단위배출원에서 기인한 입자상오염물질의 확산ㆍ추적을 통한 ISCST3모델과 수용모델의 비교연구)

  • 전상기;이성철;박경선
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.789-803
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    • 2003
  • The purpose of this study is to compare the usefulness between Gaussian dispersion model and receptor model with the experimental result of the dispersion tracing of the particulate pollutants from Taean coal-fired power plants. For this purpose, the component analysis of the collected PM 10 samples was performed. In order to trace the pollution sources, factor analysis was done with the result of the component analysis. As a result of the correlativity analysis of the fifteen power plants' profiles offered by US EPA, the correlativity of No.11202 source profile showed highest rate up to 84.5%. Thus it was adopted as proper one and the contribution rate by each pollution source was calculated by Chemical Mass Balance (CMB)-8 model. The contribution rate, which was the effect rate of the power plants on each measuring point, were calculated with a range of 24∼52% and the standard error was below 0.9 $\mu\textrm{g}$/㎥. This indicates the selection of the source profile was appropriate. Also, the concentrations of each point were calculated by the ISCST3 which is suggested by US EPA as one of the regulatory Gaussian dispersion model. The calculation result showed that the predicted concentration was 50∼58 $\mu\textrm{g}$/㎥, comparing with the measured result of 9∼65 $\mu\textrm{g}$/㎥. It was found that the concentration calculated by ISCST3 was underpredicted. It was thought that the receptor model was more favorable than the Gaussian dispersion model in estimating the effect of the particulate matter on a certain receptive point.

Analysis of Correlation between Compressive Strength, Void Ratio and Chloride Diffusion Coefficient of Concrete Using Various Kinds of Cement (시멘트의 종류별 콘크리트외 강도 및 공극률과 염화물 확산계수의 상관관계 분석)

  • Yoon Eui-Sik;Lee Taek-Woo;Park Seung-Bum
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.735-742
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    • 2005
  • The purpose of this study was to evaluate the salt water resistance of concrete depending on various types of cement. In this regard, 5 types of concrete were selected and their strength, void ratio and chloride ion diffusion characteristics were tested, and mutual correlation were analyzed. From the test results, the compressive strength and void ratio of concrete which using Type V cement was as good as Type I cement at long-term ages but the chloride diffusion coefficient of Type V cement was larger than Type I cement. And the concrete replacing some portion of the Type I cement with fly ash was superior in the cases of compressive strength, void ratio and the resistance of chloride ion permeation compared to the Type I cement with the lapse of ages. On the other hand, the compressive strength, the void ratio and the chloride diffusion coefficient of the concrete all indicated high levels of the correlation coefficient and the coefficient of determination regardless of the type of cement.

Utilization of Scheelite Mine Tailing as Raw Material of Ordinary Portland Cement (보통포틀랜드시멘트 원료로서 회중석 광미의 활용)

  • 김형석;정수복;김완태;안지환;채영배
    • Resources Recycling
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    • v.13 no.3
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    • pp.19-26
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    • 2004
  • In order to use the mine tailing which was generated in the flotation process of scheelite ore into the raw material of ordinary portland cement, the characteristics of the prepared cement clinker was investigated. Scheelite mine tailing is composed of 68.8% of $SiO_2$, 8.6% of $Al_2$$O_3$, 10.8% of $Fe_2$$O_3$, 5.0% of CaO, respectively. It exists as $\alpha$-quartz, muscovite, clinochlore and has 8.0% of 88 $\mu\textrm{m}$ residue. When LSF, SM, and IM of the raw materials (such as limestone, convertor slag, fly ash, and mine tailing) are 91.0, 2.60, and 1.60, respectively, the burnability index of the raw materials is 50.7, the crystal size of $C_3$S and $\beta$-C$_2$S in the prepared clinker is 15∼35$\mu\textrm{m}$, and about 3.8% of scheelite mine tailing can be used as raw material.

Study on the Effect of SBR Latex on the Properties of Soil Pavement (SBR Latex를 이용한 흙 포장의 재료특성 연구)

  • Lee, Sang Yum;Hwang, Sung Do;Yang, Sung Lin
    • International Journal of Highway Engineering
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    • v.16 no.5
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    • pp.73-82
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    • 2014
  • PURPOSES : The purpose of this study is to determine the optimum addition rate of SBR latex through the evaluation of durability and strength of SBR latex applied soil pavement. Formerly used materials such as fly ash and cement in soil pavement had resulted in decreased durability due to micro crack by heat of hydration and shrinkage crack in winter. However, that agglutinated polymers help adhesion to aggregate increased comes up with preventing the crack opening when the number of capillary tubes of SBR latex get decreased in the hydration process of cement. Therefore, in this study, it is suggested that the evaluation of the field applicability of soil pavement be conducted through the performance lab test in terms of strength increment, adhesion improvement, and crack resistance based on SBR latex addition rate. METHODS : In order to evaluate the field applicability of soil pavement, SBR latex was added 0 to 3% by 1% increment, with fixed cement contents of 3% and 5%. The resistance of shear failure and crack of soil pavement were evaluated by performing the uniaxial compressive strength test and indirect tensile strength test at -20 and $20^{\circ}C$, respectively. RESULTSCONCLUSIONS : It was found out that from both tests, resistance of shear failure and crack were improved with increment of curing time, and especially more than 2% of SBR latex addition rate and 5% cement content gave better results.

Enhancement of the Strength of MgO-Based Binder by Accelerated Carbonation (촉진탄산염화에 의한 마그네슘계 고화제의 강도 향상 특성)

  • Yun, Do Youn;Ahn, Jun-Young;Kim, Cheolyong;Kim, Tae Yoo;Hwang, Inseong
    • Journal of Soil and Groundwater Environment
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    • v.21 no.6
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    • pp.135-145
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    • 2016
  • MgO recently has been regarded as the alternative material for replacement of cement. The aim of this study is to investigate the effects of accelerated carbonation on the strength development of MgO-based binder which is binary mixtures of magnesium oxide (MgO) with portland cement (PC) or ground granulated blast furnace slag (GGBS) or fly ash (FA). The compressive strengths of all binders were higher in the 20% $CO_2$ condition and for longer curing time. The strength were generally higher as the following order: MgO/PC > MgO/GGBS > MgO/FA system. The binder composed of 20% MgO and 80% PC showed highest compressive strength (38.0MPa) which was higher than PC. The correlation analysis of the porosity and compressive strength showed that compressive strength was higher when porosity was lower. The hydration and carbonation products of MgO including brucite ($Ca(OH)_2$), magnesite ($MgCO_3$) and nesquehonite ($MgCO_3{\cdot}3H_2O$) presumably filled the pores and contributed to strength development. Thermogravimetric analyses elucidated that 0.34 kg of $CO_2$ could be stored the 50% MgO/50% PC binder which performed the maximum $CO_2$ uptake at 20% $CO_2$ condition.

Resistance to Freezing and Thawing of Concrete Subjected to Carbonation (탄산화를 받은 콘크리트의 동결융해 저항성)

  • Lee, Seung-Tae;Park, Kwang-Pil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.623-631
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    • 2018
  • In this study, the degree of deterioration of concrete was investigated in the laboratory under conditions of carbonation and freeze-thaw cycling, which are the major causes of the deterioration of its performance. In this test, the carbonated concrete was subjected to combined freeze-thaw deterioration tests for up to 300 cycles, and its dynamic elastic modulus and compressive strength were measured. The evaluation of the effect of the water-binder ratio on normal concrete subjected to combined carbonization and freezing-thawing showed that its resistibility against such combined deterioration decreased more rapidly in the concrete with a water-binder ratio of 55 % compared with that having a water-binder ratio of 35 %. In the case where the concrete was blended with a mineral admixture consisting of fly ash and blast furnace slag at the same water-binder ratio, it showed an increase of its resistibility against combined deterioration.

Applications of Artificial Neural Networks for Using High Performance Concrete (고성능 콘크리트의 활용을 위한 신경망의 적용)

  • Yang, Seung-Il;Yoon, Young-Soo;Lee, Seung-Hoon;Kim, Gyu-Dong
    • Journal of the Korean Society of Hazard Mitigation
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    • v.3 no.4 s.11
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    • pp.119-129
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    • 2003
  • Concrete and steel are essential structural materials in the construction. But, concrete, different from steel, consists of many materials and is affected by many factors such as properties of materials, site environmental situations, and skill of constructors. Concrete have two kinds of properties, immediately knowing properties such as slump, air contents and time dependent one like strength. Therefore, concrete mixes depend on experiences of experts. However, at point of time using High Performance Concrete, new method is wanted because of more ingredients like mineral and chemical admixtures and lack of data. Artificial Neural Networks(ANN) are a mimic models of human brain to solve a complex nonlinear problem. They are powerful pattern recognizers and classifiers, also their computing abilities have been proven in the fields of prediction, estimation and pattern recognition. Here, among them, the back propagation network and radial basis function network ate used. Compositions of high-performance concrete mixes are eight components(water, cement, fine aggregate, coarse aggregate, fly ash, silica fume, superplasticizer and air-entrainer). Compressive strength, slump, and air contents are measured. The results show that neural networks are proper tools to minimize the uncertainties of the design of concrete mixtures.

Development of Technologies for Intermediate Stuff from Waste Agricultural Plastic Film (농업용 폐비닐로부터 중간원료의 경제적인 제조기술 개발)

  • Shon, Sang-Jin;Kim, Hae-Tae;Kim, Myoung-Ho;Kim, Hyung-Kuk;Ahn, Tae-Kwang;Zhou, Gong-Ming;Chen, De-Zhen
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.97-106
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    • 2005
  • 현재 우리나라에서만 연간 약 26만들이 발생되고 있는 농업용 폐비닐은 재생원료로 재활용되어지면 국내외에서 그 용도가 매우 많으나 멀칭용으로 사용되었던 폐비닐은 그 오염도가 워낙 심하여 쉽게 재활용할 수 없는 처지이다. 즉 공급과 수요는 많으나 재생기술의 한계가 병목으로 작용하고 있는 현실이다. 따라서 간단하고 경제적인 방법으로 재활용할 수 있는 습식 및 건식 재생기술의 개발이 계속되어 요구되어 왔다. 강제 세척, 회전분리, 열풍 건조 및 압착성형을 이용한 새로운 간이습식공정을 통하여 멀칭용 농업용 폐비닐을 순도 95% 이상의 탄화 및 열화가 적은 압착 펠렛을 경제적으로 제조할 수 있었다. 이들의 재생 수지는 인장강도 $168.6{\pm}3.9kgf/cm^2$, 파단신을 315.8%, 인장탄성을 $2,551.8{\pm}50.1kgf/cm^2$, 굴곡강도와 굴곡탄성을 $166.7{\pm}7.4kgf/cm^2,\;5,716.2{\pm}242.2kgf/cm^2$ 그리고 충격강도는 $49.2kgf\;cm/cm$을 각각 보여 연질수지로써 기능하기 위한 충분한 성능을 보유하고 있음을 알 수 있었다. 또한 이들의 응용분야 확대를 위하여 fly ash 및 탄산칼슘을 배합하여 이들의 물성변화를 살폈다.

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