• Title/Summary/Keyword: Fluorocomplexes

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Synthesis and Characterization of Two New Fluoroplumbate(II) Complexes: Tetrabutylammonium Fluorodihaloplumbate, (But)4N[PbX2F] (X = Cl, I)

  • Javanshir, Zahra;Mehrani, Kheyrollah;Ghammamy, Shahriare;Saghatforoush, LotfAli;Seyedsadjadi, Seyedabolfazl;Hassanijoshaghani, Ali;Tavakol, Hossein
    • Bulletin of the Korean Chemical Society
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    • v.29 no.8
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    • pp.1464-1466
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    • 2008
  • Tetrabutylammonium Fluorodichloroplumbate(II), N$(C_4H_9)_4$[$PbCl_2F$], TBAFDiCP and Tetrabutylammonium Fluorodiiodoplumbate(II), [$(C_4H_9)_4$N][$PbI_2F$], TBAFDiIP are the first examples of fluoroplumbate salts that have been prepared from the reaction of $(C_4H_9)_4$NF with $PbCl_2$ and $PbI_2$ respectively using either $CH_3CN$ solvent. These new compound characterized by elemental analysis, IR, UV/Visible, $^1H$ NMR, and $^{19}F$ NMR techniques.