• Journal of Soil and Groundwater Environment
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• v.23 no.4
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• pp.42-47
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• 2018

E. coli TG1 pBS TOM Green was cultured to produce toluene-o-monooxygenase (TOM). A biosensor system was successfully constructed using purified TOM to effectively detect trichloroethene (TCE) and tetrachloroethene (PCE), which represent some of the major contaminants in groundwater and soil. In order to utilize TOM as a sensor, NADH, a biological oxidizer, was replaced with hydrogen peroxide which is a chemical oxidizing agent. A three-layered sandwich-type sensing tip was fabricated on the outside of the hydrophilic polyvinylidene fluoride membrane. TCE and PCE were applied to the sensor and the hydrogen ions were measured by a fiber optic fluorometer using fluoresceinamine. Calibration curves were obtained for TCE and PCE in the concentration range of 0.2-100 mg/l, and the detection limit of the system was $10{\mu}g/l$ for TCE and PCE.

• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4244-4246
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• 2011

A simple chromogenic system based on 1-fluoride was developed to determine water content in organic solvent. This system utilized deprotonation and protonation of the anion receptor 1. The water content evaluated from this system gave close value to the real water content in the range of 0 to 0.35% in acetonitrile and 0.2 to 0.5% in DMSO. Therefore, protonation and deprotonation phenomenon from the anion receptor by basic anion could be promising method for water sensing system.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.175-175
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• 2006

Considering the number of chemosensors that have been developed for the sensing of metal ions, only a few chemosensors for fluoride anion have been described in the literature that are based on fluorescent or chromogenic responses. We performed colorimetric anion sensing based on the binding of anion analytes with hydrogen donor group in polymer backbone resulting in naked-eye color change and fluorescent quenching. Our challenges using hydrogen donor moiety was designed effectively are continuing in order for high selectivity and sensitivity for ultimate applications such as fluid solution sensing in biomolecules and gas vapor sensing.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.277.2-277.2
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• 2014

For next-generation electronic applications, human-machine interface devices have recently been demonstrated such as the wearable computer as well as the electronic skin (e-skin). For integration of those systems, it is essential to develop many kinds of components including displays, energy generators and sensors. In particular, flexible sensing devices to detect some stimuli like strain, pressure, light, temperature, gase and humidity have been investigated for last few decades. Among many condidates, a pressure sensing device based on organic field-effect transistors (OFETs) is one of interesting structure in flexible touch displays, bio-monitoring and e-skin because of their flexibility. In this study, we have investigated a flexible e-skin based on highly sensitive, pressure-responsive OFETs using microstructured ferroelectric gate dielectrics, which simulates both rapidly adapting (RA) and slowly adatping (SA) mechanoreceptors in human skin. In SA-type static pressure, furthermore, we also demonstrate that the FET array can detect thermal stimuli for thermoreception through decoupling of the input signals from simultaneously applied pressure. The microstructured highly crystalline poly(vinylidene fluoride-trifluoroethylene) possessing piezoelectric-pyroelectric properties in OFETs allowed monitoring RA- and SA-mode responses in dyanamic and static pressurizing conditions, which enables to apply the e-skin to bio-monitoring of human and robotics.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.550-551
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• 2012

Physically responsive field-effect transistors (physi-FETs), which are sensitive to physical stimuli, have been studied for decades. However, the primary issue of separating responses by sensing materials from interferences by other subcomponents in a FET transducer under global physical stimuli has not been completely resolved. Recent challenges of structural design and employing smart materials with a large electro-physical coupling effect for flexible physi-FETs still remain. In this article, we propose directly integrating nanocomposites of barium titanate (BT) nanoparticles (NPs) and highly crystalline poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) as gate dielectrics into flexible organic FETs to precisely separate and quantify tiny variations of remnant polarization caused by mechanical stimuli. Investigations under static stimuli resulted in first-reported giant-positive piezoelectric coefficients of d33 up to 960 pC/N, presumably due to significant contribution of the intrinsic piezoelectricity of BT NPs and P(VDF-TrFE) crystallites. This approach provides a general research direction, and not limited to physic-FETs.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.13-16
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• 2005

The mechanical properties of composite materials may degrade severely in the presence of damage. Especially, the high-velocity impact such as bird strike, a hailstorm, and a small piece of tire or stone during high taxing, can cause sever damage to the structures and sub-system in spite of a very small mass. However, it is not easy to detect the damage in composite plates using a single technique or any conventional methods. In this paper, the PYDF(polyvinylidene fluoride) film sensors and strain gages were used for monitoring impact damage initiation and propagation in composite laminates. The WT(wavelet transform) and STFT(short time Fourier transform) are used to decompose the sensor signals. A ultrasonic C-scan and a digital microscope are also used to examine the extent of the damage in each case. This research demonstrate how various sensing techniques, PVDF sensor in particular, can be used to characterize high-velocity impact damage in advanced composites.

• Smart Structures and Systems
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• v.4 no.3
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• pp.291-304
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• 2008

Piezoelectric materials have been widely used in ultrasonic nondestructive testing (NDT). PZT ceramics can be used to receive and generate surface acoustic waves. It is a common application to attach PZT transducers to the surface of structures for detecting cracks in nondestructive testing. However, not until recently have piezoelectric polymers attracted more and more attention to be the material for interdigitated (IDT) surface and guided-wave transducers. In this paper, an interdigitated gold-on-polyvinylidene fluoride (PVDF) transducer for actuating and sensing Lamb waves has been introduced. A specific etching technology is employed for making the surface electrodes into a certain finger pattern, the spacings of which yield different single mode responses of Lamb waves. Experiments have been performed on steel and carbon fiber composite plates. Results from PVDF IDT sensors have been compared with those from PZT transducers for verification.

• 제어로봇시스템학회:학술대회논문집
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• 2002.10a
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• pp.97.6-97
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• 2002

In this paper, we present an arrayed flexible tactile sensor, which can detect contact normal forces as well as positions. The tactile sensor is developed using Polyvinylidene Fluoride (PVDF) that is known as piezoelectric polymer, and the surface electrode is fabricated using silk-screening technique with silver. We develop a charge amplifier in order to amplify the small signal from the sensor, and a fast signal processing unit by using a DSP chip. The developed tactile sensor is physically flexible and it can be deformed three-dimensionally to any shape so that it can be placed on anywhere on the curved surface. In the future, the developed sensor is applied to a dexterous robotic hand...$\textbullet$ Tactile sensing, PVDF, Robot hand

• Journal of Institute of Control, Robotics and Systems
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• v.10 no.1
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• pp.60-65
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• 2004

A flexible tactile sensor away with 8 H 8 tactile elements is designed and fabricated. The material of the sensor is PVDF(polyvinylidene fluoride) film and flexible circuitry is used in the fabrication fur the flexibility of the sensor The experimental results on static and dynamic properties of the sensor are obtained and examined. The signals of a contact pressure to the sensor are sensed and processed in the DSP system in which the signals are digitalized and filtered. The processed signals of the sensor outputs are visualized in a personal computer for illustrating the shape and force distribution of a contact object. The reasonable performance for the detection of contact state is verified through sensing examples.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2002.10a
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• pp.216-219
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• 2002

Conventional piezoelectric lead-zirconate-titanate (PZT) senor has high sensitivity, but it is very brittle. Recently polymer films such as polyvinylidene fluoride (PVDF) have been used use as a sensor. The advantages of PVDF are the flexibility and mechanical toughness. Simple process and possible several shapes are also additional advantages. PVDF sensor can be directly embedded and attached to a structure. In this study, PVDF sensor was embedded in single glass fiber/epoxy composites whereas PZT sensor with AE was attached to single fiber composites (SFC). Piezoelectric sensor responds to interfacial damage of SFC. The signals measured by PVDF sensor were compared to PZT sensor. PZT sensor detected the signals of fiber fracture, matrix crack, interfacial debonding and even sensor delamination, whereas PVDF sensor only detected fiber fracture signals so far, because PZT sensor is much more sensitive than current PVDF sensor. Wave voltage of fiber fracture measured by PVDF sensor was lower than that of PZT sensor, but the results of fast Fourier transform (FFT) analysis were same. Wave velocity using two PZT sensors was also studied to know the internal and surface damage effect of epoxy specimens.