• Title/Summary/Keyword: Fluorescent properties

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Conduction properties of phosphorescent emitting layers and their application to optimizing white OLEDs

  • Baek, Heume-Il;Noh, Seung-Uk;Lee, Hyun-Koo;Suman, C.K.;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1055-1055
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    • 2009
  • The mobility of charge carriers has been investigated in the pristine and phosphorescent materials doped host materials using time-of-flight photoconductivity technique. The field and temperature dependences of the mobility were analyzed with the Gaussian disorder model. Based on these results, we optimized white organic light emitting diodes (WOLEDs) consisting of multi-emitting layers doped with phosphorescent and fluorescent dopants. Especially, we studied the effect of each emitter position and an interlayer on the device characteristics of WOLEDs.

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E-H mode transition of Inductively Coupled Plasma with Ar Gas Pressure and RF Power (13.56MHz) (Ar 가스압력과 RF 전력변화 (13.56MHz)에 따른 유도결합형 플라즈마의 광학적 E-H모드변환 특성)

  • Her, In-Sung;Lee, Young-Hwan;Choi, Young-Sung;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1695-1697
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    • 2003
  • In this paper the emission properties of electrodeless fluorescent lamp were discussed using the inductively coupled plasma. To transmit the electromagnetic energy into the chamber a RF power of 13.56MHz was appied to the antenna and considering the Ar gas pressure and the RF electric power change, the emission spectrum, Ar-I line, luminance were investigated. At this time the input parameter for ICP RF plasma, Ar gas pressure and RF power were applied in the range of 10${\sim}$60m Torr, 10${\sim}$300W respectively.

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White Light -Emitting Diodes with Multi-Shell Quantum Dots

  • Kim, Kyung-Nam;Han, Chang-Soo;Jeong, So-Hee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.92-92
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    • 2010
  • Replacing the existing illumination with solid-state lighting devices, such as light-emitting diodes (LEDs) are expected to reduce energy consumption and environmental pollution as they provide better efficiency and longer lifetimes. Currently, white light emitting diodes are composed of UV or blue LED with down-converting materials such as highly luminescent phosphors White light-emitting diodes (LED) were fabricated with multi-shell nanocrystal quantum dots for enhanced luminance and improved stability over time. Multi-shell quantum dots (QDs) were synthesized through one pot process by using the Successive Ionic Layer Adsorption and Reaction (SILAR) method. As prepared, the multi-shell QD has cubic lattice of zinc-blend structure with semi-spherical shape with quantum yield of higher than 60 % in solution. Further, highly fluorescent multi-shell QD was deposited on the blue LED, which resulted in QD-based white LED with high luminance with excellent color rendering properties.

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Absorption and Fluorescence Studies of 3-Ethenylindoles

  • Singh, Anil K.;Hota, Prasanta K.
    • Journal of Photoscience
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    • v.11 no.3
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    • pp.107-113
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    • 2004
  • Synthesis, absorption and fluorescence properties of 3-methyl indole (1), N-(benzenesulfonyl)-3-(3-oxo-but-1-enyl)-indole (2) and 1H-3-(3-oxo-but-1-enyl)-indole (3) are described. Extended conjugation at C-3 of indole as in 3 causes moderate resolution of $^1L_a$ and $^1L_b$ bands. However, 2 having an electron-withdrawing group at indolic nitrogen shows only the $^1L_a$ band. While the $^1L_b$ band largely remains solvent polarity independent, the $^1L_a$ band undergoes moderate red shift in polar solvents. The fluorescence in 2 and 3 originates from the $L_b$ transition. Additionally, interaction of 2 and 3 with BSA indicates that these compounds bind to the hydrophobic site of BSA with the formation of a highly fluorescent BSA-probe complex.

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Fluorescent Properties of Daehwangjam, Golden Silk, and Juhwangjam and Their Diminishing upon HCl Vapor Exposure

  • Rakesh K. Jha;Seong-Wan Kim;Sunghwan Kim
    • International Journal of Industrial Entomology and Biomaterials
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    • v.48 no.1
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    • pp.19-24
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    • 2024
  • For over five millennia, humans have benefited from the valuable byproducts of Bombyx mori silkworms nourished on mulberry leaves and a multitude of potential applications remains available due to the diverse array of silkworm varieties. In this work, we discuss the utilization of Daehwangjam (DHJ), golden silk (GS), and Juhwangjam (JHJ), distinctive colored silks found in Korea, as chemosensors. These novel silks emit fluorescence under external stimuli and show a diminishing fluorescence intensity when exposed to HCl vapor. The considerable surface-to-volume ratio of these cocoons allows for the identification of 5 ppm, 300 ppm, and 3000 ppm HCl vapors through decreased fluorescence intensity. The results show the suitability of natural DHJ, GS, and JHJ for applications in biosensing applications.

Synthesis and Characterization of CdSe Quantum Dot with Injection Temperature and Reaction Time (Injection 온도 및 합성시간에 따른 CdSe 양자점 합성 및 특성)

  • Eom, Nu-Si-A;Kim, Taek-Soo;Choa, Yong-Ho;Kim, Bum-Sung
    • Korean Journal of Materials Research
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    • v.22 no.3
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    • pp.140-144
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    • 2012
  • Compared with bulk material, quantum dots have received increasing attention due to their fascinating physical properties, including optical and electronic properties, which are due to the quantum confinement effect. Especially, Luminescent CdSe quantum dots have been highly investigated due to their tunable size-dependent photoluminescence across the visible spectrum. They are of great interest for technical applications such as light-emitting devices, lasers, and fluorescent labels. In particular, quantum dot-based light-emitting diodes emit high luminance. Quantum dots have very high luminescence properties because of their absorption coefficient and quantum efficiency, which are higher than those of typical dyes. CdSe quantum dots were synthesized as a function of the synthesis time and synthesis temperature. The photoluminescence properties were found strongly to depend on the reaction time and the temperature due to the core size changing. It was also observed that the photoluminescence intensity is decreased with the synthesis time due to the temperature dependence of the band gap. The wavelength of the synthesized quantum dots was about 550-700 nm and the intensity of the photoluminescence increased about 22~70%. After the CdSe quantum dots were synthesized, the particles were found to have grown until reaching a saturated concentration as time increased. Red shift occurred because of the particle growth. The microstructure and phase developments were measured by transmission electron microscopy (TEM) and X-ray diffractometry (XRD), respectively.

A Study on Optical Properties of Nanocomposite Composed of Au Nanorods and Organic Dyes (금 나노막대와 유기 염료로 구성된 나노복합체의 광학특성 연구)

  • Kim, Ki-Se;Yoo, Seong Il;Sohn, Byeong-Hyeok
    • Clean Technology
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    • v.20 no.2
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    • pp.141-145
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    • 2014
  • In this study, we studied optical properties on the layer-by-layer (LbL) assemblies consisting of Au nanorods and organic dyes. For this purpose, poly (allylamine hydrochloride), PAH and poly (styrene sulfonate), PSS were selected as ionic polymers and rhodamine B isothiocyanate (RB) was utilized as an organic dye based on its spectral overlap with plasmon band of Au nanorods. In the view point of assembling methods, RB was covalently attached to PAH, then, LbL structure of Au [PSS/PAH]2/PSS/PAH-RB was prepared by sequential coating of PAH, PSS, PAH-RB on Au nanorods. Since the prepared LbL assembly exhibits both plasmonic and fluorescent properties, we studied the mutual nanorod-dye properties by dissolving Au nanorods.

Electrochemical and Fluorescent Properties of Ferrocenyl Chalcones Containing 1-Naphthalenyl Group: X-ray Crystal Structure of Fc-C(O)CH=CH-(1-Naph)

  • Suh, Woo-Young;Jeon, Hyo-Kyung;Lee, Ji-Yeon;Lim, Chae-Mi;Lee, Su-Kyung;Noh, Dong-Youn
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.443-448
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    • 2012
  • Ferrocenyl chalcones (Fc-C(O)CH=CH-Ar: Fc-Ar) with mono- and di-1-naphthalenyl moieties (Fc-1Naph and Fc-d1Naph) were prepared and spectroscopically characterized. The enone bridge was in the s-cis conformation and the $\pi$-electrons on the C=C bond were further delocalized on the bridge. The naphthalenyl moiety deviates greatly from the enone-Cp plane by $26.9(1)^{\circ}$. Cyclic voltammetry measurements for Fc-1Naph exhibit one reversible cycle for the redox of the ferrocenyl moiety at a lower potential, and one irreversible oxidation peak at the higher potential region. For Fc-d1Naph, the cyclic voltammogram is more featureless. Fluorescence properties for both compounds are active in polar solvents with $\lambda_{em}$ = 500 nm (EtOH) and $\lambda_{em}$ = 512 nm (MeOH) for Fc-1Naph and $\lambda_{em}$ = 496 nm (EtOH) and $\lambda_{em}$ = 508 nm (MeOH) for Fc-d1Naph. The intensity of Fc-d1Naph is more than twice than that of Fc-1Naph. The fluorescence properties for both compounds are inactive in the less polar solvents such as $CH_3CN$, $CH_2Cl_2$ and $CHCl_3$.

Fabrication and analysis of luminous properties of phosphor ceramic for laser headlamp in automotive application (자동차용 레이저 헤드램프를 위한 형광체 세라믹 제조 및 발광 특성 분석)

  • Choi, Seung Hee;Kwon, Seok Bin;Yoo, Jung Hyeon;Kim, Jae Pil;Kim, Wan Ho;Jeong, Ho-Jung;Kim, Bo Young;Yoon, Dae Ho;Song, Young Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.2
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    • pp.73-77
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    • 2020
  • In this study, phosphor ceramics were fabricated, and optical properties were analyzed for application to nextgeneration automotive laser headlamps by using a spherical YAG : Ce phosphor with a garnet structure synthesized based on the spray drying method. The thickness of phosphor ceramic using spherical YAG : Ce phosphor was obtained with 100 ㎛, 150 ㎛, and 200 ㎛ to investigate the effect of thickness on optical properties such as light conversion efficiency, heat dissipation, luminance and color temperature. The results of this study are expected to play a significant role in the manufacturing process for the fabrication of phosphor ceramic by solving issues such as the high cost and low yield in the conventional liquid method to manufacture YAG : Ce nano fluorescent materials.

Characteristics of Asphalt Concrete using Waste Foundry Sand (주물고사 첨가 아스팔트 콘크리트의 특성에 관한 연구)

  • Kim, Kwang-Woo;Ko, Dong-Hyuk;Choi, Dong-Chon;Kim, Sung-Won;Kim, Joong-Yul
    • International Journal of Highway Engineering
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    • v.3 no.4 s.10
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    • pp.105-116
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    • 2001
  • This study was performed to evaluate the characteristics of waste foundry sand (WFS) and the asphalt mixture made of a foundry waste sand. To estimate the applicability of WFS, chemical and physical properties were measured by XRF(X-ray fluorescent), and SEM(Scanning electronic microfilm). To improve the stripping resistance of WFS asphalt mixture, anti-stripping agents (a hydrated lime and a liquid anti-stripping agent) were used. To improve tensile properties and durability of WFS asphalt concrete mixture, LDPE(low-density polyethylene) was used as an asphalt modifier Marshall mix design, indirect tensile strength, tensile strength ratio(TSR) after freezing and thawing, moisture susceptibility and wheel tracking tests were carried out to evaluate performance of WFS asphalt concrete. Comparing with conventional asphalt concrete, WFS asphalt concretes showed similar or the better qualify in mechanical properties, and satisfied all specification limits. Therefore, it Is concluded that waste foundry sand can be recycled as an asphalt pavement material.

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