• Title/Summary/Keyword: Fluorescent Dye

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Optical and electrical characteristics of White OLEDs (White OLEDs의 전기 및 광학적 특성 평가)

  • Hwang, Sun-Pil;Moon, Dae-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04a
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    • pp.25-26
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    • 2008
  • In this paper, the white organic light-emitting diode(OLED)was fabricated using the DPVBi of blue emitting material and a rubrene of orange color of fluorescent dye by vacuum evaporation processes. The device structure of OLED was Glass/ITO/2T-NATA(15nm)/NPB(3nm)/DPVBi(3nm)/DPVBi rubrene[2%](10nm)/DPVBi(25nm)/$Alq_3$ or New-ETL(60nm) /LiF(0.5nm)/ Al(100nm). The device with the $Alq_3$, layer shows orange color, and the luminance of 1000cd/$m^2$ at an applied voltage of 10.4V. On the other hand, the New-En layer results in white color, CIE coordinates of (0.327, 0.323), and the lowered driving voltage of 5V for achieving the same luminance value.

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Electroluminescent Property of Tetrahydrochrysene as a Potential Emitting Layer in Organic Electroluminescent Device

  • Hwang, Kwan-Jin;Kim, Jin-Guk;Lee, Seung-Hee;Kwon, Oh-Kwan;Kim, Young-Kwan
    • Journal of Photoscience
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    • v.7 no.2
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    • pp.59-61
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    • 2000
  • As a potential electroluminescent material, tetrahydrochrysene (THC) is prepared using the dehydrocyclization following the acyloin condensation of methyl-3-phenyl propionate as key step from trans-mehyl cinnamate in 3 steps. THC showed emission at 428 and 456 nm after the photo- and electro-excitation, respectively. The luminance of THC doped on PVK was about /$25 cdm^2$ at 30 voltage with 70 nm of thickness. The results suggests that a new fluorescent organic dye, THC can be used organic electroluminescent device.

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Heptelidic Acid, a Sesquiterpene Lactone, Inhibits Etoposide-Induced Apoptosis in Human Leukemia U937 Cells

  • Kim, Jin-Hee;Lee, Choong-Hwan
    • Journal of Microbiology and Biotechnology
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    • v.19 no.8
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    • pp.787-791
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    • 2009
  • In the course of screening for substances that inhibit etoposide (10 ${\mu}g$/ml)-induced apoptosis in human leukemia U937 cells, fungal strain F000120, which exhibits potent inhibitory activity, was selected. The active compound was purified from an ethyl acetate extract of the microorganism by Sep-pak $C_{18}$ column chromatography and HPLC, and was identified as heptelidic acid (koningic acid) by spectroscopic methods. This compound inhibited caspase-3 induction in U937 cells with an $IC_{50}$ value of 40 ${\mu}M$ after 8 h of etoposide treatment. Fluorescent dye staining with acridine orange and ethidium bromide showed that heptelidic acid inhibited apoptosis. Furthermore, it was found that DNA fragmentation and caspase-3 activation, the biological hallmarks of apoptosis, were inhibited by the compound in a dose-dependent manner, suggesting that heptelidic acid inhibits etoposide-induced apoptosis via downregulation of caspases.

Synthesis and Photoluminescence of Biphenol Derivatives with Fluorescent Chromophore (형광 발색단을 가진 biphenol유도체의 합성과 PL)

  • Lee, Mun-Hag;Yang, Jong-Heon;Chung, Su-Tae;Son, Se-Mo;Kim, Sung-Bin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1010-1012
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    • 2002
  • 3,3'-di-benzothiazole-4,4-biphenol(DBTB), 3,3',5,5'-tetra-benzothiazole-4,4'- biphenol(TBTB), 5,5'-methy lene-bis(2-(2'-hydroxyphenyl) benzothiazole derivatives were synthesized by multistep. PL of DBTB and TBTB were dramatically shift 47nm and 75nm respectively longer wavelength than the emission of 2-(2'-hydroxyphenyl)-benzothiazole(HBT) because of intramolecular extened $\pi$-conjugate system but methylene-bis-benzothiazole derivatives do not occur at Wavelength-shift.

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Simultaneous Measurements of Temperature and Velocity Fields of a Buoyant Jet Using LIE and PIV Techniques (LIE와 PIV 기법을 이용한 부력제트의 온도장과 속도장 동시측정)

  • Kim Seok;Jang Young Gil;Lee Sang Joon
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.513-516
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    • 2002
  • The flow structure and heat transfer characteristics of a turbulent buoyant jet were investigated experimentally. The instantaneous temperature and velocity fields in the near field were measured using a two-frame PIV and PLIF techniques. A thin light sheet illuminated a two-dimensional cross section of the buoyant jet in which Rhodamine B was added as a fluorescent dye. The intensity variations of LIF signal from Rhodamine B molecules scattered by the laser light were captured by a CCD camera after passing an optical filter. By ensemble averaging the instantaneous temperature and velocity fields, the mean temperature and velocity fields as well as the spatial distributions of turbulent statistics were obtained. The results show the flow structure and convective heat transfer of the developing shear layer in the near field.

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Fluorescence Micropatterning Based on the Polymeric Photobase Generator Containing Oxime-Urethane Groups by Dansylation

  • Choi, Won San;Kim, Hak Soo;Chae, Kyu Ho
    • Rapid Communication in Photoscience
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    • v.2 no.1
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    • pp.24-27
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    • 2013
  • A polymeric photobase generator containing oxime-urethane groups is applied to a fluorescence micropatterning material. Polymer bearing oxime-urethane groups was prepared by copolymerization of methyl methacrylate with methacryloyloxyethyl benzophenoneoxime urethane (MBU). The reaction of amino groups in the irradiated copolymer film with dansyl chloride (Dns-Cl) was monitored by using UV absorption, IR absorption and fluorescence spectroscopy. The fluorescence spectrum of the Dns-Cl-treated irradiated copolymer film shows a strong fluorescence with a fluorescence maximum wavelength at 510 nm. A blue fluorescent micropattern with a line width of $2{\sim}3{\mu}m$ was obtained. Treatment of the irradiated copolymer film with Dns-Cl and rhodamine B mixture led to the formation of green, red, and orange-colored fluorescence micropatterns. Thus, various colored micropatterns on a single polymer film can be obtained by selective excitation of each dye molecules.

Experimental study on effect of nanochannel numbers and working conditions for concentration polarization based desalination process (농도분극현상을 이용한 담수화 과정에서의 나노채널 개수 및 운전조건 영향에 대한 실험 적 연구)

  • Li, Longnan;Kim, Daejoong
    • Journal of the Korean Society of Visualization
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    • v.13 no.2
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    • pp.16-21
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    • 2015
  • Concentration polarization(CP) phenomena show great potential on desalination technology. As we can control the dimension of silicon based nanochannel system, it can be used to model ion exchange membrane. In this study, to investigate the effect of nanochannel number and working conditions on the CP based desalination process, nanochannel based microfluidic system is fabricated. First, we optimized nanochannel number and working conditions to conduct visualization study on CP based desalination process. Second, we visualized the desalination process with fluorescent dye in the desalination chip. We also visualized that the particles also can be removed by the CP based desalination process.

Potassium Distribution in the Apical Region of Rice Root

  • Rehman Shafiq;Park Moung-Ryoul;Ashraf Muhammad;Yun Song-Joong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.4
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    • pp.295-297
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    • 2006
  • Potassium (K) distribution in rice (Oryza sativa L.) root was studied by confocal laser microscopy, using potassium sensitive fluorescent dye potassium-binding benzofuran isophthalate (PBFI). Significantly high intensity of K-specific fluorescence was detected at the root cap region followed by meristematic and basal regions. A negligible or fainted fluorescence was observed at the root hairs area. These results suggest that K is heavily distributed in the apical area of rice root, which may be required in higher concentration for division and extension of cells, as it is the rapidly growing region of the root, moreover, may also be involved in water uptake by creating osmotic gradient across membranes.

Red Organic Light-emitting Diodes utilizing Energy Transfer and Charge Trapping

  • Kim, Ju-Seung;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.3
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    • pp.91-96
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    • 2005
  • We report the efficient red light-emitting diodes based on the fluorescent dye 4-(dicyanomethylene)-2-i-propyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTI) and 5,6,11,12-tetraphenyl naphthacene (rubrene) codoped in the tris(8-hydroxyquinoline)aluminum $(Alq_3)$. Luminance efficiency of 2.2 cd/A with a Commission International De L'Eclairage (CIE) chromaticity coordinate of x, y = (0.640, 0:350) are achieved at the driving current density of $20\;mA/cm^2$. Adding the rubrene to the DCJTI in tris(8-hydroxyquinoline)aluminum $(Alq_3)$, the red color purity and luminance efficiency improved comparing to the DCJTI only doped devices because the rubrene molecules assist the polarization effect of DCJTI by molecular interaction and enhance the energy transfer from $(Alq_3)$ to DCJTI.

Syntheses and Thermal Properties of 5,10-Disubstituted-2,3,7,8-tetracyano-5,10-dihydrodipyrazino [2,3-b:2′,3′-el pyrazines and Polymeric Porphyrazines Derived from 2,3-Dichloro-5,6-dicyanopyrazine

  • Jaung, Jae-yun;Kim, Sung-Dong
    • Fibers and Polymers
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    • v.1 no.2
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    • pp.71-75
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    • 2000
  • Intermolecular cyclization of 2-alkylamino-3-chloro-5,6-dicyanopyrazine 2 in the presence of tributylamine in N,N-dimethylformamide (DMF) gave 5,10-disubstituted-2,3,7,8-tetracyano -5,10-dihydrodipyrazino〔2,3-b:2',3'-e]pyrazines 3, which showed strong mesomorphic property and were anticipated as new chromophoric system for functional dye materials. Absorption spectra, fluorescent properties and other physical properties were correlated with their chemical structures. Vanadyl oligomeric porphyrazine with long alkyl groups synthesized from 3 had satisfactory solubility in tetrahydrofuran (THF), diethyl ether and dimethylsulfoxide (DMSO). The syntheses and characterization of vanadyl polymeric porphyrazines derived from 3 with long alkyl groups are reported.

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