• Tribology and Lubricants
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• v.29 no.1
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• pp.51-55
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• 2013

In this work, a new fluorescence emission measurement technology was introduced and experimentally compared with other measurement methods, such as the titration method and IR spectroscopy, to validate it for the oil oxidation measurement of electrical insulating oil. The oxidation characteristics of insulating oil were found to be fairly represented by the titration method and IR spectroscopy, and the results are comparable to a change in the fluorescence emission ratio that is defined as the shift in fluorescence intensity in the measured wavelength range. The result also shows that by the measurement of fluorescence emission ratio, it is possible to detect the oxidation of oil relatively earlier than by other methods. This study suggests that the developed technology can provide sufficient information for evaluating the insulating oil quality, and that the developed FER sensor can be used as an effective condition monitoring device of electrical insulating oil oxidation.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.353-356
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• 2002

Planar laser induced fluorescence(PLIF) has been widely used to obtain two dimensional fuel distribution. Preliminary investigation was performed to measure quantitative air excess ratio distribution in an engine fueled with LPG. It is known that fluorescence signal from acetone as a fluorescent tracer is less sensitive to oxygen quenching than other dopants. Acetone was excited by KrF excimer laser (248nm) and its fluorescence image was acquired by ICCD camera with a cut-of filter to suppress Mie scattering from the laser light. For the purpose of quantifying PLIF signal, an image processing method including the correction of laser sheet beam profile was suggested. Raw images were divided by each intensity of laser energy and profile of laser sheet beam. Inhomogeneous fluorescence images scaled with the reference data, which was taken by a calibration process, were converted to air excess ratio distribution. This investigation showed instantaneous quantitative measurement of planar air excess ratio distribution for gaseous fuel.

• Journal of Environmental Science International
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• v.27 no.6
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• pp.437-445
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• 2018

Laser induced-exciplex-fluorescence (EXCIPLEX) proposed by Melton is used to visualize fuel vapor in spray combustion. However, in the EXCIPLEX method based on TMPD/naphthalene system, the TMPD : naphthalene ratio is strictly restricted to 1 : 9. In addition, fluorescence intensity due to the vapor phase is extremely weak. To overcome these drawbacks, we propose a new laser-induced-excimer fluorescence (EXCIMER) method to visualize the liquid and vapor phases simultaneously. The spatial distributions of liquid and vapor in fuel spray suspended by ultrasonic waves are compared using the EXCIPLEX and EXCIMER methods. The correlation between fuel vapor concentration and fluorescence intensity is experimentally investigated by measuring the fluorescence intensity of saturated vapor formed over liquid fuel at a controlled temperature. These experimental results indicate that the EXCIMER method is effective for evaluating fuel vapor visualization in spray combustion. Furthermore, the quantitative distribution of fuel vapor concentration can be correctly estimated by the EXCIMER method.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.1
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• pp.74-82
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• 2004

Planar laser-induced fluorescence(PLIF) has been widely used to obtain two dimensional fuel distribution. Acetone PLIF is chosen because fluorescence signal from acetone as a fluorescent tracer is less sensitive to oxygen quenching than other dopants. Acetone PLIF is applied to measure quantitative air excess ratio distribution in an engine fueled with LPG. Acetone is excited by KrF excimer laser (248nm) and its fluorescence image is acquired by ICCD camera with a cut-off filter to suppress Mie scattering from the laser light. For the purpose of quantifying PLIF signal, an image processing method including the correction of laser sheet beam profile is suggested. Raw images are divided by each intensity of laser energy and profile of laser sheet beam. Inhomogeneous fluorescence images scaled with the reference data, which is taken by a calibration process, are converted to air excess ratio distribution. This investigation shows instantaneous quantitative measurement of planar air excess ratio distribution for gaseous fuel.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.781-789
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• 2008

The fluorescence ratio method for processing planar laser induced fluorescence(PLIF) data was generalized for quantitative imaging of the injectant mole-fraction in supersonic mixing flowfields. The original fluorescence ratio approach was introduced by Hartfield et al. for tests in a special closed-loop wind tunnel to eliminate the effects of thermodynamic property variations in compressible flowfields and to provide a quantitative means of mole-fraction measurement. However, they implicitly assumed that the tracer molecules were seeded at the same fraction in both main and secondary flows. In the present study, we proposed generalizing the Hartfield method by considering differences in the tracer seeding rates. We examined the generalized method in a mixing flowfield formed by sonic transverse injection into a Mach 1.8 supersonic air stream. The injectant molefraction distribution obtained from PLIF data processed by our new approach showed better agreement with the gas chromatograph than one based on the Hartfield method.

• Journal of Mechanical Science and Technology
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• v.14 no.10
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• pp.1143-1150
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• 2000

The effects of ambient conditions on vaporizing sprays from a high-pressure swirl injector were investigated by an exciplex fluorescence method. Dopants used were 2% fluorobenzene and 9% DEMA (diethyl-methyl-amine) in 89% solution of hexane by volume. In order to examine the behavior of liquid and vapor phases inside of vaporizing sprays, ambient temperatures and pressures similar to engine atmospheres were set. It was found that the ambient pressure had a significant effect on the axial growth of spray, while ambient temperature had a great influence on the radial growth. The spatial distribution of vapor phase at temperatures above 473K became wider than that of liquid phase after half of injection duration. From the analysis of the area ratio for each phase, the middle part (region II) in the divided region was the region which liquid and vapor phases intersect. For liquid phase, fluorescence-intensity ratio was greatly changed at lms after the start of injection. However, the ratio of vapor phase was nearly uniform in each divided region throughout the injection.

• Analytical Science and Technology
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• v.35 no.1
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• pp.1-7
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• 2022

This study suggests a new one-step fluorescent cyanoacylate-fuming method for developing fingerprints by using a CAB mixed with dimethylaminobenzalde (DMAB) and cyanoacylate (CA) in a specific ratio. CAB is prepared by mixing 2.5 % (w/w) DMAB with CA and fumigated at 180 ℃. Under these conditions, developing fingerprints showed the best results. The fuming method using CAB develops latent fingerprints into fluorescence and has a higher sensitivity than CA, and it showed comparable or better contrast to existing fluorescence enhancement methods. It was also applicable on a variety of non-porous surfaces that can be encountered at ordinary times. This method is more useful than conventional fluorescent dyeing methods in that it minimizes damage to fingerprints or samples, makes it easy to manufacture, saves time, and can use existing current equipment as it is.

• Journal of Mechanical Science and Technology
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• v.17 no.1
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• pp.157-167
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• 2003

The exciplex fluorescence technique with the TMPD (tetamethyl-Ρ-phenylene-diamine) / naphthalene dopant system was applied in a combustion-type constant-volume spray chamber. A detailed set of calibration experiments has been performed in order to quantify the TMPD fluorescence signal. It has been demonstrated that the TMPD fluorescence intensity was directly proportional to concentration, was independent of the chamber pressure, and was not sensitive to quenching by either water vapor or carbon dioxide. Using a dual heated-jet experiment, the temperature dependence of TMPD fluorescence up to 1000 K was measured. The temperature field in the spray images was determined using a simple mixing model, and an iterative solution method was used to determine the concentration and temperature field including the additional effects of the laser sheet extinction. The integrated fuel vapor concentration compared favorably with the measured amount of injected fuel when all of the liquid fuel had evaporated.

• Journal of Industrial and Engineering Chemistry
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• v.67
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• pp.236-243
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• 2018

A series of $Er^{3+}/Yb^{3+}$ co-doped fluorophosphate glasses with varying $YbF_3$ concentration were prepared by a high temperature melt quenching technique. Absorption and emission cross-sections were determined by using the McCumber theory. The larger emission cross-section ($9.86{\times}10^{-21}cm^2$) and longer fluorescence lifetime (12.37 ms) were obtained for the $^4I_{13/2}{\rightarrow}^4I_{15/2}$ transition of ABS3Er4Yb glass. The sensitivity and temperature of the maximum sensitivity were evaluated by the fluorescence intensity ratio method from the measured upconversion spectra. The results were discussed and compared to the other reported glasses.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.26 no.4
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• pp.614-621
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• 2002

This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston bowl shapes(F, B and R-type) in a optically accessible engine. The images of liquid and vapor phases were captured in the motoring engine using exciplex fluorescence method. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure was 5.1MPa. Two dimensional spray fluorescence image of vapor phase was acquired to analyze spray behaviors and fuel distribution inside of cylinder. Four injection timings were set at BTDC 90$^{\circ}$, 80$^{\circ}$, 70$^{\circ}$, and 60$^{\circ}$. With a fuel injection timing of BTDC 90$^{\circ}$, fuel-rich mixture level in the center region was highest in a B-type piston. With a fuel injection timing of BTDC 60$^{\circ}$, R-type piston was best. R-type piston shape was suitable under enhanced swirl ratio and late injection condition and B-type piston shape was right in a weak swirl ratio. It was found that the piston bowl shape affected the mixture stratification inside of cylinder.