• 한국세라믹학회지
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• 제54권5호
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• pp.380-387
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• 2017

In this study, unstable CaO was converted into a stable Ca compound by using carbonation in a circulating fluidized bed boiler of fly ash to confirm material usability as cement admixture; also undertaken was carbonation test and mortar to examine chemical and physical change by measuring absorption rate and compressive strength. To investigate the chemical properties of circulating fluidized bed boiler fly ash, XRD and TG-DTA were used to determine how the properties of the reaction product change quantitatively during carbonation. In order to stabilize CaO, carbonation of CaO is considered to be the most desirable process. This is because $CaCO_3$, which is a Ca compound, was produced by carbonate reaction of unstable CaO, and decrease of the absorption rate and improvement of the compressive strength were observed when the carbonated fly ash was replaced with cement.

• 한국세라믹학회지
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• 제54권2호
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• pp.128-136
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• 2017

Fly ash from a circulating fluidized bed combustion boiler (CFBC fly ash) is very different in mineralogical composition, chemical composition, and morphology from coal ash from traditional pulverized fuel firing because of many differences in their combustion processes. The main minerals of CFBC fly ash are lime and anhydrous gypsum; however, due to the fuel type, the strength development of CFBC fly ash is affected by minor components of active $SiO_2$ and $Al_2O_3$. The initial hydration product of the circulating fluidized bed combustion fly ash (B CFBC ash) using petro coke as a fuel is Portlandite which becomes gypsum after 7 days. Due to the structural features of the portlandite and gypsum, the self-cementitious strength of B CFBC ash was low. While the hydration products of the circulating fluidized bed combustion fly ash (A CFBC ash) using bituminous coal as a fuel were initially portlandite and ettringite, after 7 days the hydration products were gypsum and C-S-H. Due to the structural features of ettringite and C-S-H, A CFBC ash showed a certain degree of self-cementitious strength.

• 한국세라믹학회지
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• 제56권2호
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• pp.153-159
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• 2019

In this study, fly ash of a fluidized bed boiler produced in a power plant was stabilized by hydration and carbonation reaction. Then, each raw material was pulverized by two kinds of grinding equipment (Planetary mills and pot mills); the degree of grinding and the agglomeration behavior were observed. It was found that there were changes of specific surface area and particle size distribution according to grinding time. The surface of the raw material was observed using an optical microscope. As a result, agglomerates of about 75 ㎛ or more due to electrostatic phenomenon were formed as the grinding time became longer; it was confirmed that the crushing efficiency slightly increased with use of antistatic agent.

• 한국구조물진단유지관리공학회 논문집
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• 제22권5호
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• pp.119-126
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• 2018

최근 화력발전소에서는 순환유동층 연소방식의 발전소가 증가하는 추세이다. 순환유동층 보일러애시는 탈황 효과를 위해 석회석을 첨가함에 따라 애시 중에 포함되는 CaO, $SO_3$성분이 증가하여 일반적인 플라이애시 보다 free-CaO 함량이 높다. 또한 순환유동층 보일러애시는 기존의 플라이애시와 다르게 자기수경성 특성과, 높은 free-CaO함량에 의해 물과 만나면 높은 반응성을 갖는다. 본 연구는 순환유동층 보일러애시의 자기수경성 특성을 이용하여, 시멘트를 대체할 수 있는 비소성 결합재로써 활용 가능성에 대해 분석하였다. 순환유동층 보일러 애시의 함량에 따른 역학적 및 수화특성에 대해 검토하였다. 또한 석고의 종류 및 함유량에 따른 순환유동층 보일러애시 활용 비소성 결합재에 대한 압축강도 및 미세구조에 미치는 영향을 분석하였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2017년도 추계 학술논문 발표대회
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• pp.225-226
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• 2017

Recently, there has been a growing interest in the development of non-sintered binder to reduce CO2 emissions from the cement clinker manufacturing process and a number of studies have been conducted on fly ashes as an industrial by-product. However, in order to utilize fly ashes as a non-sintered binder, it is necessary to solve problems such as safety issues and economical efficiency due to use of an alkali activator. This study evaluates the material properties and compressive strength characteristics of three types of circulating fluidized bed boiler ashes. As a result, it was confirmed that the characteristics of each binder vary depending on the location of the power plant and the types of raw materials. In addition, it has been confirmed that the fluidized bed boiler ash shows a high compressive strength and can be used sufficiently as an non-sintered binder.

• 한국환경과학회지
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• 제15권6호
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• pp.587-592
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• 2006

The advantage of CFBC(Circulating fluidized bed combustor) is that it can apply to various fuel sources including the lower rank fuel and remove SOx by means of direct supply of limestone to the combustor without additional desulfation facility. In this paper, we denote characteristics of fly and bed ash to reuse finer limestone usually abandoned(used spec[Coarse LS] 0.1mm under 25%, new spec[Fine LS] 0.1mm under 50%). According to the results, the chemical composition of fly ash was as follows; $SiO_2\;40.8%,\;Al_2O_3\;31.9%,\;CaO\;10.7%,\;K_2O\;4.46%$ in the case of coarse limestone and $SiO_2\;41.1%,\;Al_2O_3\;31.3%,\;CaO\;10.9%,\;K_2O\;4.66%$ in the case of fine limestone. The chemical composition of bed ash was as follows; $SiO_2\;54.2%,\;Al_2O_3\;33.1%,\;CaO\;1.56%,\;K_2O\;4.34%$ in the case of coarse limestone and $SiO_2\;53.8%,\;Al_2O_3\;32.6%,\;CaO\;2.21%,\;K_2O\;4.45%$ in the case of fine limestone. It showed that there was no significant change in chemical composition. And it is conformed that there was no significant change in particle size and shapes.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 봄 학술논문 발표대회
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• pp.185-186
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• 2020

This study In order to reduce the amount of cement that generates a large amount of carbon dioxide and attempts to find a recycling method to solve environmental problems by using biomass fly ash. Experiments were conducted according to replacement ratio of biomass fly ash based on GGBFS, The test items are flowability, air content, unit volume weight, water absorption, flexural strength and compressive strength. As a result of the experiment, as increased replacement ratio of biomass fly ash, the flowability and air content was increased. As increased replacement ratio, the density was decreased and water absorption was increased. The compressive strength tended to decrease as increased replacement ratio. The flexural strength tended to increased as increased replacement ratio.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권6호
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• pp.475-482
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• 1999

The electrostatic precipitation characteristics of two kinds of fly ashes, one derived from a fluidized bed combustor(FBC), the other from a pulverized coal(PC) fired furnace, have been studied on a pilot plant. Experiments have been carried out to enhance the collection efficiency while changing the operating conditions for two kinds of coal ashes, respectively. It has been shown that collection efficiency is affected by many factors such as shape of the ashes, dust contents, humidity, and temperature, etc. Experimantal results showed that collection efficiency of the FBC ashes was higher than that of the PC fly ash in spite of the small size of the FBC ashes. The experimetal results have been applied to the collection efficiency equations to show that the modified Deutsch equation was well agreed with experiment results if modification parameter k was set to 0.6 for the fluidized bed fly ashes and to 0.43 for the pulverized coal fly ashes.

• 한국지반환경공학회 논문집
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• 제17권12호
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• pp.17-26
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• 2016

본 연구에서는 등급 외 플라이애쉬 중 산화칼슘 함량이 높은 플라이애쉬를 저강도 유동화 채움재(controlled low strength material, CLSM)의 바인더로써 활용 가능성을 알아보았다. 사용된 플라이애쉬는 상대적으로 산화칼슘 함량이 높은 플라이애쉬를 배출하는 유동층형 보일러(circulating fluidized bed combustion boiler, CFBC)에서 시료를 채집하여 사용하였다. 배합한 시료의 유동성, 일축압축강도, 단위중량 등을 파악하여 CLSM 시료의 공학적 특징을 알아보았으며, 미세구조관찰과 X선 회절분석을 통한 CLSM 시료의 경화 메커니즘을 파악하였다. 실험 수행 결과 유동성을 만족하는 함수비는 42에서 85%의 범위를 보였으며, 유동성 시험 결과 골재의 종류와 관계없이 골재율이 증가함에 따라 유동성이 증가하는 것으로 나타났다. 일축압축강도는 0.3MPa에서 1.9MPa의 분포를 보였다. 규사를 골재로 사용한 경우 골재율이 증가함에 따라 일축압축강도는 증가하였으나, 바텀애쉬를 골재로 사용한 경우 골재율이 증가함에 따라 일축압축강도는 감소하였다. 미세구조관찰 결과와 X선 회절분석을 통해 CLSM 시료는 고분자 중합반응과 시멘트 수화반응을 통해 강도를 발현하는 것으로 확인하였다. 본 연구의 결과로부터 산화칼슘 함량이 높은 플라이애쉬의 자체 경화성을 이용하여 저강도 유동화 채움재로써 활용이 가능하다고 판단된다.

• 한국연소학회지
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• 제8권2호
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• pp.34-40
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• 2003

Analyses for concentration, surface phenomena, and crystal structure were performed to identify the causes of clinker formation in three type of pulverized coal fired boilers. Some clinkers had partially molten surface and more CaO and $Fe_2O_3$ as compared with fly ash, and the major crystalline phases identified in the clinker were mullite and quartz. Clinkers were formed in high temperature zone of the boiler according to the identification of mullite by XRD. Free $SiO_2$ in sand combined with K, Na and Ca in limestone served as a fluxing agent to form clinkers in a circulating bed boiler.