• 한국세라믹학회지
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• 제34권12호
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• pp.1261-1267
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• 1997

Four kids of powder admixtures(A, B, C, D) based on anhydrite were manufactured by mixing at a fixed rate of II-anhydrite, fly ash and active silica as an industrial by-product. Fluidity properties of cement paste such as mini-slump, apparent viscosity with elapsed time, as well as setting time of cement pastes of these admixtures substituted up to 11wt% of cement were compared to those of cement paste(SS) substisuted by marketed high-strength powder admixture(S). Among these powder admixtures, the fluidity of cement pastes(PA, PC) substituted by A and C powder admixtures manufactured from II-anhydrite and fly ash had an excellent property than that of cement paste substituted by marketed powder admixture and also a good fluidity-retention effect with elapsed time by adding of superplasticizer. The setting time of cement paste substituted by powder admixtures based on anhydrite slightly retarded than that of cement paste substituted by marketed powder admixture.

• 한국세라믹학회지
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• 제51권6호
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• pp.584-590
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• 2014

Air-cooled slag showed grindability approximately twice as good as that of water-cooled slag. While the studied water-cooled slag was composed of glass as constituent mineral, the air-cooled slag was mainly composed of melilite. It is assumed that the sulfur in air-cooled slag is mainly in the form of CaS, which is oxidized into $CaS_2O_3$ when in contact with air. $CaS_2O_3$, then, is released mainly as $S_2O{_3}^{2-}$ion when in contact with water. However, the sulfur in water-cooled slag functioned as a constituent of the glass structure, so the$S_2O{_3}^{2-}$ ion was not released even when in contact with water. When no chemical admixture was added, the blended cement of air-cooled slag showed higher fluidity and retention effect than those of the blended cement of the water-cooled slag. It seems that these discrepancies are caused by the initial hydration inhibition effect of cement by the $S_2O{_3}^{2-}$ ion of air-cooled slag. When a superplasticizer is added, the air-cooled slag used more superplasticizer than did the blast furnace slag for the same flow because the air-cooled slag had higher specific surface area due to the presence of micro-pores. Meanwhile, the blended cement of the air-cooled slag showed a greater fluidity retention effect than that of the blended cement of the water-cooled slag. This may be a combined effect of the increased use of superplasticizer and the presence of released $S_2O{_3}^{2-}$ ion; however, further, more detailed studies will need to be conducted.

• Advances in concrete construction
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• 제6권6호
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• pp.561-583
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• 2018

A variety of polycarboxylate ether (PCE)-based superplasticizers are commercially available. Their influence on the rheological retention and slump loss in respect of concrete differ considerably. Fluidity and slump loss are the cardinal features responsible for the quality of concrete. These are related to the dispersion of cement particles and the hydration process which are greatly influenced by type of polycarboxylate ether (PCE)-based superplasticizers. On the backdrop of relatively less studies in the context of rheological retention of high strength self-consolidating concrete (HS-SCC), the experimental investigations were carried out aiming at quantifying the effect of the six different PCE polymers (PCE 1-6) on the rheological retention of HS-SCC mixes containing two types of Ordinary Portland Cements (OPC) and unwashed crushed sand as the fine aggregate. The tests that were carried out included $T_{500}$, V-Funnel, yield stress and viscosity retention tests. The supplementary cementitious materials such as fly ash (FA) and micro-silica (MS) were also used in ternary blend keeping the mix paste volume and flow of concrete constant. Low water to binder ratio was used. The results reveal that not only the PCEs of different polymer groups behave differently, but even the PCEs of same polymer groups also behave differently. The study also indicates that the HS-SCC mixes containing PCE 6 and PCE 5 performed better as compared to the mixes containing PCE 1, PCE 2, PCE 3 and PCE 4 in respect of all the rheological tests. The PCE 6 is a new class of chemical admixtures known as Polyaryl Ether (PAE) developed by BASF to provide better rheological properties in even in HS-SCC mixes at low water to binder mix. In the present study, the PCE 6, is found to help not only in reduction in the plastic viscosity and yield stress, but also provide good rheological retention over the period of 180 minutes. Further, the early compressive strength properties (one day compressive strength) highly depend on the type of PCE polymer. The side chain length of PCE polymer and the fineness of the cement considerably affect the early strength gain.

• 지능정보연구
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• 제21권2호
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• pp.19-47
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• 2015

오늘날의 지식기반경제에서 핵심적인 역할을 수행하고 있는 가상 커뮤니티의 성공을 위해 턴오버(turnover)는 매우 중요한 의미를 가지고 있다. 그런데, 이에 대한 연구는 많이 부족한 실정이다. 우선, 턴오버를 측정하는 방법부터가 명확하지 않다. 가상 커뮤니티에서 새로운 구성원의 유입은 비교적 확실하게 인지할 수 있지만, 탈퇴는 명시적으로 탈퇴 처리를 하는 사람들이 드물고 재방문 가능성이 상존하기 때문에 구별하기가 쉽지 않다. 그리고, 특정기간 동안 임의의 구성원이 해당 커뮤니티를 위해 활동하고 있는 진정한 구성원인지를 판단하는 방식이 분명하지 않아 전통적인 조직의 턴오버 공식을 그대로 적용하기 힘든 면이 있다. 본 연구에서는 이러한 한계점과 가상 커뮤니티 구성원의 행위 패턴을 고려하여, 일차적으로 턴오버를 포함한 가상 커뮤니티 구성원의 유동성(fluidity) 관련 척도들을 도출하고, 이를 토대로 유동성과 가상 협업 성과의 관계를 작업의 전문적인 특성을 반영하여 분석하였다. 요컨대, 대표적인 지식 협업 커뮤니티인 영어 위키피디아의 2,978개 피쳐드 아티클(featured article)에 대한 지식 협업 행위로부터 다음과 같은 결과를 얻었다. 첫째, 협업 효율성에 대한 턴오버의 관계는 오른쪽 부분이 짧은 U자 형태를 보이며, 똑같은 턴오버율에 대해 보다 학문적인 아티클을 완성하는 것이 더 오래 걸리고, 이 차이는 턴오버율이 증가함에 따라 감소한다. 둘째, 협업효율성에 대한 재방문기간의 관계는 왼쪽 부분이 짧은 U자 형태의 관계를 가지며, 전문적이지 않은 작업일수록 재방문기간의 일단위 변화에 대한 협업 효율성의 변화가 크다. 그리고, 똑같은 재방문기간에 대해 보다 학문적인 아티클을 완성하는 것이 더 오래 걸리며, 이 차이는 재방문기간이 평균이상으로 증가함에 따라 더욱 커진다. 셋째, 협업효율성에 대한 월(month)별 유입 신규 구성원 수의 관계는 왼쪽 부분이 짧은 역 U자 관계를 가지며, 이 관계에 대한 작업 특성의 영향은 유의하지 않은 것으로 보인다.