• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.37 no.1 s.109
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• pp.10-16
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• 2005

Flocculation of fibers and its distribution in paper are related to flocculation mechanisms, retention and drainage. Relationship between flocculation mechanisms and physical properties of paper has not been fully studied. In this study, flocculation of fibers was investigated by changing cationic polymers for flocculation mechanism analysis. Flocculation of stock and physical strength of paper were similar when using branched PAM and linear PAM with fillers and microparticles Flocculation and physical strength were also similar when using branched PAM and linear PAM and microparticles without fillers. In that case excessive flocculation was not produced, so formation was improved but physical strength was decreased. When using branched PAM instead of linear PAM with filler addition, drainage time was decreased, air permeability was improved, and physical strength was increased.

• Journal of Korean Society on Water Environment
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• v.36 no.3
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• pp.185-193
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• 2020

Bimodal flocculation describes the aggregation and breakage processes of the flocculi (or primary particles) and the flocs in the water environment. Bimodal flocculation causes bimodal size distribution with the two separate peaks of the flocculi and the flocs. Extracellular polymeric substances and ionic species common in the water environment increase the occurrence of bimodal flocculation and flocculi-floc size distribution, under the flocculation mechanisms of electrostatic attraction and polymeric bridging. This study investigated bimodal flocculation and flocculi-floc size distribution, with respect to the extracellular polymeric substance concentration and ionic strength in the kaolinite-containing suspension. The batch flocculation tests comprising 0.12 g/L of kaolinite showed that the highest flocculation potential occurred at the lowest xanthan gum (as extracellular polymeric substances) concentration, under all the ionic strengths of 0.001, 0.01, and 0.1 M NaCl. Also, it was important to note that the higher ionic strength resulted in the higher flocculation potential, at all the xanthan gum concentrations. The bimodal flocculation and flocculi-floc size distribution became apparent in the experimental conditions, which had low and intermediate flocculation potential. Besides the polymeric bridging flocculation, steric stabilization increased the flocculi mass fraction against the floc mass fraction, thereby developing the bimodal size distribution.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.427-431
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• 2006

Formation which is one of the most fundamental characteristic of paper quality is affected by a number of variables. Fiber flocculation in the headbox has been recognized as the most important variable influencing formation. Consistency and crowding number of headbox stock are known to represent the flocculation potential of stocks. The effects of consistency and crowding number on paper formation were studied by measuring the flocculation of fiber suspensions. Increasing consistency increased the degree of fiber flocculation. Especially the consistency of long fiber fraction was the most crucial factor of flocculation. Tensile strength of handsheets was furnish dependent rather than flocculation dependent. Crowding number of a furnish can be used for the characterization of stock flocculation.

• Journal of Korean Society on Water Environment
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• v.21 no.3
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• pp.230-235
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• 2005

The main purpose of the flocculation process is to make flocs bigger to be removed easily in the following processes. The flow pattern and mixing intensity have a great influence on flocculation. In this study, the flow pattern was examined by a hydraulic tracer-test, where 3 water treatment plants having $800,000m^3/d$, $44,000m^3/d$ and $40,000m^3/d$ were employed. Also, the settling test was conducted to find out the relationship between the mixing intensity and the settling ability of flocs. The hydraulic tracer-test was conducted for the various flocculation processes that have different structures of flocculation basins. In the result, the retention time distribution (RTD) curves for the flocculation processes were quite different. In case of the inappropriate structure of the flocculation basin, the flow is not even so that the floc does not grow enough. To find out the relationship between mixing intensity and settleability of flocs, G-values were calculated and the settling test was conducted for two flocculation basins which have the same conditions except the G-value. For the flocculation basin with uneven G-value, the floc settleability was revealed poor. On the other hand, the flocculation basin with even G-value, the settleability was better than the previous one. From these experimental results, it is confirmed that the flow pattern is closely related to the structure of the flocculation basin and the settleability is affected by mixing intensity. Therefore the flow pattern and the strength of the mixing intensity should be examined sufficiently to design and operate flocculation basin.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.39 no.5
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• pp.1-6
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• 2007

Formation which is one of the most fundamental characteristic of paper quality is affected by a number of variables. Fiber flocculation in the headbox has been recognized as the most important variable influencing formation. Consistency and crowding number of head box stock are known to represent the flocculation potential of stocks. The effects of consistency and crowding number on paper formation were studied by measuring the flocculation of fiber suspensions. Increasing consistency increased the degree of fiber flocculation. Especially the consistency of long fiber fraction was the most crucial factor of flocculation. Tensile strength of handsheets was furnish dependent rather than flocculation dependent. Crowding number of a furnish can be used for the characterization of stock flocculation.

• Journal of Environmental Science International
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• v.14 no.8
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• pp.723-737
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• 2005

The effects of pH (5, 7 and 9) and ionic strength of different salts on the flocculation characteristics of humic acid by inorganic (alum, polyaluminum chloride (PAC) with degree of neutralization, r=(OH/Al) of 1.7) and organic (cationic polyelectrolyte) coagulants, have been examined using a simple continuous optical technique, coupled with measurements of zeta potential. The results are compared mainly by the mechanisms of its destabilization and subsequent removal. The destabilization and subsequent removal of humic acid by PAC and cationic polyelectrolyte occur by a simple charge neutralization, regardless of pH of the solution. However, the mechanism of those by alum is greatly dependent on pH and coagulant dosage, i.e., both mechanisms of charge neutralization at lower dosages and sweep flocculation at higher dosages at pH 5, by sweep flocculation mechanism at pH 7, and little flocculation because of electrostatic repulsion between negatively charged humic acid and aluminum species at pH 9. The ionic strength also affects those greatly, mainly based on the charge of salts, and so is more evident for the salts of highly charged cationic species, such as $CaCl_2$ and $MgCI_2.$ However, it is found that the salts have no effect on those at the optimum dosage for alum acting by the mechanism of sweep flocculation at pH 7, regardless of their charge.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.36 no.4 s.107
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• pp.25-32
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• 2004

Flocculation of fibers and its distribution in paper are related to flocculation mechanisms, retention and drainage. Relationship between flocculation mechanisms and physical properties of paper has not been fully studied. In this study, flocculation of fibers was investigated by changing microparticles for flocculation mechanism analysis. When fillers were not added, formation and strength were deteriorated by 100, 300, or 500 ppm of linear PAM (all L-PAM), All L-PAM + 1200 ppm inorganic microparticle (1200-IM), all L-PAM + 120 ppm organic microparticle (120-OM), all L-PAM + 1200 ppm organic microparticle (1200-OM) because of too much flocculation. When 5, 15, $25\%$ (od.w/w) fillers were added, retention and drainage process were not affected by the extent flocculation when 500 ppm L - PAM, 500 ppm L - PAM + 1200- IM, and 500 ppm L - PAM + 120 ppm OM were added.

• Korean Chemical Engineering Research
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• v.55 no.1
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• pp.1-6
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• 2017

More addition of calcium carbonate in printing paper allows savings of the wood fibers and the drying energy. Pre-flocculation of GCC (ground calcium carbonate) using functional polymers was known as the best available technology to make high loaded paper until now, and it allowed less reduction of the paper essential properties such as tensile strength and smoothness at higher GCC content. However, pre-flocculated GCC became unstable in size under the continued agitation in the mill. Therefore, pre-flocculation method was modified in such a way that the in-situ calcium carbonate was formed between the GCC particles of the pre-flocculated GCC, and the resultant became more stable in size, which we named as HCC (hybrid calcium carbonate). HCC turned out to make high tensile strength and smoothness as much as the pre-flocculated GCC and gave much better size stability against stirring. Furthermore, HCC gave high bulk that pre-flocculation could not make.

• Journal of Korea Water Resources Association
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• v.50 no.11
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• pp.715-723
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• 2017

Extracellular Polymeric Substances (EPS) in the water environment assemble fine, colloidal particles, such as clays, microorganisms and biomass, in large flocs, which are eventually subject to sedimentation and deposition and determine water/sediment quality and quantity. This study hence aimed to investigate the way that water and colloidal chemistry affects EPS-mediated flocculation of colloidal particles, using a jar-test experiment. Especially, ionic strength, divalent cation and humic substances concentrations were selected as experimental variables in the jar-test experiments, to elucidate their effects on EPS-mediated flocculation. A higher ionic strength increased flocculation capability, reducing electrostatic repulsion between EPS-attached colloidal particles and enhancing particle aggregation. 0.1 M NaCl ionic strength had higher flocculation capability, with 3 times larger floc size and 2.5 times lower suspended solid concentration, than 0.001 M NaCl. Divalent cations, such as $Ca^{2+}$, built divalent cationic bridges between colloidal particles and EPS (i.e., $colloid-Ca^{2+}-EPS$ or $EPS-Ca^{2+}-EPS$) and hence made colloidal particles to build into large, settelable flocs. A small $Ca^{2+}$ concentration enhanced flocculation capability, reducing suspended solid concentration 20 times lower than the initial dosed concentration. However, humic substances, adsorbed on colloidal particles, reduced flocculation, because they blocked EPS adsorption on colloidal particles and increased negative charges and electrostatic repulsion of colloidal particles. Suspended solid concentration in the tests with humic substances remained as high as the initial dosed concentration, indicating stabilization rather than flocculation. Findings about EPS-mediated flocculation in this research will be used for better understanding the fate and transport of colloidal particles in the water environment and for developing the best management practices for water/sediment quality.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.3
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• pp.44-51
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• 2001

Sedimentation characteristics such as SS, $BOD_5$, COD removal efficiency of waste water in the toilet paper mill using milk carton were examined. Optimum dosage of coagulant, rapid mixing time and slow mixing time were determined by turbidity, SS, COD, $BOD_5$ and then equation for treatment efficiency was suggested. Mechanical strength of floc was determined by turbidity. For the coagulant, polyacrylamide (PAM) is more efficient for removing pollution than the aluminium sulfate. Effective mixing ratios of PAM and aluminum sulfate to remove pollution are 70:30 and 30:70. The lowest turbidity was showed when rapid mixing at 300 rpm after coagulant injection was applied. That which indicates the highest point of flocs mechanical strength.