• Environmental Engineering Research
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• 제11권4호
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• pp.208-216
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• 2006

In order to create a single flocculant/dual flocculation system, polyacrylamide-co-trimethyl ammonium ethyl acrylate chloride (TAEAC) polymers with varying molecular weights and structures were prepared for use of flocculants. The higher the cationic density of the polymer is higher, the higher was the conversion rate and the ratio of monomer. An acrylamide as nonionic monomer was less reactive than a TAEAC as cationic monomer. The branched polymer which was polymerized with a cross-linking agent, N, N-methylene bis-acrylamide had a higher stability and higher viscosity than a linear polymer but its dewatering efficiency was poor in a single flocculation system. In the case of single flocculant/dual flocculation, the branched polymer has better flocculation efficiency and the water content of the dewatered cakes was lower than the others, as the result of a re-flocculation effect. The optimum conditions for dual flocculation are a sequence in which the $1^{st}$ and $2^{nd}$ dosage are 75% and 25%/total dosage of a single flocculation system. The dewatering efficiency of a dual flocculation system is improved considerably from 10 to 25% under the experimental conditions used herein.

• 상하수도학회지
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• 제20권2호
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• pp.245-255
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• 2006

Dissolved air flotation is a solid-liquid separation system that uses fine bubbles rising from bottom to remove particles in water. In order to enhance the flotation velocity and removal efficiency of flocs in the flotation process, we tried to obtain pretreatment conditions for the optimum DAF process operation by comparing and evaluating features of actual floc formation and flotation velocity etc, according to coagulant types and conditions for flocculation mixing intensity by using PIA, PDA, and FSA. Accordingly, generating big flocs that have low density at low flocculation mixing intensity may reduce treatment efficiency. In addition, generating small flocs at high flocculation mixing intensity makes floc-bubbles smaller, which reduces flotation velocity, In this study, it was found that high flocculation mixing intensity could not remove the remaining micro-particles after flocculation, which had negative effects on treated water quality, Therefore, in order to enhance treatment efficiency in a flotation process, flocculation mixing intensity around $50sec^{-1}$ is effective.

• 한국물환경학회지
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• 제39권6호
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• pp.465-474
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• 2023

The chemical composition and molecular weight characteristics of dissolved organic matter (DOM) exert a profound influence on the efficiency of organic matter removal in water treatment systems, acting as efficiency predictive indicators. This research evaluated the primary chemical and molecular weight properties of DOM derived from diverse sources, including rivers, lakes, and biomasses, and assessed their relationship with the efficiency of coagulation/flocculation treatments. Dissolved organic carbon (DOC) removal efficiency through coagulation/flocculation exhibited significant correlations with DOM's hydrophobic distribution, the ratio of humic-like to protein-like fluorescence, and the molecular weight associated with humic substances (HS). These findings suggest that the DOC removal rate in coagulation/flocculation processes is enhanced by a higher presence of HS in DOM, an increased influence of externally sourced DOM, and more presence of high molecular weight compounds. The results of this study further posit that the efficacy of water treatment processes can be more accurately predicted when considering multiple DOM characteristics rather than relying on a singular trait. Based on major results from this study, a predictive model for DOC removal efficiency by coagulation/flocculation was formulated as: 24.3 - 7.83 × (fluorescence index) + 0.089 × (hydrophilic distribution) + 0.102 × (HS molecular weight). This proposed model, coupled with supplementary monitoring of influent organic matter, has the potential to enhance the design and predictive accuracy for coagulation/flocculation treatments targeting DOC removal in future applications.

• 상하수도학회지
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• 제20권6호
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• pp.789-797
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• 2006

This study was conducted to establish the refined model for prediction of flocculation/sedimentation efficiency in factual drinking water treatment plants using model tree technique. In order to carry out machine leaning for determining each linear model, five parameters; time, coagulant dose, raw water turbidity, SCD and conductivity, which were measured and collected from the field (K_DWTP), were selected and used. The existing analytical models developed by previous researchers were used only to examine closely the mechanism of flocculation rather than to apply it for practical purpose. The refined model established using model tree technique in this study could predict the factual sedimentation efficiency accurately (below 9% of average absolute error). Also, in aspect of engineering convenience, without any additional manipulation of parameters, it can be applied to practical works.

• 펄프종이기술
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• 제33권1호
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• pp.16-23
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• 2001

Hydraulic transport of fines up to the surface of flotation cell was supposed to be a mechanism of fines fractionation through the froth-flotation. Efficient fractionation of fines means efficient skimming out of flotation rejects as much as possible with least long fiber loss. The selectivity of fines fractionation was found to be mainly affected by long fibers flocculation degree in this study. Lack of sufficient flocculation of long fibers could lead to extensive loss of long fibers. It was also found that higher flotation flux caused higher flotation reject as well as the increase of long fiber loss, but did not affect the fine content ratio in the flotation reject. We controlled the flotation flux and the stock consistency, and chose a cationic polymer to maximize the flocculation of long fibers and to increase the amount of flotation reject. The highest efficiency of fines fractionation was obtained at 1.3% of stock consistency and at 100L/min of flotation flux in our experimental set up. The cationaic polymer we chose was found to be very effective in fiber flocculation and flotation froth stabilization. New definitions of fractionation efficiency were introduced in this study to compare the results more clearly.

• 환경위생공학
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• 제10권2호
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• pp.30-35
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• 1995

In this research effect of physicochemical parameter on flocculation using PASS-100 were evaluated. pEt flocculant dosage, mixing intensity and detention time were adopted as experimental variables. The physicochemical parameter( p% mixing intensity and mixing time ) were important Parameter on flocculation performance. Effluent pH range for effective flocculation was 4.5-7. Optimum Gt$_{d}$ range was 20,000-30,000 and its range similar to alum flucculation. Rapid mixing was very important parameter to floe formation in PASS- 100 flocculation. Whereas, slow mixing did not affect to the removal efficiency at settling time for 30minute or more.

• 한국물환경학회지
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• 제21권3호
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• pp.230-235
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• 2005

The main purpose of the flocculation process is to make flocs bigger to be removed easily in the following processes. The flow pattern and mixing intensity have a great influence on flocculation. In this study, the flow pattern was examined by a hydraulic tracer-test, where 3 water treatment plants having $800,000m^3/d$, $44,000m^3/d$ and $40,000m^3/d$ were employed. Also, the settling test was conducted to find out the relationship between the mixing intensity and the settling ability of flocs. The hydraulic tracer-test was conducted for the various flocculation processes that have different structures of flocculation basins. In the result, the retention time distribution (RTD) curves for the flocculation processes were quite different. In case of the inappropriate structure of the flocculation basin, the flow is not even so that the floc does not grow enough. To find out the relationship between mixing intensity and settleability of flocs, G-values were calculated and the settling test was conducted for two flocculation basins which have the same conditions except the G-value. For the flocculation basin with uneven G-value, the floc settleability was revealed poor. On the other hand, the flocculation basin with even G-value, the settleability was better than the previous one. From these experimental results, it is confirmed that the flow pattern is closely related to the structure of the flocculation basin and the settleability is affected by mixing intensity. Therefore the flow pattern and the strength of the mixing intensity should be examined sufficiently to design and operate flocculation basin.

• 한국환경기술학회지
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• 제19권6호
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• pp.563-569
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• 2018

본 연구에서는 영양염류 및 응집을 중심으로 미세조류를 이용한 폐수처리 효율에 관한 연구를 수행하였다. 미세조류 배양을 통한 폐수의 영양염류 저감의 가능성을 확인하기 위하여 미세조류의 배양에 따른 인 및 질소의 제거율을 관찰한 결과, 각각 약 92 % 및 99 % 이상의 제거율을 보였다. 효율적인 미세조류의 회수를 위하여 Auto-flocculation 조건 및 다양한 첨가물에 따른 응집실험을 진행한 결과, 응집제인 PAC(Poly Aluminum Chloride) 및 $FeCl_3$를 첨가한 경우에 각각 평균 94 % 및 92 %의 높은 응집율을 보였다. 또한, 최소한의 농도로 90 % 이상의 응집율을 보이는 최적의 조건을 찾기 위하여 응집제별 최적농도 산출 실험을 진행하였으며, 그 결과 PAC는 30 mg/L, $FeCl_3$는 40 mg/L가 최적의 농도임을 확인하였다.

• 펄프종이기술
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• 제40권4호
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• pp.10-15
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• 2008

Flocculation phenomena of the stock mixed with cellulosic fibers, fillers and polymers were investigated by a new turbidity measurement system consisted of a probe-type turbidimeter, data acquisition system and computer. The probe-type turbidimeter allowed to measure the real time flocculation of the stock induced by single polymer and microparticle systems. Flocculation phenomena were evaluated by average and final relative turbidity indices. Turbidity and flocculation showed inverse relationship, i.e. the turbidity decreased with the formation of flocs. Relative turbidity of the stock treated with microparticle system was lower than that of the stock containing single polymer system, which indicated that the microparticle system showed greater floc forming efficiency than single polymer system.

• 상하수도학회지
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• 제35권1호
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• pp.63-69
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• 2021

Microalgae are primary producers of aquatic ecosystems, securing biodiversity and health of the ecosystem and contributing to reducing the impact of climate change through carbon dioxide fixation. Also, they are useful biomass that can be used as biological resources for producing valuable industrial products. However, harvesting process, which is the separation of microalgal biomass from mixed liquor, is an important bottleneck in use of valorization of microalgae as a bioresource accounting for 20 to 30% of the total production cost. This study investigates the applicability of sewage sludge-derived extracellular polymeric substance (EPS) as bioflucculant for harvesting microalgae. We compared the flocculation characteristics of microalgae using EPSs extracted from sewage sludge by three methods. The flocculation efficiency of microalgae is closely related to the carbohydrate and protein concentrations of EPS. Heat-extracted EPS contains the highest carbohydrate and protein concentrations and can be a best-suited bioflocculant for microalgae recovery with 87.2% flocculation efficiency. Injection of bioflocculant improved the flocculation efficiency of all three different algal strains, Chlorella Vulgaris, Chlamydomonas Asymmetrica, Scenedesmus sp., however the improvement was more significant when it was used for flocculation of Chlamydomonas Asymmetrica with flagella.