• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.3
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• pp.9-17
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• 2001

The floc characteristics of base paper stock for coating by the retention aid system consisting of polyacrylamide (high molecular weight low charge density, HMLC) and PEI without and with anionic inorganic oxide (IO) were investigated under various shear conditions of MDDA (modified dynamic drainage analyzer). The floc size was increased with cationic electrolytes dosage whatever inorganic oxide is applied or not. The effect of inorganic oxide on the floc size showed the different result between PAM and PEI. The smaller floc was obtained by PAM without inorganic oxide, but larger floc was obtained by PAM with inorganic oxide. However, the effect of shear force was not observed. Floc formation index was decreased by the addition of cationic electrolytes with or without inorganic oxide. Floc formation index had better correlation format formation index than floc size. The relationships between wet web permeability and mat air permeability showed the significant linear correlation ($R^2$=0.97~0.98) for HML PAM and PEI. Floc formation index gave more useful information than the retention measurement when the performance of retention aids is evaluated at the laboratory before applying at the paper mill.

• Journal of Environmental Science International
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• v.23 no.4
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• pp.715-722
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• 2014

Effects of coagulation types on flocculation were investigated by using a photometric dispersion analyzer (PDA) as an on-line monitoring technique in this study. Nakdong River water were used and alum and ferric chloride were used as coagulants. The aim of this study is to compare the coagulation characteristics of alum and ferric chloride by a photometric dispersion analyzer (PDA). Floc growing rates ($R_v$) in three different water temperatures ($4^{\circ}C$, $16^{\circ}C$ and $30^{\circ}C$) and coagulants doses (0.15 mM, 0.20 mM and 0.25 mM as Al, Fe) were measured. The floc growing rate ($R_v$) by alum was 1.8~2.8 times higher than that of ferric chloride during rapid mixing period, however, for 0.15 mM~0.25 mM coagulant doses the floc growing rate ($R_v$) by ferric chloride was 1.1~2.3 times higher than that of alum in the slow mixing period at $16^{\circ}C$ water temperature. Reasonable coagulant doses of alum and ferric chloride for turbidity removal were 0.1 mM (as Al) and 0.2 mM (as Fe), respectively, and the removal efficiency of those coagulant doses showed 94% for alum and 97% for ferric chloride. The appropriate coagulant dose of alum and ferric chloride for removing dissolved organic carbon (DOC) showed about 0.3 mM (as Al, Fe) and at this dosage, DOC removal efficiencies were 36% and 44%, and ferric chloride was superior to the alum for removal of the DOC in water.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.4
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• pp.397-406
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• 2009

This study was conducted to monitor the floc sizes forming in the mixing zone in the water treatment plant. The dosing amount of poly aluminium chloride(PAC) was determined by particle dispersion analyzer(iPDA) in the lab and field scale test. During a field test period, PAC coagulant was used and the raw water was taken from Nakdong river. PAC wad diluted to activate the coagulant, leading to bring the more homogeneous dispersion in the shorter time. To monitor the floc sizes, the unit of floc size index(FSI) was used. With increasing of raw water turbidity, FSI value was increased. Also, the increased dosing amount of PAC brought the increased FSI and with overdosing of coagulant was in turn decreased. When the PAC was fed into the raw water after dilution in a field scale test, the width of FSI was narrower compared with the feeding of the mother liquor of PAC, implying that the formed flocs are denser and more uniform sizes. The width of FSI in average was varied on depending on the basicity of coagulant. Also, dF value, fractal dimension was evalued with the different coagulants, showing from 2.01 to 2.03. On-line floc monitor was effective for the optimal dosing in the drinking water plant.

• Nuclear Engineering and Technology
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• v.51 no.3
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• pp.738-745
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• 2019

Coprecipitation using hydrous ferric oxide (HFO) has been effectively used for the removal of radionuclides from radioactive wastewater. This work studied the dynamic behavior of HFO floc formation during the neutralization of acidic ferric iron in the presence of several radionuclides by using a photometric dispersion analyzer (PDA). Then the coagulation-flocculation system using HFO-anionic poly acrylamide (PAM) composite floc system was evaluated and compared in seawater and distilled water to find the effective condition to remove the target nuclides (Co-60, Mn-54, Sb-125, and Ru-106) present in wastewater generated in the severe accident of nuclear power plant like Fukushima Daiichi case. A ferric iron dosage of 10 ppm for the formation of HFO was suitable in terms of fast formation of HFO flocs without induction time, and maximum total removal yield of radioactivity from the wastewater. The settling time of HFO flocs was reduced by changing them to HFO-PAM composite floc. The optimal dosage of anionic PAM for HFO-anionic PAM floc system was approximately 1-10 ppm. The total removal yield of Mn-54, Co-60, Sb-125, Ru-106 radionuclides by the HFO-anionic PAM coagulation-flocculation system was higher in distilled water than in seawater and was more than 99%.

• Journal of Environmental Science International
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• v.25 no.2
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• pp.231-238
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• 2016

In this study, we have investigated to find optimal pre-treatment flocculation condition by analyzing the floc growth rate with mixing conditions and the membrane permeation flux for pre-treatment step of the membrane process. The higher mixing intensity showed a constant floc size index (FSI) values, and lower mixing intensity increased the degree of dispersion of the FSI values. Results of comparing the distribution characteristics of the FSI value and the permeation flux were more effective in increasing flux when the FSI values were 0.2 or higher. The degree of dispersion of FSI was relatively large in 40 rpm mixing condition compared to 120 rpm. In 40 rpm mixing condition, it decreased the permeation flux compared to 120 rpm because various sizes of flocs were distributed. Coagulation-UF membrane process enhanced 30%~40% of the flux rate compare to UF alone process, and the coagulation-MF process increased up to 5% of the flux rate compare to MF alone process. Pre-treatment, that is, coagulation process, has been found to be less effects on relatively larger pore size for MF membrane. For UF membrane, the flux was a little bit same when applying only the rapid mixing process or rapid mixing with slow mixing processes together. In case of MF membrane, the flux was improved when rapid mixing process applied with slow mixing process together.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.1
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• pp.92-97
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• 2005

This research is to investigate the effect of the dual coagulant using inorganic coagulants($AICl3{\cdot}6H2O$) and polymer on the coagulant process. Jar-test was conducted by using Kaolin injected raw water. PDA(Photometric Dispersion Analyzer) equipment in order to analyze the size of the particles and the characteristics of the shapes. The change in the rate of sample ores' residual deposited after coagulants were also compared. According to the result derived from this experiment, the concentration of inorganic coagulant reduced 50% and the residual was lower by using dual coagulants compared to using single coagulant. However the dual coagulant required sufficient mixing time, and affected particle characteristics, with the effect of the injection order of coagulants, the simultaneous injection of inorganic coagulant and polymer showed the most effective in the particle removal.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.4
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• pp.263-271
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• 2009

This study evaluated the flocs forming characteristics in the mixing zone to increase the coagulation effect in the drinking water plant. As a measuring tool of formed flocs, on-line particle dispersion analyzer (iPDA) was used in Y drinking water plant. To evaluate the forming flocs, many parameters such as poly amine, coagulant dosing amount, raw water turbidity, and pH was applied in this study. During the periods of field test, poly aluminium chloride (PACl) as a coagulant was used. With the increase of the raw water turbidities, poly amine was also added as one of aids for increasing in coagulation efficiency. The turbidity and pH of raw water was ranged from 7 to 9 and from 25 to 140 NTU, respectively. The increasing of raw water turbidity brought the bigger floc sizes accordingly. From a regression analysis, $R^2$ value was 0.8040 as a function of T, raw water turbidity. Floc size index (FSI) was obtained from a correlation equation as follows; FSI = 0.9388logT - 0.3214 Also, polyamine gave the bigger flocs the moment it is added to the coagulated water in the rapid mixing zone. One of parameters influencing the floc sizes was the addition of powdered active carbon(PAC) in the mixing zone. In case of higher turbidity of raw water, $R^2$ value was 0.9050 in the parameters of [PACl] and [PAC]; FSI = $0.0407[T]^{0.324}[PACI]^{0.769}[PAC]^{0.178}$ On-line floc monitor was beneficial to evaluate the flocs sizes depending on the many parameters consisting raw water properties, bring the profitable basic data to control the mixing zone more effectively.

• Journal of the Korean Society for Marine Environment & Energy
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• v.19 no.4
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• pp.341-348
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• 2016

Micro-algae, one of the biological resources for alternative energy, has been heavily studied. Among various methods to analyze the status of the micro-algae including counting, screening, and flocculation, the flocculation approach has been widely accepted in many critical applications such as red tide removal study or microalgae resource study. To characterize the flocculation status of the micro-alga. A traditional optical modality, i.e., photospectrometry, measuring the optical density of the flocs has been frequently employed. While this traditional optical method needs shorter time than the counting method in flocculation status analysis, it has relatively lower detection accuracy. To address this issue, a novel real-time micro-algae flocculation analysis method based on the lens-free shadow imaging technique (LSIT) is introduced. Both single cell detection and floc detection are simultaneously available with a proposed lens-free shadow image, confirmed by comparing the results with optical microscope images. And three shadow parameters, e.g., number of flocs, effective area of flocs, and maximum size of floc, enabling quantification of the flocculation phenomenon of micro-alga, are firstly demonstrated in this article. The efficacy of each shadow parameter is verified with the real-time flocculation monitoring experiments using custom developed cohesive agents.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.3
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• pp.203-207
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• 2009

The concern of seriousness and harmful effects of environmental pollution is rising by the various water pollutions, appearances of new micro-noxious substances and increase of sustainable pollutants. The method is suggested that can effectively increase the removal of organic substances and several pollutants using a coagulation process. The experiment for characteristics of $ZrSiO_4$ (zirconium silicate) as a coagulation-aid was carried out for application to coagulation process with domestic wastewater and lake water, and the removal rate of the organic substances depending on a dosage was evaluated by PDA (Photometric Dispersion Analyzer) in this study. Zeta-potential of zirconium silicate solution was -32.22 mv at pH 7 and the lower negative(-) charge was detected in the more acidic conditions. Absorbance on $UV_{254}$ presented higher when zirconium silicate was added than in a domestic wastewater itself. Besides, the results by PDA experiment represented that injection of zirconium silicate could promote growing of floc. Tests for coagulation process were conducted by three ways which are pre-injection, co-injection and post-injection of zirconium silicate with alum. Accordingly, removal efficiency of organic substances increased over 15% in co-injection than in using of alum as a sole reagent. When a 20 mg/L of alum was used with a 10 mg/L of zirconium silicate, the removal efficiency was high up to 90%. Removal efficiency of $COD_{Cr}$ was improved more than 15% in case of dosage of coagulant either PAC (Poly aluminium chloride) or PACS (Poly aluminium chloride Silicate) together with zirconium silicate. As a result, the removal efficiency of $COD_{Cr}$ were 5~10% higher in a co-injection of zirconium silicate with a coagulant than a pre-injection and a post-injection but it of soluble substances was lower in a co-injection.