• 한국응용과학기술학회지
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• 제25권3호
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• pp.332-340
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• 2008

Two component polyurethane (PU) flame retardant coatings were prepared by blending trichloro modified polyesters (TCMPs) and isophorone diisocyanate isocyanurate. TCMPs were synthesized by polycondensation of trichlorobenzoic acid (TCBA), a flame retardant component, with adipic acid, 1,4 butanediol, and trimethylolpropane. The content of TCBA was varied in 10, 20, and 30 wt% for the reaction. Theses new flame retardant coatings showed various properties comparable to other non flame retardant coatings. Moreover, we carried out the combustion test and the flammability test for our flame retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TCBA were determined as no burn. The results of flammability test for the coatings with 20 wt% and 30 wt% of TCBA contents indicated the limiting oxygen index (LOI) values of 26% and 29% respectively, which implied relatively good flame retardancy.

• 한국염색가공학회지
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• 제32권2호
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• pp.103-110
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• 2020

Super engineering plastic(SEP) are applied to high performance and high value industries due to their excellent mechanical properties and high continuous operating temperature. Among them, PES and PEI are amorphous SEPs, and have the advantages of high flexibility, mechanical properties, transparency, and thermal stability. In this study, polyethersulfone(PES) and polyetherimide(PEI) fibers were manufactured to produce flame retardant artificial hair. PES and PEI fibers prepared through a melt-spinning process at a high temperature of 360 to 420℃. They are compared with commercial artificial hair by thermal gravimetric analysis(TGA), linear density, tenacity, and limited oxygen index(LOI) analysis. PES and PEI fibers have similar linear density and tenacity to commercial artificial hair, while their thermal stability and flame retardant are excellent. In particular, flame retardant was analyzed through LOI value and PES was 35.1%, which is superior to commercial artificial hair PET/Br(28.2%) and PET/P(20.2%). Therefore, PES and PEI are suitable as artificial hair for flame retardant.

• 한국응용과학기술학회지
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• 제20권2호
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• pp.110-117
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• 2003

Pyrophosphoric modified polyesters (TATBs) were synthesized by polycondensation of adipic acid, trimethylolpropane, 1,4-butanediol, and tetramethylene bis(orthophosphate). Two-component PU flame-retardant coatings (TATBCs) were prepared by blending TATBs with HDI-Biuret. Most of the physical properties of the flame-retardant coatings were comparable to those of non-flame-retardant coatings. Coatings containing 10 and 15wt% 1,4-butanediol, TATBC-10C and TATBC-15C were not flammable in the vertical flame-retardancy test.

• Journal of the Korean Wood Science and Technology
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• 제42권5호
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• pp.590-596
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• 2014

Wooden cultural heritages of Korea have been destroyed by fire in many cases. As a result, a number of methods to protect wooden cultural properties against fire were introduced. A way of protecting wooden cultural properties installations of fire equipments such as sprinkler, fire alarm system, or fire extinguisher. Another way of protecting wooden cultural properties is to treat them with flame retardants for their safety. Development of a very effective flame retardant with a good performance without affecting danchung and wood quality is required. At the same time, methods of evaluating flame retardant treated woods should be devised to assess their efficacy. In this study, combustion characteristics using cone-calorimeter, limit oxygen index, moisture absorption, iron corrosive and weathering were analyzed to evaluate the flame resistance efficacy and performance of flame retardants treated woods. The evaluation methods of flame retardants for wooden cultural heritage were suggested.

• 대한안전경영과학회지
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• 제14권2호
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• pp.65-70
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• 2012

This study was performed to test the combustive properties of the pipe insulation materials which are mainly used in the industries and buildings. Fire characteristic test of pipe insulation film according to the KS F ISO 5660-1 was performed. The experimental materials commonly used in the pipe insulation were used four kinds of films. Two kinds of 4 types of products that have the flame retardant performance and the other two types of them have no flame retardant performance. They were selected for fire characteristic test. The result of finding 25kW/$m^2$ radiation from the ignition was that flame retardant products were 140sec and the other one were 69sec in average of heat release rate(HRR). The result of flame retardant products in the 50kW/$m^2$ was 34sec and the other one were 15sec in average of HRR. However, the HRR of flame retardant products was much higher than the other one. Flame propagation test was conducted according to the KOFEIS 1001. The result of flame retardant products was that flame retardant products had a hold without fire spread after firing them. But the other one were completely fired after firing them. Therefore, I want to recommend that flame retardant products need to be used by the regulation to prevent or decrease a fire spread.

• 패션비즈니스
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• 제14권5호
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• pp.102-111
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• 2010

The pegging board planning for jacquard weaves was carried out to express a big enough design in 60 inch width. 20 Kinds of fabrics were fabricated by a jacquard loom with a warp density of 168 yarns/inch, a weft density of 100T, and a weight of 180-220g/$m^2$ or 250-300g/$m^2$. The result of sanitary test about Escherichia coli, Staphilococcus aureus, Klebsiella pneumoniae and Salmonella typhimurium showed a sterilizing power of over 90% after cultivating for 30, 60, 120 minutes. And also its property was sustained after laundrying 20 times. The flame retardant properties showed a good result and complied with the flame retardant criteria of KOFEI 1001. Abrasion, laundry and light fastnesses of flame retardant fabrics showed 4-5 grades. The fabrics manufactured from 30's fiber appeared a little fluff and pill on the fabric. Therefore, they need a shearing process after finishing all processes to decrease the fluff or pill on the fabric. The flame retardant fabric manufactured from 30's and 40's fiber showed increased strength and elongation after soaping and dyeing finishing because the fabrics were shrunk.

• 한국전기전자재료학회논문지
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• 제35권5호
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• pp.494-498
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• 2022

In this study, SiO₂ 20 phr, ATH 70 phr, and platinum flame retardant were mixed with raw silicone rubber and -10 kV was applied to measure electrostatic charge attenuation voltage, surface resistance, and volume resistance, and the following conclusions were obtained. When the platinum flame retardant was 0 phr, the humidity 74.6% and the temperature was 21.8℃, the potential was half-reduced to 0.63 kV, 0.57 kV, and 0.44 kV when the applied voltage was changed from -10 kV to -8 kV, and the time halved to 50% was increased to 2.40 seconds, 2.47 seconds, and 2.61 seconds. It was confirmed that as the platinum flame retardant increased from 0.1 to 0.3 phr, the potential half-reduced to 0.67 kV, 0.60 kV, and 0.595 kV decreased, and the charge potential attenuation time half-reduced to 50% decreased to 3.44 seconds, 1.78 seconds, and 1.60 seconds. It was confirmed that the surface resistance increased as the humidity decreased, and the volume resistance decreased as the platinum flame retardant increased.

• Macromolecular Research
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• 제13권2호
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• pp.128-134
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• 2005

The phosphorus comonomer [(6-oxido-6H-dibenz<1,2>oxaphosphorin-6-yl)methyl]-methyl butane-dioate (DOP-MBDA) was synthesized through the addition reaction of dimethyl itaconate (DMI) with 9,10-dihydro­9-oxa-10-phosphaphenan threne-10-oxide (DOP). A series of novel flame retardant poly(butylene terephthalate)s (PBTs) containing different amounts of phosphorus were prepared using DOP-MBDA as a comonomer. These novel polymers were characterized by $^{1}H-NMR$, IR, and differential scanning calorimetry (DSC). The novel phosphorus­containing poly(butylene terephthalate)s, referred to as FR-PBTs, exhibited interesting thermal and mechanical behavior, as well as superior flame retardancy. These properties are attributed to the effect of incorporating the rigid structure of DOP-MBDA and the pendant phosphorus group into the poly(butylene terephthalate) (PBT) homopolymer. The UL 94-V2 rating could be achieved with this novel flame retardant PBT, which has a phosphorus content as low as $0.5 wt\%$, and the FR-PBTs emitted less fumes and toxic gases than the PBT homopolymer.

• 폴리머
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• 제25권3호
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• pp.391-398
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• 2001

난연성분인 트리브로모아세트산의 함량을 10, 20, 30wt%로 변화시키면서 1,4-부탄디올, 아디프산 및 트리메틸올프로판과 축합중합을 하여 트리브로모 변성폴리에스테르(TBAO)를 합성한 후에, TBAO류와 이소시아네이트를 블렌드하여 2성분계 폴리우레탄(PU) 난연도료를 제조하였다. 제조된 난연도료의 도막물성을 측정한 결과, 결코 비난연도료보다 물성이 저하되지는 않았다. 또한 난연도료의 난연성 시험결과, 수직법에서 트리브로모아세트산 20 wt%에서 불꽃에 타지 않아서 양호한 난연도료임을 알 수 있었다.

• Composites Research
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• 제33권6호
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• pp.408-414
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• 2020

샌드위치 구조는 우수한 강도와 경량성을 동시에 만족하는 구조물로써 다양한 분야에서 널리 사용되고 있다. 스킨은 주로 고강도의 섬유가, 코어는 경량화에 유리한 허니콤 구조 및 발사(balsa) 나무가 주로 사용되고 있으나, 내부의 공기층 및 난연처리의 어려움으로 인하여 화재에 취약하는 것이 단점이다. 본 연구에서는 대나무 섬유의 난연처리 연구를 통하여 친환경적인 소재를 이용한 난연처리 조건을 제시하였다. 또한 대나무 섬유를 이용하여 천연섬유 샌드위치 복합재료를 제조하고 기계적 특성평가를 수행하였다. 난연성이 향상된 천연섬유를 이용하여 샌드위치 구조의 복합재료를 제조한다면 새로운 유형의 복합재료가 될 수 있을 것으로 기대된다.