• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.314-320
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• 2022

The function of reinforcing fibers used in building materials is to maintain resistance to bending loads and to function for cracking caused by drying shrinkage. High-density fiber-cement composites are mainly used for linear plates and are used to increase bending resistance. Therefore, tensile properties, bonding strength with cement hydrate, alkali resistance, and the like are required. Recently, as the non-combustible performance has been strengthened, a function to minimize the occurrence of sparks during high-temperature heating has been added. Therefore, the use of organic fibers is limited. In this study, a study was conducted to replace polypropylene used as reinforcing fiber with hemp fiber with excellent heat resistance. Hemp fibers have excellent heat resistance, good affinity with cement, and excellent alkali resistance. Based on the total volume of polypropylene fibers used in the existing formulation, the non-combustible performance was compared and evaluated by using hemp fibers instead of the polypropylene fibers, and basic physical properties such as flexural strength were tested. As a result of conducting a non-combustibility and physical property test using hemp fibers with a fiber length of 7 mm using 2 % and 3 % by weight, it was found that there is no remaining time of the flame, and the flexural strength can be secured at 95 % level of the existing polypropylene fiber.

• Applied Chemistry for Engineering
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• v.3 no.1
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• pp.130-137
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• 1992

The Graft copolymerization of acrylonitrile(AN) and styrene(ST) onto chloroprene rubber(CR) were carried out with benzoyl peroxide(BPO) as an initiator. The synthesized graft copolymer(ACS) was separated from polymeric mixture by the extraction with ethyl acetate and n-hexane, acetone and methanol, dimethylformamide(DMF) and methanol mixed solvent systems. The graft copolymer obtained, acrylonitrile-chloroprene-styrene(ACS) was identified by IR spectrophotometer. The effect of mole ratio of styrene to acrylonitrile, reaction time and temperature, initiator concentration, CR content and solvents on graft copolymerization were examined. It was observed that the grafting efficiency increased with [ST]/[AN] mole ratio and reaction time. The grafting efficiency increased with increasing initiator concentration and CR content. The maximum grafting efficiency was obtained when the mole ratio of [ST]/[AN] was 1.5 and reaction was made at 40hrs, and $70^{\circ}C$ using chloroform/toluene mixed solvent. The thermal properties, light resistance and flammability of ACS were compared with those of ABS and AES. It was found that flame retardancy of related polymers increased in the order ACS>ABS>AES. The thermal stability of ACS was greatly improved when compared with ABS or AES. Morphology of ACS was also investigated by using a transmisson electron microscope(TEM).

• Journal of Korean Tunnelling and Underground Space Association
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• v.23 no.6
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• pp.535-547
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• 2021

A policy to expand the hydrogen economy has been established in Korea and the supply of FCEV is being expanded to realize a hydrogen society. Therefore, the supply of FCEV is expected to increase rapidly, and a solution to respond to accidents of FCEV is required. In this study, an experimental study was conducted to analyze the effect of the hydrogen jet flame generated by a FCEV on the inner wall of the tunnel and the characteristics of the internal radiant heat. For the experiment, the initial pressure of hydrogen tank was set to 700 bar, and the injection nozzle diameter was set to 1.8 mm in order to make the same as the conditions generated in the FCEV. In addition, a tunnel fire resistance test specimen having the same strength as the compressive strength of concrete applied to general tunnels of 40 MPa was manufactured and used in the experiment. The results were analyzed for the separation distance (2 m and 4 m) between the hydrogen release nozzle and the tunnel fire resistance test concrete. As the result, the maximum internal temperature of the test concrete was measured to 1,349.9℃ (2 m separation distance), and the radiant heat around the jet flame was up to 39.16 kW/m².

• Fire Science and Engineering
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• v.33 no.6
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• pp.165-172
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• 2019

This study presents the design and manufacture of a self-contained breathing apparatus SCBA wireless communication module with a multipoint simultaneous full-duplex communication system to enable communication between team members wearing the SCBA system. It is necessary for fire-fighters to wear the SCBA system during extinguishing and rescue work at the fire site. Evaluation of the team communication module confirmed the feasibility of communication over more than 500 m in the test condition based on the line of sight. By implementing the Ad-hoc function, it was confirmed that the communication distance could be extended to 128 m by automatic routing up to 3 hoc. The vertical distance inside the building for successful communication was up to the 5th floor in the open staircase and up to the 3rd floor in the partitioned staircase. Furthermore, the performance testing of the communication module assuming a fire situation, confirmed that five team members correctly recognized the standard abbreviation of fire and wireless communication without a separate PTT key operation. In addition, the flame resistance was verified by exposing the module to a flame at 950 ± 50 ℃ for 5 s and then immediately extinguishing the flame.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.4
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• pp.1-9
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• 2021

A60 class deck penetration piece is a fire-resistance apparatus installed on the deck compartment to protect lives and prevent flame diffusion in fire accidents. In case that the A60 piece is newly developed or its initial design is revised, it is important to verify the fire resistance performance using a fire test procedure (FTP) code. In this paper, transient heat transfer analysis was carried out to evaluate the fire resistance design compatibility of the newly devised A60 piece. The analysis results were verified via a fire test. The heat transfer characteristics were also investigated by comparing design specifications, such as diameter, internal configuration, and material type. The analysis was performed using ABAQUS/Implicit, and the fire test was performed according to the FTP code. The fire resistance performance of the A60 pieces satisfied the safety of life at sea convention regulation. The material type was the most important design specification for the A60 piece. Based on the maximum test temperature, the measured temperature of SUS316L material was 25% lower than that of S45C on average. The differences between thermal conductivity and specific heat of each material were 17% and 58%, respectively.

• Fire Science and Engineering
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• v.28 no.4
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• pp.97-103
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• 2014

To ensure adequate protection from the risk of burns, fire fighter's turnout has a composite of more than three components and air gaps between layers of materials. During the flame exposure, radiation and convection heat transfer occurs in the air gap, thus the air gap acts as a thermal resistance with non-linear characteristics. Therefore, in this study, the experiments were performed to identify the effect of various air gap width (0~7 mm) on the thermal protective performance of fire fighter's clothing. The temperatures on each layer and RPP (Radiant Protective Performance, the most effective index representing the thermal protective performance) were measured with various incident radiant heat fluxes. The temperature at the rear surface of the garment decreased and RPP increased with increasing air gap width because the thermal resistance increased. Especially, it could be found that RPP value and air gap width has almost linear relation for the constant incident heat flux conditions. Thus relatively simple RPP predictive equation was suggested for various incident heat flux and air gap conditions.

• Composites Research
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• v.26 no.5
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• pp.309-314
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• 2013

Highly ablation resistant carbon nanotube (CNT)-phenolic composites were fabricated by the addition of low concentrations of CNT nanofiller. Tensile and compressive properties as well as ablative resistance were significantly improved by the addition of only 0.1 and 0.3 wt% of uniformly dispersed CNTs. An oxygen-kerosene-flame torch and a field emission scanning electron microscope (FE-SEM) were used to evaluate the ablative properties and microstructures of these CNT-phenolic composites. Thermal gravimetric analysis (TGA) revealed that the ablation rate was lower for the 0.3 wt% CNT-phenolic composites than for neat phenolic or the composite with 0.1 wt% CNT. Ablative mechanisms for all three materials were investigated using this TGA in conjunction with microstructural studies using a FE-SEM. The microstructural studies revealed that CNT acted as an ablation resistant phase at high temperatures, and that the uniformity of dispersion of the CNT played an important role in this resistance to ablation.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.1
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• pp.78-84
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• 2012

Mold may experience deterioration of molding quality as the abrasion of mold occurring due to friction between mold and molded product works as allowance in the course of press process. Therefore, to improve the wear-resistance of mold, methods like nitriding, carburizing, flame and induction surface hardening treatment etc have been applied. However, as such methods are accompanied by problems like shape limitation or product deformation etc, laser surface treatment technology is under review as surface treatment method that can solve such problems. Therefore, in this study, mold material cast iron was surface-treated by using high power diode laser. In previous report 1 and report 2, the heat treatment characteristics were compared by the differences of die materials and shapes, then this paper observed microstructure by using optical microscope and scanning electronic microscope to analyze the structural difference of hardened zone, interface area and base metal after heat treatment. And the structural condition was grasped through EDS. As a result of microstructure, hardened zone showed formation of acicular martensite.

• Fire Science and Engineering
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• v.30 no.1
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• pp.86-95
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• 2016

Weight-bearing building materials are substantially weakened under high temperatures, and this is evident through the collapse of structures once engulfed by fire. Currently, there is no scientific or technological process of evaluating the real-time structural stability of a building whcih is engulfed by flame. There are many building design specifications which aim to reduce the risk of fire, but little consideration given to fire officer safety while operating in a dangerous building. This paper aims to provide direction within building policy in order to ensure the safe evacuation of fire-fighters in case of an impending building collapse. This paper suggests evaluation criteria for buildings which are damaged due to fire, autilizing current information on fire-resistant building design and a fire-resistant capacity.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.365-372
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• 2018

3D printing technology of construction field can be divided into structural materials, interior and exterior finishing materials, and is mainly done by extruding and adapting. Particularly when it is applied as an exterior materials, it is mainly applied to an unstructured exterior materials and high accuracy is required. The exterior materials can be used as a cement composite materials, it is suitable also for a additive type manufacturing, and the role of a redispersible polymer powder is important. But, high temperatures, redispersible polymer cement base material beget dehydration and micro crack of cement matrix. In this research, we developed a EVA, EVCL redispersible polymer cement base material applicable as a 3D printing exterior materials, confirmed density and strength characteristics for application as an exterior materials, a flame retardancy test for improving the fire resistance of buildings and confirmed its possibility. From the test result, developed EVCL redispersible polymer cement mortar showed good stability in high temperatures. These high temperature stability is caused by the ethylene-vinyl chloride binding. Thus, this result indicates that it is possible to fire resistant 3D printing interior and exterior finishing materials.