• 제목/요약/키워드: Flame resistance

검색결과 192건 처리시간 0.028초

PVC 바닥상재용 광경화형 내열 코팅액의 제조 및 응용에 관한 연구 (Manufacture and Application of UV-Cured Anti-cigar burning Coating Compounds for PVC Tile)

  • 박보람;하진욱
    • 한국산학기술학회논문지
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    • 제11권2호
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    • pp.608-613
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    • 2010
  • 본 연구는 건축용 바닥재로 널리 이용되는 PVC 상재의 표면을 열에 의한 손상으로부터 보호하기 위하여 기존에 사용하는 광경화형 우레탄-아크릴 수지에 내열성(anti-cigar burning)을 향상시킨 광경화형 수성도료 개발에 관한 것이다. PVC 바닥상재용으로 사용되는 내열기능성이 없는 우레탄-아크릴 수지에 인계화합물을 주원료로 합성한 내열재, 구아니딘을 주원료로 합성한 내열재, 일시적 방염제로 사용되는 제 2인산암모늄을 수지의 양 대비 함량(wt%)을 10, 20, 30%로 변화하여 첨가한 후 배합하여 수지의 내열성을 향상시킨 코팅액을 제조하였다. 제조한 코팅액은 코팅층의 두께조절이 가능한 Bar-coating을 사용하여 PVC 바닥상재에 코팅한 후, 내열성, 부착력, 내화학성, 코팅두께 등의 코팅층 표면물성을 평가하였다. 연구결과, 수지에 인계화합물을 주원료로 합성한 내열재 30%를 혼합하여 제조한 코팅액을 Bar-coater No.12로 코팅한 코팅표면이 열에 의한 손상이 가장 적고, 부착력 100%, 내화학성 양호로 가장 좋은 물성을 보였다. 전반적으로 내열재 함량이 높고, 코팅 두께가 두꺼울수록 내열성이 우수한 것으로 나타났다.

화재시 비차열 유리의 복사열에 관한 실험적 연구 (The Experimental Study for Radiant Heat Flux of Non-insulated Glazed Window in Fire)

  • 박수영;서희원;김대회;왕남웅;여인환;최동호
    • 한국화재소방학회논문지
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    • 제28권2호
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    • pp.26-33
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    • 2014
  • 최근 국내에서는 건축물에서 공간의 미관이나 활용성 때문에 유리창 및 유리벽체의 사용에 대한 관심이 높아지고 있다. 하지만, 건축물의 내부공간은 화재시 연소확대 및 인명피해를 막기 위해 건축법에 따라 내화구조로 방화구획을 하여야 한다. 이러한 방화구획벽에 비차열 유리를 사용할 경우, 화재시 인접 거실로 복사열에 의한 화재의 확대, 인명 피해가 일어날 수 있다. 본 연구에서는 비차열 유리창에 대한 복사열의 위험성을 평가하기 위하여 내화실험을 실시하여 실험체 이면에서의 온도와 열류량을 측정하여 그 결과를 분석하였다.

컨버터 내장형 LED 가로등 및 보안등의 전기적 특성 분석 (Electrical Characteristics Analysis of LED Lamps using Internal Converter for Road and Street Lighting)

  • 김향곤;길형준;최효상
    • 전기학회논문지P
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    • 제59권2호
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    • pp.238-244
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    • 2010
  • In this paper, we studied electrical characteristics of internal converter type of LED lamps for road and street lighting. We surveyed electro-technical regulations and KS(Korean industrial standards) about LED luminairs. Waveforms of voltage and current, thermal distributions, insulation resistances between live parts and exposed conductive parts, and flame test of cover of LED lamps were experimented and analyzed. In regulations, insulation resistance between live conductors and exposed conductive parts should be greater than $0.2M{\Omega}$ in case nominal voltage of wiring is 220V. In KS codes, the value of insulation resistance should be greater than $2M{\Omega}$ while applying DC 500V or DC 100V. In the result of this study, waveforms of primary voltage and current were distorted. There was difference in waveforms of secondary voltage and current according to composition of converter. Mostly, insulation resistances were measured high more than regulation and code value but some measured points were measured badly($0.0M{\Omega}$). Cover of LED lamps was ignited easily. We expect that the results of this study would be helpful for revision of regulations and national codes for the electrical safety of LED road and street lighting.

Ablative Properties of 4D Carbon/Carbon Composites by Combustion Test

  • Park, Jong-Min;Ahn, Chong-Jin;Joo, Hyeok-Jong
    • Carbon letters
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    • 제9권4호
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    • pp.316-323
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    • 2008
  • The factors that influence ablation resistance in fiber composites are properties of the reinforced fiber and matrix, plugging quantity of fiber, geometrical arrangement, crack, pore size, and their distributions. To examine ablation resistance according to distribution of crack and pore size that exist in carbon/carbon composites, this study produced various sizes of unit cells of preforms. They were densified using high pressure impregnation and carbonization process. Reinforced fiber is PAN based carbon fiber and composites were heat-treated up to $2800^{\circ}C$. The finally acquired density of carbon/carbon composites reached more than $1.932\;g/cm^3$. The ablation test was performed by a solid propellant rocket engine. The erosion rate of samples is below 0.0286 mm/s. In conclusion, in terms of ablation properties, the higher degree of graphitization is, the more fibers that are arranged vertically to the direction of combustion flame are, and the less interface between reinforced fiber bundle and matrix is, the better ablation resistance is shown.

목분-고밀도폴리에틸렌 복합체의 연소성 및 열적특성 (Combustion Characteristics and Thermal Properties for Wood Flour-High Density Polyethylene Composites)

  • 신백우;정국삼
    • 한국화재소방학회논문지
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    • 제26권1호
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    • pp.89-95
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    • 2012
  • 본 연구에서는 목분-HDPE 복합체를 모듈라 회전 이축압출기를 이용하여 제조하여 연소성 및 열적특성을 평가하기 위하여 콘칼로리미터 실험및 열중량 분석실험을 실시하였다. 그리고 복합체의 난연성능 향상을 위하여 난연제(3종)를 첨가한 복합체의 화재성능을 평가하였다. 콘칼로리미터 실험 결과 난연제를 첨가하지 않은 복합체의 열방출률이 가장 높았으며 최대 열방출률 값은 $446.6kW/m^2$, 평균 열방출률 값은 $185.5kW/m^2$으로 가장 높게 나타났다. 열중량 분석 결과 난연제 첨가한 복합체들의 열분해가 먼저 시작되고 열 안정성을 향상시켰다.

다층 코팅된 Stainless Steel의 고온 내삭마특성 (High Temperature Ablation Behaviors of Multilayer Coated Stainless Steel)

  • 최광수;양원철;김영주;박준식;김민규
    • 한국재료학회지
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    • 제28권3호
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    • pp.135-141
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    • 2018
  • Stainless steel is being used in various industries such as automobile and aerospace for its cheap manufacturing cost and excellent mechanical properties. However, stainless steel failed to stably protect a specimen with a $Cr_2O_3$ protective layer at temperatures above $1000^{\circ}C$. Thus, improving the high temperature flame resistance of the specimen through additional surface coating was needed. In this study, multilayer coatings of YSZ and $Al_2O_3$ were performed on SUS 304 specimens using pack cementation coatings and thermal plasma spray. The multilayer coated specimen showed enhanced thermal properties due to the coated layers. The microstructures and phase stability are discussed together with flame conditions at $1350^{\circ}C$.

Cell Surface Display of Four Types of Solanum nigrum Metallothionein on Saccharomyces cerevisiae for Biosorption of Cadmium

  • Wei, Qinguo;Zhang, Honghai;Guo, Dongge;Ma, Shisheng
    • Journal of Microbiology and Biotechnology
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    • 제26권5호
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    • pp.846-853
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    • 2016
  • We displayed four types of Solanum nigrum metallothionein (SMT) for the first time on the surface of Saccharomyces cerevisiae using an α-agglutinin-based display system. The SMT genes were amplified by RT-PCR. The plasmid pYES2 was used to construct the expression vector. Transformed yeast strains were confirmed by PCR amplification and custom sequencing. Surface-expressed metallothioneins were indirectly indicated by the enhanced cadmium sorption capacity. Flame atomic absorption spectrophotometry was used to examine the concentration of Cd2+ in this study. The transformed yeast strains showed much higher resistance ability to Cd2+ compared with the control. Strikingly, their Cd2+ accumulation was almost twice as much as that of the wild-type yeast cells. Furthermore, surface-engineered yeast strains could effectively adsorb ultra-trace cadmium and accumulate Cd2+ under a wide range of pH levels, from 3 to 7, without disturbing the Cu2+ and Hg2+. Four types of surfaceengineered Saccharomyces cerevisiae strains were constructed and they could be used to purify Cd2+-contaminated water and adsorb ultra-trace cadmium effectively. The surface-engineered Saccharomyces cerevisiae strains would be useful tools for the bioremediation and biosorption of environmental cadmium contaminants.

Synergistic effect of clay and polypropylene short fibers in epoxy based ternary composite hybrids

  • Prabhu, T. Niranjana;Demappa, T.;Harish, V.;Prashantha, K.
    • Advances in materials Research
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    • 제4권2호
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    • pp.97-111
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    • 2015
  • Polypropylene short fiber (PP)-clay particulate-epoxy ternary composites were prepared by reinforcing PP short fiber and clay particles in the range of 0.1 phr to 0.7 phr into epoxy resin. Prepared hybrid composites were characterized for their mechanical, thermal and flame retardant properties. The obtained results indicated an increase in impact resistance, tensile strength, flexural strength and Young's modulus to an extent (up to 0.5 phr clay and 0.5 phr PP short fiber) and then decreases as the reinforcing phases are further increased. The thermal stability of these materials are found to increase up to 0.2 phr clay and 0.2 phr PP addition, beyond which it is decreased. Addition of clay is found to have the negative effect on epoxy-PP short fiber composites, which is evident from the comparison of mechanical and thermal properties of epoxy-0.5 phr PP short fiber composite and epoxy-0.5 phr PP short fiber-0.5 phr clay composite hybrid. UL-94 tests conducted on the composite hybrids have showed a reduction in the burning rate. Morphological observations indicated a greater fiber pull with the addition of clay. The performed tests in the present study indicated that materials under investigation have promising applications in construction, agriculture and decorative purposes.

날아가는 섬광탄이 연료탱크 수평핀에 미치는 복사열전달 연구 (An Investigation of Radiation Heat Transfer on The Horizontal Fin of An External Fuel Tank by Flame of a Flying Flare)

  • 정대한;강치행;김시태
    • 한국군사과학기술학회지
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    • 제17권2호
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    • pp.197-203
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    • 2014
  • In this paper, the effect of unsteady radiation on the horizontal fin of an external fuel tank by flame of a flying flare was analysed to see the temperature increase of the fin and the thermal impact on the fin. Radiation between two surfaces was calculated using the concept of radiation resistance of surface and space including radiation, irradiation and shape factor for two flying trajectories of a flare, maximum temperature of 2200 K, emissivity of 0.95, flying velocity of 30 m/s, and thermal surface area of $0.01m^2$. The result shows that the temperature increase of the fin is 0.236 K, and the thermal effect on the fin is ignorable. And it was found that temperature is increased a little because small amount of heat energy can be radiated due to the short exposure time to the heat source.

알루미나 골재를 첨가한 FA-BFS계 지오폴리머 세라믹스의 열확산에 대한 표면 특성 (Surface characteristics for thermal diffusion of FA-BFS-based geopolymer ceramics added alumina aggregate)

  • 김진호;박현;김경남
    • 한국결정성장학회지
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    • 제29권2호
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    • pp.61-70
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    • 2019
  • Geopolymer는 시멘트와 비교하여 $CO_2$ 배출량의 감소, 내화성, 낮은 열전도성 등 다양한 장점을 보유하고 있는 eco-friendly 건설재료이다. 그러나 표면에 화염을 가할 경우 geopolymer panel 표면의 열적거동에 대한 연구결과는 많지 않다. 본 연구에서는 내열성 건축자재로서 화염노출시 geopolymer 경화체의 표면특성을 조사하기 위하여 alumina 골재가 사용된 geopolymer 경화체 표면의 화염노출 특성에 대하여 조사하였다. 화염노출시 panel의 외형변형 및 열충격에 의한 크랙은 없었으며, calcite의 잔존량과 aluminosilicate gel의 halo 패턴으로 보아 화염에 의한 탈탄산 및 탈수는 표면에 국한되어 발생했으며, geopolymer 경화체의 내구성은 화염조사 후에도 유지되고 있는 것으로 판단된다. Quartz와 calcite가 감소함에 따라 gehlenite와 calcium silicate가 증가하는 경향을 나타내고 있으며, BFS의 치환량이 많을수록 현저하게 나타난다. 화염노출에 따른 미세구조의 변화는 탈탄산, 결정수의 탈수 등으로 기공의 형성과 발전되는 과정을 거쳐 calcium silicate, gehlenite 등과 같은 새로운 결정상의 형성에 의해 geopolymer panel 표면의 치밀화와 강화기구로 작용하여 내구성이 향상된 것으로 생각된다.