• Korean Journal of Materials Research
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• v.32 no.12
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• pp.553-559
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• 2022

In this work, the ablation behavior of monolith ZrB₂-30 vol%SiC (Z30S) composites were studied under various oxy-acetylene flame angles. Typical oxidized microstructures (SiO₂/SiC-depleted/ZrB₂-SiC) were observed when the flame to Z30S was arranged vertically. However, formation of the outmost glassy SiO₂ layer was hindered when the Z30S was tilted. The SiC-depleted region was fully exposed to air with reduced thickness when highly tilted. Traces of the ablated and island type SiO₂ were observed at intermediate flame angles, which clearly verified the effect of flame angle on the ablation of the SiO₂ layer. Furthermore, the observed maximum surface temperature of the Z30S gradually increased up to 2,200 ℃ proving that surface amorphous silica was continuously removed while monoclinic ZrO₂ phase began to be exposed. A proposed ablation mechanism with respect to flame angles is discussed. This observation is expected to contribute to the design of complex-shaped UHTC applications for hypersonic vehicles and re-entry projectiles.

• Nuclear Engineering and Technology
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• v.37 no.3
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• pp.265-272
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• 2005

Severe accidents in nuclear power plants can cause hydrogen-generating chemical reactions, which create the danger of hydrogen combustion and thus threaten containment integrity. For containment analyses, a three-dimensional mechanistic code, GOTHIC-3D has been applied near source compartments to predict whether or not highly reactive gas mixtures can form during an accident with the hydrogen mitigation system working. To assess the code applicability to hydrogen combustion analysis, this paper presents the numerical calculation results of GOTHIC-3D for various hydrogen combustion experiments, including FLAME, LSVCTF, and SNU-2D. In this study, a technical base for the modeling oflarge- and small-scale facilities was introduced through sensitivity studies on cell size and bum modeling parameters. Use of a turbulent bum option of the eddy dissipation concept enabled scale-free applications. Lowering the bum parameter values for the flame thickness and the bum temperature limit resulted in a larger flame velocity. When applied to hydrogen combustion analysis, this study revealed that the GOTHIC-3D code is generally able to predict the combustion phenomena with its default bum modeling parameters for large-scale facilities. However, the code needs further modifications of its bum modeling parameters to be applied to either small-scale facilities or extremely fast transients.

• Journal of the Korean Society of Combustion
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• v.10 no.4
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• pp.33-40
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• 2005

The propagation rates of advancing and retreating non-premixed edge flames in a slot-jet counterflow were measured as a function of strain rate for varying jet spacing, mixture strength, stoichiometric mixture fractions $(Z_{st})$ and Lewis numbers (Le). Methane and propane fuels were tested and nitrogen and carbon dioxide were used as inerts. As results, we could identify igniting fronts, retreating fronts, two total extinction limits, and short-length edge flames. A burner separation affected to a low extinction limit only. Regimes for advancing and retreating edges together with total extinction were mapped in terms of normalized flame thickness and heat loss factor for $CH_4/O_2/N_2$ mixtures. Edge flames for $Z_{st}$ > 0.5 behaved like a stronger mixture while for $Z_{st}$ < 0.5 showed deteriorated feature, because of relative locations of a non-premixed flame and intermediate species such as CO and $H_2$. Furthermore, due to the relative importance of heat loss, propagating speeds of edge flames were significantly enhanced in $CH_4/O_2/CO_2$ mixtures (Le < 1) demonstrating increasing stability limits. However $C_3H_8/O_2/N_2$ mixtures (Le > 1) showed opposite result.

• Journal of the Korean Society of Safety
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• v.19 no.1
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• pp.124-130
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• 2004

The structure of the nonpremixed methane-air counterflow flames in microgravity was investigated by axisymmetric simulation with Fire Dynamics Simulator (FDS) to evaluate the numerical method and to see the effects of strain rate and fuel concentration on the diffusion flame structure in microgravity. Results of FDS for the methane mole fractions, $X_m$=20, 50, and 80% in the fuel stream, and the global strain rates $a_g$=20, 50, and $90s^{-1}$ for each methane mole fraction were compared with those of OPPDIF, an one-dimensional flamelet code. There was good agreement in the temperature and axial velocity profiles between the axisymmetric and one-dimensional computations. It was shown that FDS is applicable to the counterflow flames in a wide range of strain rate and fuel concentration by predicting accurately the flame thickness, flame positions and stagnation points.

• Journal of Fisheries and Marine Sciences Education
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• v.26 no.6
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• pp.1435-1441
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• 2014

The fire took place in the synthetic heat transfer fluid boiler used in production process of medium density fiberboard. This study investigated pressure distribution of the first, second and third passes and the temperature in the fire burner. The boiler's internal fluid is unsteady due to the out of order inverter. As the operation continues, the flame's flow and speed are unsteady. The synthetic heat transfer fluid leak spouted about 120kg/min in the form of vapor in the early period of the fire. The flame extended to the second and third passes. The highest temperature of the second and third pass is $1059^{\circ}C$ and $1007^{\circ}C$, respectively. The synthetic heat transfer fluid spouted through the cracked part of the fire box in the first pass and accumulated on the turn table. Therefore, it is expected that the temperature of the interior of the fire box is above $1200^{\circ}C$. The temperature of the burner rises to a maximum level several times in a short period. On account of that, several explosions occur in the fire burner. Pressure distribution at steady state in combustion furnace is 2~5mAq and pressure distribution at inverter under fault condition in combustion furnace is 10~-53mAq. The decrement of coil thickness measurement for synthetic heat transfer fluid boiler is 0~5mm.

• Elastomers and Composites
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• v.43 no.4
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• pp.241-252
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• 2008

ZnAl-LDH(layered double hydroxide) modified with oleic acid(SO-ZnAl LDH) was synthesized and added to the flame retardant ABS compounds containing brominated epoxy resin(BER) and antimony trioxide(${Sb_2}{O_3}$). Flame retardant ABS compounds were manufactured by using a twin-screw co-rotating extruder and subsequently injection molded into several specimen for flame retardancy and mechanical properties. The XRD patterns of ABS nanocomposites showed no peaks. The thermal stability of ABS nanocomposites was enhanced by the addition of SO-ZnAl LDH as shown in TGA results. However, these nanocomposites showed no rating in the UL 94 vertical test at 1.6 mm thickness. Only ABS nanocomposites with additional BER more than 1.5 wt% showed UL 94 V0 rating. Notched Izod impact strength, tensile modulus, and elongation at break of flame retardant ABS nanocomposites increased with the proportion of So-ZnAl LDH whereas their melt index decreased.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.2
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• pp.265-270
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• 1989

The present study considers the thermal structure variation in a porous medium caused by changing the most important radiative property of porous medium, absorption coefficient, as well as altering the physical dimension of porous medium and the equivalence ratio of premixed gas mixture. The radiation model was introduced as an unsteady differential form using the two-flux gray radiation model. The role of the conductive heat transfer through both gas phase and porous medium was found to be almost insignificant compared with that of the radiative heat transfer. The reaction zone shifted upstream and the flame thickness decreased as either the geometrical length of porous medium increased or the absorption coefficient decreased.

• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.603-608
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• 2010

A study has been conducted experimentally to investigate behavior of ignition and flame spread over metal dust deposits with particle size using by a developed apparatus and thermogravimetric analysis(TGA). Zr, Ta and Mg-Al(90:10 wt%) alloy metal powders including Mg and Ti with different particle size were used. Also we used PMMA(Polymethylmethacrylate) powder to compare the combustion properties to those of metal powders. When dust layers were more than 5 mm in thickness, the dependency of deposit depth on flame spread rate over dust layer was not shown. With decreasing mean particle diameter, flame spread rate over Ti dust layer decreased, while the spread rate over Mg dust layer increased. For mean diameter of $51{\mu}m$, fire spread rate over pure Mg dust layer decreased to about 50 percent in Mg-Al(90:10 wt%) dust layer. The oxide thickness of metal dust used in this study tended to be inversely proportional with the spread rate, and it was quite small for influence with particle size. From the results of TGA for Ti and Mg, weight increasing curves(550 for Mg, 578 for Ta) were observed in the oxidation process, and they seems to be caused by ignition of upper dust layer.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.1
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• pp.120-127
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• 2015

The purpose of this study is to improve the fire prevention performance using the fire venetian blind louver subjected to burning by fire flame. The investigation is based on testing 2 full scale specimens, which is $3m{\times}3m$ module, $850mm{\times}1,500mm$ open, and $900mm{\times}900mm{\times}175mm$ venetian blind louver. Two louver thickness (1.5 and 2.0mm) were adopted. The specimens were exposed to fire flame temperature levels of ISO834 at the lower surface of the fire venetian blind louver specimens with exposure duration of one hour in Korea Institute of Construction Technology (KICT). It was found from the test results that the values of distributed temperature, decreased for all specimens for protecting to fire flame by venetian blind louver. The results of tests were a good fire prevention performance between in initial to 6 mins. At 60 minutes around ISO 834 fire loading, the percentages of distributed temperature in 500mm and 800mm height ranged between 11 and 10% respectively, regardless of louver thickness. This study, therefore, will improve the fire venetian blind louver for fire protection and prevention performance.

• Journal of the Korean Ceramic Society
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• v.35 no.4
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• pp.364-370
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• 1998

Boron-phoshor-silicate glass was fabricated on Si substrates by FHD(Flame Hydrolysis Deposition) The microstructrue of silica soot deposited at various conditon such as composition and substrate temperature was analysed by SEM. After consolidation the refractive index and composition of the silica layer were in-vestigated. For refractive index control B, P and Ge were used as additive elements while B and Ge oxides are easily mixed into $SiO_2$, P oxide($B_2O_3$) doping is difficult because of the volatile property due to low melt-ing point. Boron-phosphorous-silicate glass (BPSG) layer were fabricated using bertical torch and optimized flame temperature substrate temperature and distance of torch and substrate. P concentration of BPSG lay-er measured 3.3 Wt% and the consolidation temperature was lower than $1180^{\circ}C$. The measured refractive index of BPSG silica layer in $1.55\;\mu\textrm{m}$ wavelength was $1.4480{\pm}1{\times}10^{-1}$ and the thickness was $22{\pm}1\;\mu\textrm{m}$.