• Title/Summary/Keyword: Flame Spray

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화염분무열분해법을 이용한 이산화세륨 나노분말 제조 (Preparation of CeO2 Nanoparticles using Flame Spray Pyrolysis)

  • 김선경;박수련;장한권;장희동
    • 한국입자에어로졸학회지
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    • 제12권2호
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    • pp.37-42
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    • 2016
  • $CeO_2$ nanoparticles were prepared by a flame spray pyrolysis from aqueous solution of cerium nitrate. The morphology, structure crystallinity and specific surface area of as-prepared nanoparticles were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and Brunauer-Emmett-Telle (BET). The $CeO_2$ nanoparticles about 5 nm in diameter showed a cubic fluorite structure and polyhedral morphology. The average particle size increased as the cerium nitrate concentration increased. UV absorption performance of the as-prepared nanoparticles was measured by UV-visible spectroscopy. UV absorption of $CeO_2$ nanoparticles was more effective than that of commercial $TiO_2$ nanoparticles. Effect of dopants such as Ti and Zn to $CeO_2$ nanoparticles on UV absorption properties was also investigated. In case of $Ti/CeO_2$, and $Zn/CeO_2$ nanoparticles, they showed a little higher UV absorption values compared with $CeO_2$ nanoparticles. The as-prepared nanoparticles can be promising materials with high UV absorption value.

동시 시계열 계측에 의한 예혼합 분무화염 내 유적군 연소기구의 평가 (Evaluation of Combustion Mechanism of Droplet Cluster in Premixed Spray Flame by Simultaneous Time-Series Measurement)

  • 황승민
    • 대한환경공학회지
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    • 제31권6호
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    • pp.442-448
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    • 2009
  • 예혼합 분무화염의 유적군 연소 기구를 평가하기 위하여 레이저 가시화법, MICRO (multi-color integrated Cassegrain receiving optics) 및 PDA (phase Doppler anemometer) 광학계측 시스템을 이용하여 동시 시계열 계측을 실시하였다. 또한 유적군의 군연소수를 실험적으로 산출하여 이론해석에 적용하였을 경우 실제로 관찰되는 군연소 형태와 일치하는지에 대하여 검토하였다. 유적군 단면화상에 의해 확인된 모든 유적군에 대하여 실험적으로 군연소수 $G_c$를 산출한 결과 주로 내부 군연소와 외부 군연소로 분류되었으며 이론해석과 일치하였다. 또한 실제 관찰된 군연소 형태와 그 유적군의 군연소수를 이론해석에 적용한 경우에 군연소 형태가 일치하는 경우와 일치하지 않는 경우가 있었다. 일치하지 않는 원인은 군연소수를 유적의 기하학적 배치만으로 결정한 것이나 현상의 3차원성이 측정 결과에 영향을 미친 것이라고 생각되어진다.

3단 덕트 시스템에서 화염전달함수가 연소불안정 모델링 결과에 미치는 영향 (Effects of Flame Transfer Function on Modeling Results of Combustion Instabilities in a 3 Step Duct System)

  • 홍수민;김대식
    • 한국분무공학회지
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    • 제25권3호
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    • pp.119-125
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    • 2020
  • In this paper, we used Helmholtz solver based on 3D finite element method to quantitatively analyze the effects of change of gain, time delay and time delay spread, which are the main variables of flame transfer function, on combustion instability in gas turbine combustor. The effects of the variable of flame transfer function on the frequency and growth rate, which are the main results of combustion instability, were analyzed by applying the conventional heat release fluctuation model and modified one considering the time spread. The analysis results showed that the change of gain and time delay in the same resonance mode affected the frequency of the given resonance modes as well as growth rate of the feedback instability, however, the effect of time delay spread was not relatively remarkable, compared with the dominant effect of time delay.

평면 레이저 유도 형광법(PLIF)을 이용한 $CH_4/O_2N_2$ 예혼합화염의 NO 농도 분포 가시화에 관한 연구 (A Study on the Visualization of NO Concentration Distributions in $CH_4/O_2N_2$ Premixed Flames by PLIF)

  • 박경석;이세환
    • 한국분무공학회지
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    • 제6권3호
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    • pp.1-7
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    • 2001
  • In this study, quantitative measurement of nitric oxide concentration distributions visualization were investigated in the laminar $CH_4/O_2N_2$ nixed flame by Planar laser-induced fluorescence(PLIF). The NO A-X (0,0) vibrational band around 226nm was excited using a XeCl excimer-pumped dye laser. Selecting an appropriate NO transition minimizes interference from Rayleigh scattering and $O_2$ fluorescence. The measurements were taken in $CH_4/O_2N_2$ premixed flame with equivalence ratios varying from $1.0{\sim}1.6$, and a fixed flow rate of 3slpm. NO was found to produce primarily between an inner premixed and an outer nonpremixed flame front, and total NO concentration is raised when equivalence ratios increase. These results suggest that prompt NO is likely to contribute to MO formation in $CH_4/O_2N_2$ premixed flame. Furthermore, this trend was well matched with previous works.

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비정상 층류화염편 모델을 이용한 비예혼합 난류화염 해석 (Unsteady Flamelet Modeling of Turbulent Nonpremixed Flames)

  • 김성구;강성모;서보선;김용모
    • 한국분무공학회지
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    • 제6권3호
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    • pp.8-16
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    • 2001
  • The present study is focused on modeling the transient behavior of the local flame structure which is especially important for slow reaction processes, such as NOx formation in the radiating flame field. The unsteady flamelet model recently developed has been applied to analyze a steady, turbulent jet flame. Numerical results are compared with experimental data and numerical results of the conventional steady flamelet model. The numerical result reveals that the unsteady flamelet model correctly predicts the nonequilibrium effect upsteam and the subsequent decay of the superequilibrium radical concentrations further downstream.

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미분무 시스템이 장착된 화염방지장치의 화재 진화 특성에 관한 연구 (A Study on the Fire Suppression Characteristics of a Flame Arrester with Water Mist System)

  • 김해지;이경로
    • 한국기계가공학회지
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    • 제15권5호
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    • pp.117-124
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    • 2016
  • In this paper, we developed a breather valve with a water mist system for use near an oil storage tank. Our process applied a water mist system to the flame arrester to evaluate the fire suppression characteristics. For the fire suppression evaluation of the water mist system, we evaluated the angle of the nozzle, fire suppression, spray particle size, flashback, fire suppression time, and fire suppression test of antifreeze. Through the fire suppression test, the best fire suppression nozzle used an angle of $140^{\circ}$, and the flashback phenomenon of flame arrester did not occur. The fire suppression time of water mist system time was within three seconds, and the antifreeze was no problem with the fire suppression.

화염분무열분해 공정을 이용한 저온 연료전지 연료전극용 탄소담지 Pt-Ru 촉매의 제조 (Synthesis of Carbon-Supported Pt-Ru Catalysts using a Flame Spray Pyrolysis Method for Fuel Electrode of Low Temperature Fuel Cell)

  • 이현민;이동근
    • 한국입자에어로졸학회지
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    • 제8권2호
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    • pp.69-74
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    • 2012
  • This study describes how successfully a conventional flame aerosol synthesis was used to continuously synthesize Pt-Ru catalysts supported by carbon agglomerates. Nearly spherical catalysts produced in the flame were mainly composed of metallic Pt and Ru with the molar ratio of 1:1 and those sizes were controllable from ~1.5 nm to ~2.0 nm. Nevertheless, only Pt peaks were found from X-ray diffraction experiments, suggesting that amorphous-like Ru was well mixed in the crystalline Pt lattices. It was found from Cyclo-voltamograms and CO stripping experiments that the electrochemical properties of the catalysts are at least comparable to that of a conventional commercial sample.

교류 전기장 인가에 따른 프로판 예혼합 화염의 유동 특성 (Flow Characteristics of Propane Premixed Flame on AC Electric Field)

  • 김보윤;김민석;김태훈;권일송;김혜민
    • 한국분무공학회지
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    • 제29권1호
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    • pp.38-44
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    • 2024
  • This study investigates the flow characteristics of propane-air premixed flames on AC electric field using the Schlieren method. A voltage was applied to the ring electrode and the burner was grounded to form an electric field, and the applied voltage was fixed at 16 kV (Vpp). Results show that under the application of AC electric fields, flow around the flame oscillated only at frequencies below 50 Hz, and no oscillation was observed above this frequency range. Flame height oscillated with frequency in the range of 25 to 300 Hz, with frequency doubling observed in the range of 25 to 150 Hz. The flammability limit increased with frequency up to 250 Hz, but in the high-frequency range above 250 Hz, the flammability limit did not increased and converged.

스월 인젝터의 작동조건 및 인젝터 형상에 따른 분무특성 (The Effects of Operating Conditions and Injector Geometry on the Spray Characteristics of Swirl Injectors)

  • 김동준;임지혁;한풍규;윤영빈
    • 한국분무공학회지
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    • 제9권1호
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    • pp.21-29
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    • 2004
  • The flow characteristics of a swirl injector were investigated with the variation of the flow condition and geometric dimensions, such as orifice length for considering the viscous effect and tangential entry port area for considering the swirl intensity. The liquid film thickness strongly influencing on the formed drop size of the spray was measured using a new technique. The film thickness measurement technique proposed here, used the attenuation of fluorescence signal near the injector exit. The breakup length that is important for the flame location as well as the spray cone angle which influences on the ignition performance was measured using a backlit stroboscopic photography technique. From the experimental results, it is found that an increase in injection pressure decreased the film thickness and breakup length, and also enlarged the spray cone angle. A decrease in orifice length and tangential entry port area has a similar tendency of thinner film thickness, shorter breakup length and larger spray cone angle. In the present study, we proposed empirical models of the flow characteristics of the swirl injectors.

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다구찌 기법을 이용한 용사코팅의 공정 최적화 (Optimization for Thermal spray Process by Taguchi Method)

  • 김균택;김영식
    • 동력기계공학회지
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    • 제16권2호
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    • pp.54-59
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    • 2012
  • In the present study, process optimization for thermal-sprayed Ni-based alloy coating has been performed using Taguchi method and analysis of variance(ANOVA). Ni-based alloy coatings were fabricated by flame spray process on steel substrate, and the hardness test and wear test were performed. Experiments were designed as per Taguchi's L9 orthogonal array and tests were conducted with different Oxygen gas flow, Acetylene gas flow, Powder feed rate and Spray distance. Multi response signal to noise ratio (MRSN) was calculated for the response variables and the optimum combination level of factors was obtained simultaneously using Taguchi's parametric design.