• Bulletin of the Korean Chemical Society
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• v.23 no.5
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• pp.693-698
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• 2002

A method has been described for the determination of Cu(Ⅱ), Pb(Ⅱ), Ni(Ⅱ), Cd(Ⅱ), Mn(Ⅱ) and Fe(Ⅲ) by flame atomic absorption spectrometry (FAAS) after preconcentration on Amberlite XAD-16 resin, using hexamethyleneammonium-hexamethylenedithiocarbamate (HMA-HMDTC) as a chelating agent, and NH3/NH4Cl buffer solution (pH 9). Influences of various analytical parameters such as pH, concentration of nitric acid, amount of analytes, diverse ions and sample volume were investigated. The relative standard deviation (RSD) and the detection limit (LOD) were found in the range of 0.8-2.9% and 0.006-0.277 ㎍/mL,respectively. Recoveries obtained by the column method were quantitative ( >95%) at optimum conditions.The method was applied to the determination of some metal ions in seawater and wastewater samples. A high preconcentration factor (about 150 for seawater and 75 for wastewater samples) and simplicity are the main advantages of this suggested method.

• Journal of Welding and Joining
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• v.28 no.5
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• pp.64-68
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• 2010

The purpose of this study is to develop the control technology of global distortion in the deck of superstructures during manufacturing processes. The behavior of global distortion in the deck was evaluated by FEA and verified through comparing with the measured results by 3D measuring instrument. It was seen from the results that the principal factor inducing the global distortion is to be the bending moment associated with the longitudinal shrinkage force and transverse shrinkage caused by welding of stiffeners and flame heating to correct the excessive local out-of-plane distortion. Based on the results, the amount of reverse distortion in the thin deck plate was determined to control the global distortion in the deck plate. The proposed distortion control technology was verified by applying it to the actual structure.

• Journal of the korean Society of Automotive Engineers
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• v.13 no.5
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• pp.89-94
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• 1991

In the quantitative analysis of oxygenated exhaust emissions (unburned methanol, formal- dehyde) from methanol fueled vehicles, the oxygen contained in oxygenated exhaust gases lowers the FID (Flame Ionization Detector) response factor of conventional THC analyzer and leads to erroneous HC reading. For correct measurement of various HCs including oxygenated HCs emitted from FFV(Flexible Fuel Vehicle), first of all, the measurement technique of real HC emissions should be established. GC and HPLC-DNPH measuring methods specified by the EPA are used in this paper to analyze unburned methanol and formaldehyde components in the exhaust emissions. In emission test of FFV, unburned methanol and formaldehyde are emitted mostly during cold transient period, and it is shown that formaldehyde emission level is proportional to engine displacements. In view of the HC emission level, vehicle using M85 has 40% advantage over gasoline-fueled vehicle in OMHCE and has a good potential of a low emission vehicle.

• Bulletin of the Korean Chemical Society
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• v.23 no.4
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• pp.545-549
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• 2002

A simple and rapid technique for the separation and preconcentration of lead in water and biological samples has been devised. Preconcentrationis based on the depositionof analyte onto a column packed with dithizone immobilized on sodium dodecyl sulfate coated alumina at pH $\geq$ 3. The trapped lead is eluted with 5 mL of 4 M nitric acid and determined by flame atomic absorption spectroscopy. A sample of 1 L, results in a preconcentration factor of 200 and the precision at 20${\mu}g$ $L^{-1}$ is 1.3%(n=8). The procedure is applied to tap water, well water, river water, vegetable extract and milk samples, and accuracy is assessed through recovery experiments and by independent analysis by furnace atomic absorption.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.519-524
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• 2008

A numerical study is conducted to investigate propulsion performance enhancement based on S225 experiment case of ISL(French-German Research Institute of Saint-Louis)'s superdetonative ram accelerator. For govern equation, multi-species Navier-Stokes equation coupled with Baldwin-Lomax turbulence modeling is used. Govern equation is discretized by Roe's FDS and integrated by LU-SGS time integration. Detailed chemical reaction about $H_2/O_2/CO_2$ for high pressure is considered. $2H_2+O_2+2.5CO_2$ mixture was used for propellant gas. For the same over-driven factor, the launching speed of computation was faster than one of S225. Another configuration and condition of S225 was applied. A flame structure is very different from S225. For strong mixture case, it shows ignition by viscous effect. Acceleration and speed increment is higher than S225 computation and experiment. By using more strong mixture, propulsion performance was enhanced.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.26 no.3
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• pp.31-38
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• 2003

There is boner process of stone manufacturing to become quality down of stone to consolidated micro crack appearance of stone surface and biotite by fire that is to be route process in stone surface by flame of LPG. And then, it is develop that stone surface process equipment by automation for the work method of boner process can be substitute work method by water jet To development of equipment, There is to be down noise and dust. According to remove calamity growth hazardous substance in the work environment, there is to solve workplace avoidance factor.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.111-112
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• 2020

In the case of, the ignition of flammable external materials by the radiant flame and the accompanying fire in the upper layer are occurring every year, and in the case of the Flashover prediction formula, the limit is reached through the surface area of the space and the factor. Predicts heat release rate. In this study, the critical heat release rate of each prediction formula was calculated based on the ISO 9705 model.

• Journal of the Korean Chemical Society
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• v.52 no.2
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• pp.155-163
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• 2008

.A simple and reproducible method for the rapid extraction and determination of trace amounts of copper(II) ions using mesoporous organo-silicas mesoporous silica and atomic absorption spectrometry is presented. Common coexisting ions did not interfere with the separation and determination. The preconcentration factor was 100 (1 ml elution volume) for a 100 ml sample volume. The limit of detection of the proposed method is 1.0 ng ml-1. The maximum sorption capacity of sorbent under optimum conditions has been found to be 5mg of copper per gram of sorbent. The relative standard deviation under optimum conditions was 2.8% (n=10). Accuracy and application of the method was estimated by using test samples of natural and synthetic water spiked with different amounts of copper(II) ion.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.3
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• pp.751-767
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• 1994

Recent developments of S.I. engine, aiming to higher power, better fuel economy, lower air pollution and better driveability, have much focused on the importance of the role of computer simulation in engine research and development. In this point of view, improving engine performance requires finding some means to improve volumetric efficiency. Up to now there have been several attempts to optimize the intake and exhaust system of internal system of S.I. engine by computer simulation. There appear to be few studies available, however, of such simulation & experimental studies applied to the optimization of exhaust manifold configuration. In this study, gas exchange & power process of 4 cylinder S.I. Engine was studies numerically & experimentally, and governing equation of a one-dimensional unsteady compressible flow and combustion process were respectively solved by a characteristics method and 2-zone model. The aim of this study is to predict and investigate the influence of pressure wave interaction at the exhaust systems on engine performance with widely differing exhaust manifold configuration.

• Bulletin of the Korean Chemical Society
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• v.27 no.5
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• pp.725-732
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• 2006

A rapid flotation methodology for zinc(II) separation and enrichment from human biofluids is established. At pH 6.0 and ambient temperature, using oleic acid (HOL) as a foaming reagent, zinc(II) was separated with phenanthraquinone monophenyl thiosemicarbazone (PPT) as a new flotation collector for Zn(II). The floated red colored 1 : 2 Zn(II)-PPT complex was measured spectrophotometrically at 526 nm with a molar absorptivity of $1.83 \;{\times}\; 10^5\; L$ mol $L ^{-1}\;cm ^{-1}$. Beer's law was obeyed over a concentration range 0.05-1.0 mg $L ^{-1}$ in the aqueous as well as in the scum layers. The proposed preconcentration flotation methodology was applied to determine Zn(II) in human biofluids. Application was, also, extended to determine Zn(II) in pharmaceutical samples and natural water samples spiked with known amounts of Zn(II) with a preconcentration factor of 100 and a detection limit of 10 ng m$L ^{-1}$. The method was verified by comparison of the spectrophotometric results with flame atomic absorption spectrometric (AAS) measurements. Moreover a postulation for the mechanism of flotation is proposed.