• 제목/요약/키워드: Flake graphite

검색결과 54건 처리시간 0.021초

CV흑연주철(黑鉛鑄鐵)에서의 표면응고층(表面凝固層) 생성(生成)에 관(關)한 연구(硏究) (A study on the formation of surface solidification layer in compacted/vermicular graphite cast iron)

  • 박기성;이상익;김수영
    • 한국주조공학회지
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    • 제6권1호
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    • pp.20-26
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    • 1986
  • In order to investigate the solidification characteristics of CV. graphite cast iron, decantation technique and thermal analysis test were used. Solidification characteristics were studied in the specimens with various compositions and graphite shape. The results were as follows; 1. The first surface solidifcation layer is formed along the mold wall by the growth of austenite dendrites in hypoeutectic composition and thin solid film in hypereutectic composition. 2. The mushy degree of solidifcation of hypereutiectic composition is higher than that of hypoeutectic. 3. In hypoeutectic, the effect of change of the mushy degree of solidification on the graphite shape is small, however, in hypereutectic the mushy degree of solidification becomes higher in order of flake, CV, and spheroidal graphite cast iron.

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고(高)알루미늄 내열주철(耐熱鑄鐵)에서의 흑연구상화(黑鉛球狀化)와 내산화성(耐酸化性)에 관한 연구(硏究) (A Study on the Graphitization and Scaling Resistance property of High Al-Cast Iron)

  • 김동규;나형용
    • 한국주조공학회지
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    • 제1권2호
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    • pp.2-9
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    • 1981
  • Graphite spheroidization and scaling resistance of cast iron containing 5-10% Al were investigated. It is impossible to obtain spheroidal graphite in cast iron containing Al with 8 % and over, but possible to obtain spheroidal graphite even in cast iron with an Al content of about 10 % by increasing Si content. In the scaling test carried out under the heating condition of $950^{\circ}C$ in air for total of 50 hours, the scaling resistance of cast iron containing Al with 8 % and over was remarkably superior, and also spheroidal graphite cast iron was superior to flake graphite cast iron. The scale became thinner more compacts and more protective with increasing Al content.

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PEMFC용 복합소재 분리판을 위한 2단계 제조공법의 제조 조건에 대한 연구 (A study on fabrication condition of the 2-step manufacturing method for PEMFC composite bipolar plates)

  • 허성일;오경석;윤진철;양유창;한경섭
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.146-149
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    • 2007
  • The 2-step manufacturing method consisting of preforming and stamping processes was developed to manufacture composite bipolar plates for PEMFCs. The preform was composed of expanded graphite, graphite flake and phenol resin. Precuring conditions were optimized by checking the electrical conductivity, flexural strength and microstructure. Precuring temperature ($100^{\circ}C$) slightly above the melting point of phenol powders ($90^{\circ}C$) induced moderate curing, but also prevented excessive curing. Preforms utilizing the tangled structure of expanded graphite were easily fabricated at low pressure of 0.07-0.28MPa. The proper precuring time, 5min, was determined to fabricate the preform stably because insufficient and excessive precuring deteriorated the flexural strength of composite bipolar plates.

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금형재료용 주철의 다이오드 레이저 표면경화처리에 관한 연구(I) - 금형재료에 따른 표면경화 특성 - (A Study on the Diode Laser Surface Hardening Treatment of Cast Iron for Die Material(I) - Characteristics of Surface Hardening by Die Materials -)

  • 김종도;송무근;황현태
    • Journal of Advanced Marine Engineering and Technology
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    • 제35권8호
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    • pp.1041-1047
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    • 2011
  • 본 연구에서는 거의 모든 기반산업에서 필수적인 생산기술로 사용되고 있는 금형의 기계적 성질을 향상시키기 위해 고출력 다이오드 레이저를 이용하여 두 종류의 금형재료용 주철을 표면경화처리하였다. 우선, 구상흑연 주철인 FCD550 소재에 대하여 열처리 특성을 파악한 후, 편상흑연 주철인 HCI350 소재를 열처리하여 두 소재의 표면경화 특성을 비교하였다. 경화부의 경도는 두 시험편 모두 모재에 비해 3배 이상의 경도 상승을 보였지만, 재료에 포함된 흑연의 함유량 및 형상의 차이에 의한 재료의 열전도도에 따라서 FCD550 소재에 비해 HCI350이 열처리하는데 있어서 더 많은 입열이 요구되었다.

자동차 브레이크용 디스크의 미세조직에 따른 편마모 특성에 관한 연구 (Wear Characteristics of Automotive Disc Brakes: Effect of Gray Cast Iron Microstructures)

  • 이재영;김성진;한창주;장호
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 제35회 춘계학술대회
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    • pp.235-239
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    • 2002
  • The objective of the experiment is to investigate the effect of microstructures of gray cast iron oil wear characteristics of automotive disc brakes. Six different gray cast iron rotors were manufactured by changing carbon equivalent and cooling rate. The change of DTV (disc thickness variation) before and after wear tests was measured to examine the wear properties according to the microstructures of gray iron discs since the DTV generation is caused by the circumferential uneven wear. Experimental results showed that the morphology of graphite flake and hardness in gray cast iron were crucially associated with the change of DTV. In particular, the DTV changes of rotor decrease when the length and area fraction of graphite flake in brake rotors increase and hardness of brake discs reduces.

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3.9%C 회주철의 진동감쇠능 및 기계적 성질에 미치는 합금원소 첨가의 영향 (Effects of Alloying Elements on the Damping Capacities and Mechanical Properties in 3.9%C Gray Cast Iron)

  • 김정철;손용철;한동운;백승한
    • 열처리공학회지
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    • 제10권1호
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    • pp.47-54
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    • 1997
  • Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occuring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of Ni on the damping capacities and mechanical properties are investigated in 3.9%C-0.3% Cu gray cast iron. At 0.2% Ni content, specific damping capacity showed the maximum value, and decreased with further increase in Ni content, Graphite continuity also showed same behavior. This indicates that the specific damping capacity has a close relation with graphite continuity. On the other hand, the damping capacity in pearlite matrix showed superior to that in ferrite. In contrast, with increasing the Ni content, both tensile strength and hardness increased due to the decrease of graphite length and eutectic cell size.

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Preparation of zirconia coated graphite powders

  • Kim, J.H.;Lee, K.G.;Lee, S.K.
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1997년도 Proceedings of the 12th KACG Technical Meeting and the 4th Korea-Japan EMGS (Electronic Materials Growth Symposium)
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    • pp.45-48
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    • 1997
  • ZrO$_2$ coated flake graphite powders were prepared by the controlled hydrolysis of zirconium oxichloride. The stirring process plays an important role in the coating process. There are two types of coated ZrO$_2$ particles: (a)primary particles with few nm size were obtained by the direct formation of the shell by precipitation of the surface of the graphite and (b) Secondary particles of ZrO$_2$ with ∼0.1$\mu\textrm{m}$ size were obtained by the independent formation of primary particles ZrO$_2$ and subsequent heterocoagulation at the graphites surface.

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인산형 연료전지 분리판용 천연흑연-불소수지계 복합재료의 흑연입도에 따른 전기비저항 변화 (Electrical Resistivity of Natural Graphite-Fluorine Resin Composite for Bipolar Plates of Phosphoric Acid Fuel Cell(PAFC) Depending on Graphite Particle Size)

  • 이상민;백운경;김태진;노재승
    • 한국재료학회지
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    • 제27권12호
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    • pp.664-671
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    • 2017
  • A composite material was prepared for the bipolar plates of phosphoric acid fuel cells(PAFC) by hot pressing a flake type natural graphite powder as a filler material and a fluorine resin as a binder. Average particle sizes of the powders were 610.3, 401.6, 99.5, and $37.7{\mu}m$. The density of the composite increased from 2.25 to $2.72g/cm^3$ as the graphite size increased from 37.7 to $610.3{\mu}m$. The anisotropy ratio of the composite increased from 1.8 to 490.9 as the graphite size increased. The flexural strength of the composite decreased from 15.60 to 8.94MPa as the graphite size increased. The porosity and the resistivity of the composite showed the same tendencies, and decreased as the graphite size increased. The lowest resistivity and porosity of the composite were $1.99{\times}10^{-3}{\Omega}cm$ and 2.02 %, respectively, when the graphite size was $401.6{\mu}m$. The flexural strength of the composite was 10.3MPa when the graphite size was $401.6{\mu}m$. The lowest resistance to electron mobility was well correlated with the composite with lowest porosity. It was possible the flaky large graphite particles survive after the hot pressing process.

Phenylethynyl-terminated polyimide, exfoliated graphite nanoplatelets, and the composites: an overview

  • Cho, Donghwan;Drzal, Lawrence T.
    • Carbon letters
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    • 제19권
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    • pp.1-11
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    • 2016
  • In efforts to characterize and understand the properties and processing of phenylethynyl-terminated imide (LaRC PETI-5, simply referred to as PETI-5) oligomers and polymers as a high-temperature sizing material for carbon fiber-reinforced polymer matrix composites, PETI-5 imidization and thermal curing behaviors have been extensively investigated based on the phenylethynyl end-group reaction. These studies are reviewed here. In addition, the use of PETI-5 to enhance interfacial adhesion between carbon fibers and a bismaleimide (BMI) matrix, as well as the dynamic mechanical properties of carbon/BMI composites, are discussed. Reports on the thermal expansion behavior of intercalated graphite flake, and the effects of exfoliated graphite nanoplatelets (xGnP) on the properties of PETI-5 matrix composites are also reviewed. The dynamic mechanical and thermal properties and the electrical resistivity of xGnP/PETI-5 composites are characterized. The effect of liquid rubber amine-terminated poly(butadiene-co-acrylonitrile) (ATBN)-coated xGnP particles incorporated into epoxy resin on the toughness of xGnP/epoxy composites is examined in terms of its impact on Izod strength. This paper provides an extensive overview from fundamental studies on PETI-5 and xGnP, as well as applied studies on relevant composite materials.