• 한국환경과학회지
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• 제26권7호
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• pp.859-868
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• 2017

In this study, the reductive dechlorination of triclosan using zero-valent iron (ZVI, $Fe^0$) and modified zero-valent iron (i.e., acid-washed iron (Aw/Fe) and palladium-coated iron (Pd/Fe)) was experimentally investigated, and the reduction characteristics were evaluated by analyzing the reaction kinetics. Triclosan could be reductively decomposed using zero-valent iron. The degradation rates of triclosan were about 50% and 67% when $Fe^0$ and Aw/Fe were used as reductants, respectively, after 8 h of reaction. For the Pd/Fe system, the degradation rate was about 57% after 1 h of reaction. Thus, Pd/Fe exhibited remarkable performance in the reductive degradation of triclosan. Several dechlorinated intermediates were predicted by GC-MS spectrum, and 2-phenoxyphenol was detected as the by-product of the decomposition reaction of triclosan, indicating that reductive dechlorination occurred continuously. As the reaction proceeded, the pH of the solution increased steadily; the pH increase for the Pd/Fe system was smaller than that for the $Fe^0$ and Aw/Fe system. Further, zero-order, first-order, and second-order kinetic models were used to analyze the reaction kinetics. The first-order kinetic model was found to be the best with good correlation for the $Fe^0$ and Aw/Fe system. However, for the Pd/Fe system, the experimental data were evaluated to be well fitted to the second-order kinetic model. The reaction rate constants (k) were in the order of Pd/Fe > Aw/Fe > $Fe^0$, with the rate constant of Pd/Fe being much higher than that of the other two reductants.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2002년도 ICCAS
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• pp.46.3-46
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• 2002

Most of the process control algorithms in practice are based on the finite dimensional control theory. However, many chemical processes are described by partial differential equations (PDE's) and are infinite dimensional in nature due to spatial variation. Especially when the convection is dominant and thus diffusion can be ignored, chemical processes that are described by a system of first order hyperbolic PDE's. Such processes include tubular reactors, fixed bed reactors and pressure swinging adsorption. Conventionally such infinite dimensional systems described by PDE's are controlled by finite dimensional controllers that are designed through finite dimensional reduction of the process m...

• Communications for Statistical Applications and Methods
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• 제28권6호
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• pp.595-610
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• 2021

Recently a few articles have derived robust first-order rotatable and D-optimal designs for the lifetime response having distributions gamma, lognormal, Weibull, exponential assuming errors that are correlated with different correlation structures such as autocorrelated, intra-class, inter-class, tri-diagonal, compound symmetry. Practically, a first-order model is an adequate approximation to the true surface in a small region of the explanatory variables. A second-order model is always appropriate for an unknown region, or if there is any curvature in the system. The current article aims to extend the ideas of these articles for second-order models. Invariant (free of the above four distributions) robust (free of correlation parameter values) second-order rotatable designs have been derived for the intra-class and inter-class correlated error structures. Second-order rotatability conditions have been derived herein assuming the response follows non-normal distribution (any one of the above four distributions) and errors have a general correlated error structure. These conditions are further simplified under intra-class and inter-class correlated error structures, and second-order rotatable designs are developed under these two structures for the response having anyone of the above four distributions. It is derived herein that robust second-order rotatable designs depend on the respective error variance covariance structure but they are independent of the correlation parameter values, as well as the considered four response lifetime distributions.

• 대한안전경영과학회지
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• 제3권3호
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• pp.97-106
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• 2001

This paper considers automated storage and retrieval systems with double shuttle. We developed the expected travel time model based on the first come first served rule. An heuristic procedure by retrieval order sequencing was presented which aimed to improve the operation efficiency laking advantage of ＂No cost zone＂. Through sensitivity study, we evaluated the performance of the double shuttle system working on the four command cycle.

• Membrane and Water Treatment
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• 제8권1호
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• pp.73-88
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• 2017

Adsorption kinetics of aqueous ferric ion ($Fe^{3+}$) onto bio-natural rice grains (BRG) have been studied in a batch system. The influence of contact time (0-180 minutes), the dosage of BRG adsorbent (10, 20, 40, and $60gL^{-1}$), and ambient temperature (27, 37, 47, and $57^{\circ}C$) for the adsorption system have been reported. The equilibrium time achieved after 20 minutes of adsorption contact time. The maximum removal of ferric ion is 99% by using $60gL^{-1}$ of BRG, $T=37^{\circ}C$, and $50mgL^{-1}$ ferric ion solution. Adsorption kinetic and diffusion models, such as pseudo-first order, pseudo-second order, and Weber-Morris intra-particle diffusion model, have been used to describe the adsorption rate and mechanism of the ferric ion onto BRG surface. The sorption data results are fitted by Lagergren pseudo-second order model ($R^2=1.0$). The kinetic parameters, rate constant, and sorption capacities have been calculated. The new information in this study suggests that BRG could adsorb ferric ion from water physiosorption during the first 5 minutes. Afterward, the electrostatic interaction between ferric ion and BGR-surface could take place as a very weak chemisorptions process. Thus, there is no significant change could be noticed in the FTIR spectra after adsorption. I recommend producing BGR as a bio-natural filtering material for removing the ferric ion from water.

• 대한전기학회논문지
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• 제36권9호
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• pp.660-669
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• 1987

Routh approximation method is the most computationally attractive. But this method may cause time-response error because this method does not match the time-response directly. In this paper a new mixed method for obtaining stable reduced-order models for high-order continuous-time systems is proposed. It makes use of the advantages of the Routh approximation method and the Minimization of Integral Squared Error(MISE) criterion approach. In this mixed method the characteristic polynomial of the reduced-order model is first obtained from that of original system by using the Auxiliary Denominator Polynomial(ADP). The numerator polynomial is then determined so as to minimize the intergral squared-error of unit step responses. The advantages of the propsed method are that the reduced models are always stable if the original system are stable and the frequency domain and time domain characteristic of the original system will be preserved in the reduced models.

• Bulletin of the Korean Chemical Society
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• 제18권11호
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• pp.1199-1203
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• 1997

The investigation of cure kinetics of biphenyl epoxy (4,4-diglycidyloxy-3,3,5,5-tetramethyl biphenyl)-xylok resin system with four different catalysts was performed by differential scanning calorimeter using an isothermal approach. All kinetic parameters of the curing reaction including the reaction order, activation energy and rate constant were calculated and reported. The results indicate that the curing reaction of the formulations using triphenylphosphine (TPP) and 1-benzyl-2-methylimidazole (1B2MI) as a catalyst proceeds through a first order kinetic mechanism, whereas that of the formulations using diazabicyloundecene (DBU) and tetraphenyl phosphonium tetraphenyl borate (TPP-TPB) proceeds by an autocatalytic kinetic mechanism. To describe the cure reaction in the latter stage, we have used the semiempirical relationship proposed by Chern and Poehlein. By combining an nth order kinetic model or an autocatalytic model with a diffusion factor, it is possible to predict the cure kinetics of each catalytic system over the whole range of conversion.

• Ocean Systems Engineering
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• 제12권3호
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• pp.359-384
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• 2022

We develop in this work a new well-balanced preserving-positivity path-conservative central-upwind scheme for Saint-Venant-Exner (SVE) model. The SVE system (SVEs) under some considerations, is a nonconservative hyperbolic system of nonlinear partial differential equations. This model is widely used in coastal engineering to simulate the interaction of fluid flow with sediment beds. It is well known that SVEs requires a robust treatment of nonconservative terms. Some efficient numerical schemes have been proposed to overcome the difficulties related to these terms. However, the main drawbacks of these schemes are what follows: (i) Lack of robustness, (ii) Generation of non-physical diffusions, (iii) Presence of instabilities within numerical solutions. This collection of drawbacks weakens the efficiency of most numerical methods proposed in the literature. To overcome these drawbacks a reformulation of the central-upwind scheme for SVEs (CU-SVEs for short) in a path-conservative version is presented in this work. We first develop a finite-volume method of the first order and then extend it to the second order via the averaging essentially non oscillatory (AENO) framework. Our numerical approach is shown to be well-balanced positivity-preserving and shock-capturing. The resulting scheme could be seen as a predictor-corrector method. The accuracy and robustness of the proposed scheme are assessed through a carefully selected suite of tests.

• 전기학회논문지
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• 제65권4호
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• pp.652-658
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• 2016

In practical control systems differences between nominal and real systems arise from internal uncertainties and/or external disturbances. This paper presents a model-based low-order disturbance observer for a sinusoidal disturbance with unknown constant offset. By using the disturbance model of a biased harmonic signal, the proposed method can successfully estimate the biased sinusoidal disturbance with unknown amplitude and phase but known frequency. At the first stage of the observer design, a model-based disturbance observer is designed when all the system states are measurable. Next, a sufficient condition is presented for the proposed observer to estimate the sinusoidal disturbance with a minimal-order additional dynamics using only output measurement. Comparative computer simulations are performed to test the performance of the proposed method. The simulation results show the enhanced performance of the proposed disturbance observer.

• Journal of Biosystems Engineering
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• 제12권1호
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• pp.31-38
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• 1987

In order to improve the traditional post harvest system in Korea, a model for mechanized rice drying and storage system was developed and introduced as the first part of the study(Park, 1986). As the second part of the study, capital requirement and cost of the model system was analyzed. Also, optimum size of the model system was estimated by comparing with the traditional harvest system. From the study, the following results can be concluded: 1. The capital requirement of the model system decreases as the model size increases. For example, a model system having 500 ton storage capacity requires 439,000 Won/ton. However it requires 313,200 Won/ton only, if the model size increases to 1000 ton. 2. Also, total cost of the model system decreases as the model size increases. For example, total costs of the model system having 500 ton and 1000 ton storage capacity are 101,208 Won/ton and 69,320 Won/ton, respectively. 3. The breakeven point (optimum size) of the model can be estimated around 630 ton storage capacity if the operation rate is assumed as 100%. However, the optimum size of the model is 710 ton, if the operation rate it assumed 80%.