• Journal of the Korean Institute of Gas
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• 제9권2호
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• pp.1-7
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• 2005

The thermochemical parameters for safe handling, storage, transport, operation and process design of flammable substances are explosive limit, flash point, autoignition temperature, minimum oxygen concentration, heat of combustion etc.. Explosive limit and autoignition temperature are the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limit and autoignition temperature of methane fur LNG process safety were investigated. By using the literatures data, the lower and upper explosive limits of methane recommended 4.8 vol$\%$ and 16 vol$\%$, respectively. Also autoignition temperatures of methane with ignition sources recommended $540^{\circ}C$ at the electrically heated cruicible furnace (the whole surface heating) and recommended about $1000^{\circ}C$ in the local hot surface. The new equations for predicting the temperature dependence and the pressure dependence of the lower explosive limits for methane are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

• Journal of the Korean Institute of Gas
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• 제3권1호
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• pp.8-13
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• 1999

The article 49-2 of Industrial Safety Law requires that all the owners of industrial plants which contains dangerous facilities perform the process safety management. That is, this law requires the owners of industrial plants to take necessary measures to prevent fire, harmful gas leaking, explosion, and other serious accidents that could cause demage and injuries to the employees. So far, domestic chemical plants have tried to invest money and time in safety management. But, such efforts have been made only in chemical plants that were subsidiaries of large business groups. Moreover, since the economic crisis of Korea which is symbolized by the IMF bailout, small and medium size companies could not afford to invest in safety management. Their major concern is to increase productivity and thereby, survive in this crisis. The goal of this research is to develop the process safety management system that can help small and medium size companies to positively secure the process safety management. So, in developing the process safety management system, the financial and practical difficulties of such companies are fully taken into consideration.

• Journal of the Korean Society of Safety
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• 제26권3호
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• pp.15-22
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• 2011

Explosion and fire cause about 30 reported industrial major accidents a year by ignition source which discharge of electrostatic generated to flammable gas, vapor, dust and mixtures. It brings economically and humanly very large loss that accident was caused by fire and explosion from electrostatic discharge. Thus, it is very important that electrostatic discharge energy is to be control below not to be igniting flammable mixtures. There are two kinds of analysis model for electrostatic discharge, human body model and machine model. Human body model is available the parameter of human's electrical equivalent that capacitance is 100 pF, resistance is $1.5k{\Omega}$. To simulate and visualize the electrostatic discharge from human body need a very expensive and high voltage simulator. In this paper, we measured the value of capacitance and resistance concerned with test materials and sizing of specimen and the value of charged voltage concerned with test specimen and distance to develop an electrostatic charge/discharge simulating tool for teaching with which concerned industrial employee and students. The result of experiments, we conformed that the minimum ignition energy of methane-oxygen mixtures meets well the equation $W=1/2CV^2$, and found out that the insulating material and sizing of equivalent value having human body mode are the poly ethylene of 200 mm and 300 mm of diameter. Developed electrostatic charge/discharge simulating tool has many merits; simple mechanism, low cost, no need of electric power and so on.

• Journal of the Korean Institute of Gas
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• 제24권4호
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• pp.32-38
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• 2020

Based on the cases of fire and explosion accident in the chemical reactor, thr problems of preventive measures installed in the chemical reactor were analyzed. The chemical reactors produce a variety of chemicals and install rupture disk to relieve the pressure that rises sharply in the event of a runaway reaction. In order to maintain the function of the rupture disk, the emissions was allowed to be discharged into the atmosphere, resulting in fire and explosion accidents. As a way to improve this, safety instrumented system based on the safety integrity level(SIL3) was applied as a preventive measures for chemical reactor. Two emergency shur-off valves are installed in series on pipe dropping raw materials for chemical reactor so that the supply of raw materials can be cut off even if only one of the two emergency shut-off valves is operated during the runaway reaction. The automatic on/off valve is installed in parallel in the supply pipe of the reaction inhibitor so that the reaction inhibitor can be injected even if only one valve is opened at the time of the runaway reaction.

• Journal of the Korean Institute of Gas
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• 제22권6호
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• pp.1-7
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• 2018

Currently chemical plant risk have been issued by occurring frequent accidents. Accidents can be generally composed of fire, explosion, release in chemical plant. In case of fire and explosion, accident victims are occurred immediately after accident but release accident, late emergency response cause damage to worker. Especially, there are many victims by late emergency response against chemical exposure to skin. In case of chemical exposure to skin, irreversible damage like death, blindness, burn can be prevented by washing immediately. Safety shower can provide the cleaning for chemical exposure to eye, skin. Most of chemical plants are built in 1980s so equipment become superannuated. In this reason, safety shower also cannot operate normally in emergency situation. Therefor safety shower should be managed by installation and management guideline. This study perform the establishment guideline for safety shower installation and inspection to increase the reliability.

• Journal of Convergence for Information Technology
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• 제11권7호
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• pp.84-90
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• 2021

98.8% of accidents occurring in domestic companies are concentrated in small-sized workplaces with fewer than 50 employees. Therefore, this study developed a disaster safety program that can be implemented by small and medium-sized enterprises by comparing and analyzing the safety management system actively used with the laws and regulations related to industrial safety and facilities. The disaster and safety program included the scope of application, organizational structure, risk assessment, emergency response system, education and training, safety equipment provision and program evaluation, and detailed preparation methods and procedures for each item. In addition, items to be aware of when operating a disaster safety program and operational strategies were presented. After that, it was proposed to introduce the research results into the Occupational Safety and Health Act.

• Journal of the Korean Society of Safety
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• 제36권1호
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• pp.64-71
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• 2021

Experimental and analytical investigations are performed to explore the explosion characteristics of a hydrogen-air mixture in open atmosphere. A hydrogen-air mixture tent of total volume of 27 m³, with 40% hydrogen volume, is used to observe overpressure at a distance from the ignition source. Vapor cloud explosion analyses are performed using the TNO multi-energy model and Baker-Strehlow-Tang model. The results of these analyses are compared with experiment done from this study and references. The experimental results with and without obstacles indicate that the overpressure values measured at a distance of 4.5-21.5 m from the ignition source are about 9.4-3.6 kPa and 6.5-2 kPa, respectively. This implies that the overpressure with obstacles is approximately 1.7 times greater than that without obstacles. Analytical observation indicates that the results obtained with the Baker-Strehlow-Tang model with M_f = 0.2-0.35 are in good agreement with those of most of the previous studies, including that obtained from this study. Moreover, the TNO multi-energy model with a volume of 27 m³ well predicts the overpressure obtained from this study. Further studies should considered explosions in semi-confined spaces, which is more suitable for hydrogen refueling stations.

• Journal of the Korean Society of Safety
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• 제35권6호
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• pp.78-84
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• 2020

The F&EI technique is one of the risk assessments with many advantages. It can save time and effort compared to quantitative risk assessment (QRA). By using the evaluation result of this technique, it is possible to check the effectiveness of the investment cost. In addition, a relative risk ranking can be created and used to establish the facility management cycle and to prioritize investment. However, evaluating the target process can be evaluated more than the actual risk since the LCCF, a loss prevention measure, is too limited. In addition, calculating premiums via this method can result in excessive premiums, making it difficult to evaluate the risk precisely. Therefore, new safety guard was added to the LCCF of the F&EI risk assessment with reference to HAZOP and LOPA techniques. Newly added LCCFs are Deflagration arrester, Check valve, SIS, and Vacuum beaker, etc. As a case study, F&EI risk assessment was performed on Acetone storage tank of a API (Active pharmaceutical ingredient) plant to compare actual MPPD. The estimated loss amount was 592,558$ for the existing technique and 563,571$ for the improved technique, which was reduced by about 5% compared to the previous one.This proved that a more precise evaluation is possible and that the efforts for safety at the workplace are reflected in the evaluation results.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 한국항해항만학회 2019년도 추계학술대회
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• pp.268-268
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• 2019

The purpose of this study is to understand the risk of chemical product, Styrene Monomer(SM), shipped in a vessel. SM is harmful chemical product which can make injury, explosion and/or fire in a vessel. The understand of SM risk is very important to protect seafarer's body and vessel safety. This research can be expected that the understanding of SM risk by a seafarer's to prevent accidents by SM explosion and/or fire.

• Journal of the Korean Institute of Gas
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• 제27권4호
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• pp.1-11
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• 2023

The size of the OLED material market is expected to grow from $1.1 billion in 2019 to $2.3 billion in 2023, with an average annual sustainable growth of more than 19%. Among the facilities mainly used by OLED material manufacturers, accidents such as fire, explosion, and leakage frequently occur when using filtration equipment, so it is necessary to improve the risk when using filtration equipment. In this study, it was divided into four main processes, namely, assembly and disassembly process, filtration process, wet cake recovery process, and washing process in order to derive the risks associated with the use of filtration equipment. Hazard factors were derived by conducting accident case investigations, preliminary interviews, and surveys. For the analysis of questionnaire results, statistical analysis such as frequency analysis and Pearson chi-square test analysis was performed using SPSS 21, and risk improvement measures were suggested using the analyzed results. It is expected that this study will serve as a basis for dealing with safety and risk factors that may occur as the size of the OLED market expands.