• Journal of the Korean Institute of Gas
• /
• v.9 no.4 s.29
• /
• pp.50-56
• /
• 2005

Liquefied Petroleum 6aso-PG) is combustible gas which used for fuel for domestic and automobiles. A research for adjust a component of LPG to improve the fuel characteristics and control the manufacturing process of that is carrying in petrochemical industry. Some kinds of LPG blending is considered as a adjusting method to control component of LPG. LPG is mainly propane for domestic use and butane for automobile use but propylene and butylene also a kind of LPG Change of explosion characteristic and combustion gas component by mixing of propylene in propane and butane was measured and analysed in this research. Based on the result of experiment, it was found that explosion pressure and pressure rise rate was slightly increased with mixing rate of propylene and it was considered the possibility of increasing the CO concentration in combustion gas with increase the mixing rate of propylene.

• Journal of the Korean Society of Safety
• /
• v.25 no.3
• /
• pp.53-60
• /
• 2010

LPG(Liquefied Petroleum Gas) vehicles in metropolitan area are being applied to improve air quality and have been proven effective for the reduction of air pollutant. In addition, LPG demand is growing rapidly as an environmentally friendly energy source and its gas station is also increasing every year. Consequently, this study tries to find out the influence of flame caused by the VCE(Vapor Cloud Explosion) in filling station on the adjacent combustibles and people by simulating relevant quantity of TNT. In addition, the damage estimation was conducted by using API regulations. If the scale of the radiation heat is known by calculating the distance of flame influence from the explosion site, the damage from the site can be easily estimated. And the accident damage was estimated by applying the influence on the adjacent structures and people into the PROBIT model. According to the probit analyze, the spot which is 30m away from the flame has 100% of the damage probability by the first-degree burn, 99.2% of the damage probability by the second-degree burn and 93.4% of the death probability by the fire.

• Journal of Energy Engineering
• /
• v.28 no.4
• /
• pp.42-47
• /
• 2019

In this study, combustion characteristics were measured by selecting di-n-buthylamine, which is widely used as an emulsifier, insecticide, additive, rubber vulcanization accelerator, corrosion inhibitor, and raw material for dye production. The flash point of the di-n-buthylamine was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of the di-n-buthylamine was measured by ASTM 659E. The explosion limits of the di-n-buthylamine was calculated using the measured flash points by Setaflash tester. The flash point of the di-n-buthylamine by using Setaflash and Pensky-Martens closed-cup testers were experimented at 38 ℃ and 43 ℃, respectively. The flash points of the di-n-buthylamine by Tag and Cleveland open cup testers were experimented at 48 ℃. The AIT of the di-n-buthylamine was experimented at 247 ℃. The LEL and UEL calculated by using lower and upper flash points of Setaflash tester were calculated at 0.69 vol% and 7.7 vol%, respectively. The measurement of the flash point measurement and the calculation method of the explosion limit prediction presented in this study can be used to study the fire and explosion characteristics of the other combustible liquids.

• Journal of the Korean Society of Safety
• /
• v.35 no.6
• /
• pp.25-31
• /
• 2020

Boiling Liquid Expanding Vapor Explosion(BLEVE) can cause not only economic damage to the plant but also serious casualties. LPG accidents account for 89.6 percent of all accidents caused by gas leaks in Korea over the past nine years, while casualties from accidents also account for 73 percent of all accidents, according to statistics from the Korea Gas Safety Corporation. In addition, a potential explosion and a fire accident from one LPG storage tank may affect the nearby storage tanks, causing secondary and tertiary damage (domino effect). The safety distance standards for LPG used by LPG workplaces, charging stations, and homes in Korea have become stricter following the explosion of LPG charging stations in Bucheon. The safety distance regulation is divided into regulations based on the distance damage and the risk including frequency. This study suggests two approaches to optimizing the safety distance based on the just consequence and risk including frequencies. Using the Phast 7.2 Risk Assessment software by DNV GL, the explosion overpressure and heat radiation were derived according to the distance caused by BLEVE in the worst-case scenario, and accident and damage probability were derived by considering the probit function and domino effect. In addition, the safety distance between LPG tanks or LPG charging stations was derived to minimize damage effects by utilizing these measures.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.23 no.1
• /
• pp.47-60
• /
• 2021

Hydrogen is a next-generation energy source, and according to the roadmap for activating the hydrogen economy, it is expected that industries to stably produce, store, and transport of hydrogen as well as the supply of hydrogen fuel cell vehicles will be made rapidly. Accordingly, safety measures for accidents of hydrogen vehicles in confined spaces such as tunnels are required. In this study, as part of a study to ensure the safety of hydrogen fuel cell vehicles in road tunnels, a basic investigation and research on the risk of fire and explosion due to gas leakage and hydrogen tank rupture among various hazards caused by hydrogen fuel cell vehicle accidents in tunnels was conducted. The following results were obtained. In the event of hydrogen fuel cell vehicle accidents, the gas release rate depends on the orifice diameter of TPRD, and when the gas is ignited, the maximum heat release rate reaches 3.22~51.36 MW (orifice diameter: 1~4 mm) depending on the orifice diameter but the duration times are short. Therefore, it was analyzed that there was little increase in risk due to fire. As the overpressure of the gas explosion was calculated by the equivalent TNT method, in the case of yield of VCE of 0.2 is applied, the safety threshold distance is analyzed to be about 35 m, and number of the equivalent fatalities are conservatively predicted to reach tens of people.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.37 no.3
• /
• pp.205-216
• /
• 2024

Recently, seismic Probabilistic Safety Assessment (PSA) methods have been developed for process plants, such as gas plants, oil refineries, and chemical plants. The framework originated from the PSA of nuclear power plants, which aims to assess the risk of reactor core damage. The original PSA method was modified to adopt the characteristics of a process plant whose purpose is continuous operation without shutdown. Therefore, a fault tree, whose top event is shut down, was constructed and transformed into a Bayesian Network (BN), a probabilistic graph model, for efficient risk-informed decision-making. In this research, the fault tree-based BN from the previous research is further developed to consider the multi-hazard of earthquake-induced fire and explosion (EQ-induced F&E). For this purpose, an event tree describing the occurrence of fire and explosion from a release is first constructed and transformed into a BN. And then, this BN is connected to the previous BN model developed for seismic PSA. A virtual plot plan of a gas plant is introduced as a basis for the construction of the specific EQ-induced F&E BN to test the proposed BN framework. The paper demonstrates the method through two examples of risk-informed decision-making. In particular, the second example verifies how the proposed method can establish a repair and retrofit strategy when a shutdown occurs in a process plant.

• Journal of the Korean Institute of Gas
• /
• v.24 no.3
• /
• pp.33-39
• /
• 2020

In general, in a batch reaction process in which products are made using flammable liquids, splash filling is used to clean the walls of the reactor by spraying flammable liquids, which are raw materials used for product, during cleaning of the reactor after work. During this process, mist of flammable liquid is generated, the lower limit of explosion is lowered, and fire·explosion may occur due to discharges caused by various types of complex charges, such as flow charge, collision charge, and ejection charge. Therefore, based on the recent accident case, to identify the risk when working in the form of splash filling with toluene in a batch process and perform an explosion impact analysis using the TNT equivalent method After that, we will analyze the accident results and suggest preventive measures such as constant purge system, improvement of cleaning method, and use of tantalum to prevent such accident.

• Journal of the Korean Institute of Gas
• /
• v.20 no.6
• /
• pp.80-88
• /
• 2016

A fire station and scuba have operated filling facilities for respiratory high-pressure cylinder without getting authority or reporting according to High-Pressure Gas Safety Control Act. They need facility improvement and special management to make provision for the time of accident during filling process. The Government have strived to correct illegal operations and suggested an alternative, establishing and operating the safety cabinet. It insures a safety being distance from danger caused by overpressure and a safety provoked by the protective wall equals or superiors. The safety cabinet is required to have an internal structure that smoothly distribute overpressure at the time of rupture. Plus, it needs to minimize fragments. It is also equipped with the performance of protective wall that makes overpressure to outside vent on the place where there is no person (top or bottom). This study calculated the consequence of physical explosion damage and built a prototype of safety cabinet. In addition, through the gas burst test, it derives for the ways to mitigate the physical explosion damage.

• Fire Science and Engineering
• /
• v.31 no.3
• /
• pp.19-24
• /
• 2017

Flammable substances are used in laboratories and industrial process. The flash point (FP) is one of the most important physical properties used to determine the potential for characterizing the fire and explosion hazard of liquids. The FP data at 101.3 kPa were measured for the binary systems {toluene+ethylbenzene}, {methlycyclohenxane+ethylbenzene} and {n-heptane+ ethylbenzene}. The experiments were performed according to the standard test method (ASTM D 3278) using a SETA closed cup flash point tester. The measured FPs were compared with the values predicted using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC). The average absolute deviation between the predicted and measured lower FP was less than 1.74 K.

• Journal of ILASS-Korea
• /
• v.20 no.2
• /
• pp.107-113
• /
• 2015

To date, the demand for Combined Cycle Power Plant (CCPP) has been continuously increased to overcome the problem of air pollution and lack of energy. In particular, the underground CCPP is exposed to substantial fire and explosion risks induced by gas leakage. The present study conducted numerical simulations to examine the fire behavior and gas leakage characteristics for a restricted region including gas turbine and other components used in a typical CCPP system. The commercial code of FLUENT V.14 was used for simulation. From the results, it was found that flammable limit distribution of leakage gas affects fire behavior. Especially, the flame is propagated in an instant in restricted region with LNG gas. In addition, consequence analysis factors such as critical temperature and radiation heat flux are introduced. These results would be useful in making the safety guidelines for the underground CCPP.