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Autoignition of Urethane Foam to be Used as the Insulator of the Household Refrigerator

  • Choi, Jae Wook;Mok, Yun Soo
    • International Journal of Safety
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    • v.1 no.1
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    • pp.47-51
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    • 2002
  • This study was performed by measuring the minimum ignition temperature of polyurethane form recovered from the recycling process of the end-of-life home appliances. The critical ignition temperature of polyurethane form was lower as the size of the sample vessel was increased, and that of polyurethane form using cyclopentane as the forming agent was relatively lower than the polyurethane form using CFC and the combustion of cyclopentane-polyurethane form occurred fiercely. It is considered that the recycling process of end-of-life home appliances using cyclopentane-polyurethane form as the insulator would require a special fire and dust explosion prevention measures since there exists a high potential hazard of fire and dust explosion during crushing and storage processes.

The Influence of Pressure, Temperature, and Addition of CO2 on the Explosion Risk of Propylene used in Industrial Processes

  • Choi, Yu-Jung;Choi, Jae-Wook
    • Korean Chemical Engineering Research
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    • v.58 no.4
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    • pp.610-617
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    • 2020
  • In process installations, chemicals operate at high temperature and high pressure. Propylene is used as a basic raw material for manufacturing synthetic materials in the petrochemical industry; However, it is a flammable substance and explosive in the gaseous state. Thus, caution is needed when handling propylene. To prevent explosions, an inert gas, carbon dioxide, was used and the changes in the extent of explosion due to changes in pressure and oxygen concentration at 25 ℃, 100 ℃, and 200 ℃ were measured. At constant temperature, the increase in explosive pressure and the rates of the explosive pressure were observed to rise as the pressure was augmented. Moreover, as the oxygen concentration decreased, the maximum explosive pressure decreased. At 25 ℃ and oxygen concentration of 21%, as the pressure increased from 1.0 barg to 2.5 bar, the gas deflagration index (Kg) increased significantly from 4.71 barg·m/s to 18.83 barg·m/s.

Study on Fire.Explosion Accidents Prediction Model Development of LPG Vaporizer (LPG 기화기의 화재.폭발사고 예측모델개발에 관한 연구)

  • Ko, Jae-Sun
    • Journal of the Korean Institute of Gas
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    • v.14 no.1
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    • pp.28-36
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    • 2010
  • We have garnered 3,593 data of gas accidents reported for 12 years from 1995, and then analyzed the LPG vaporizer accidents according to their types and causes based on the classified database. According to the results the gas rupture has been the most common accident followed by the release, explosion and then fire accidents, the most frequent accident-occurring sub-cause is LPG check floater faults. In addition, we have applied the Poisson Probability Functions to predict the most-likely probabilities of fire, explosion, release and rupture with the LPG vaporizer in the upcoming 5 years. In compliance with Poisson Probability Functions results, in the item which occurs below 3 "LPG-Vaporizer-Fire", in the item which occurs below 5 "LPG-Vaporizer-Products Faults-Check Floater" and the item which occurs below 10 appeared with "LPG-Vaporizer-Products Faults". From this research we have assured the successive database updating will highly improve the anticipating probability accuracy and thus it will play a key role as a significant safety- securing guideline against the gas disasters.