• Proceedings of the Korea Institute of Fire Science and Engineering Conference
• /
• 1997.11a
• /
• pp.275-281
• /
• 1997

The destruction by accident is affected by the blast of explosion. However, there are few of research on the external effect of vented gas explosions. Therefore it is necessary to study the effect of vented explosion. This study aims to find the characteristics of gas explosion, and the effect of vented gas explosion. Using an explosion chamber, we obtained a LPG explosion characteristics according to the vent size and concentration. The result of experiment showed that the explosion pressure effect to external space was much stronger than inner space during the course of a gas explosion. And the external pressure become higher in explosion pressure as the vent diameter become smaller.

• Korean Journal of Hazardous Materials
• /
• v.6 no.2
• /
• pp.62-67
• /
• 2018

It is very important to classify explosion hazardous area in order to prevent an accident explosion. In order to prevent such a explosion, the Industrial Safety and Health Standards Rules stipulates the establishment and management of explosion hazards in accordance with the criteria set by the Korean Industrial Standards. This study has investigated the range of the explosion hazardous area according to various hole sizes, pressures, vapor densities, and wind velocities in the outdoor flammable liquid tank using KS C IEC-60079-10-1 $2^{nd}$ Ed.(=IEC CODE) and PHAST. The results show that the explosion hazardous areas by IEC CODE have circle shapes. However, the areas by PHAST show ellipse shapes. The different of the explosion hazardous areas increases with the increase of wind velocity.

• Journal of the Korean Institute of Gas
• /
• v.11 no.4
• /
• pp.7-11
• /
• 2007

There has been a report of fire and explosion accident in regenerated thermal oxidizer (RTO). This paper was to investigate accident causes of RTO in the resin re-treatment process. The experiments carried out physicochemical properties and thermal stability analyses by using flash point tester, flammable range apparatus, autoignition tester, GC/MSD and thermal screening unit. We inferred causes of fire and explosion from the regenerated thermal oxidizer to prevent an accident of its process.

• Journal of the Korean Society of Safety
• /
• v.17 no.4
• /
• pp.126-132
• /
• 2002

By using the reference data, the empirical equations which describe the interrelationships of explosion properties and physical properties of n-chlorinated hydrocarbons have been derived. The properties which have been correlated are the lower and upper explosive limits, the stoichiometric coefficients, the heats of combustion, the carbon numbers. Also, the new equations using the mathematical and statistical methods for predicting the temperature dependence of lower explosive limits(LEL) of chlorinated hydrocarbons on the basis of the literature data are proposed. The fire and explosion properties calculated by the proposed equations in this research were a good agrement with literature data within a few A.A.P.E.(Average Absolute Percent Error) and A.A.D.(Average Absolute Deviation.) From a given explosive properties, by using the proposed equations, it is possible to predict to the fire and explosion characteristics for the other chlorinated hydrocarbons.

• Journal of the Korea Safety Management & Science
• /
• v.26 no.1
• /
• pp.99-106
• /
• 2024

In the event of an emergency such as facility shutdown during process operation, the by-product gas must be urgently discharged to the vent stack to prevent leakage, fire, and explosion. At this time, the explosion drop value of the released by-product gas is calculated using ISO 10156 formula, which is 27.7 vol%. Therefore, it does not correspond to flammable gas because it is less than 13% of the explosion drop value, which is the standard for flammable gas defined by the Occupational Safety and Health Act, and since the explosion drop value is high, it can be seen that the risk of fire explosion is low even if it is discharged urgently with the vent stock. As a result of calculating the range of explosion hazard sites for hydrogen gas discharged to the Bent Stack according to KS C IEC 60079-10-1, 23 meters were calculated. Since hydrogen is lighter than air, electromechanical devices should not be installed within 23 meters of the upper portion of the Bent Stack, and if it is not possible, an explosion-proof electromechanical device suitable for type 1 of dangerous place should be installed. In addition, the height of the stack should be at least 5 meters so that the diffusion of by-product gas is facilitated in case of emergency discharge, and it should be installed so that there are no obstacles around it.

• Journal of the Korean Society of Safety
• /
• v.29 no.5
• /
• pp.60-66
• /
• 2014

Depending on the progress of the industrial advances, the use of the thermal oil system in the utility system has been increased, which became an important part in the operation of the plant. However, fire or explosion have occurred due to lack of risk awareness and safety management, more frequently than we know. In this study, by using a questionnaire, actual conditions of safety management in thermal oil system is surveyed and analyzed, it is composed of general, a safety status of the thermal oil system component and the stage of recognition and management in the thermal oil system. These results of this study can be used as basic data to the safety management and the accident prevention of fire or explosion in the workplace.

• Korean Journal of Hazardous Materials
• /
• v.6 no.2
• /
• pp.23-29
• /
• 2018

The fire and explosion properties necessary for waste, safe storage, transport, process design and operation of handling flammable substances are lower explosion limits(LEL), upper explosion limits(UEL), flash point, AIT( minimum autoignition temperature or spontaneous ignition temperature), fire point etc., An accurate knowledge of the combustion properties is important in developing appropriate prevention and control measures fire and explosion protection in chemical plants. In order to know the accuracy of data in MSDSs(material safety data sheets), the flash point of phenol was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of phenol was measured by ASTM 659E apparatus. The explosion limits of phenol was investigated in the reference data. The flash point of phenol by using Setaflash and Pensky-Martens closed-cup testers were experimented at $75^{\circ}C$ and $81^{\circ}C$, respectively. The flash points of phenol by Tag and Cleveland open cup testers were experimented at $82^{\circ}C$ and $89^{\circ}C$, respectively. The AIT of phenol was experimented at $589^{\circ}C$. The LEL and UEL calculated by using Setaflash lower and upper flash point value were calculated as 1.36vol% and 8.67vol%, respectively. By using the relationship between the spontaneous ignition temperature and the ignition delay time proposed, it is possible to predict the ignition delay time at different temperatures in the handling process of phenol.

• Korean Chemical Engineering Research
• /
• v.56 no.6
• /
• pp.811-818
• /
• 2018

A fire and explosion accident caused by a liquefied petroleum gas (LPG) welding and cutting torch gas leak occurred 10 m underground at the site of reinforcement work for bridge columns, killing four people and seriously injuring ten. We conducted a comprehensive investigation into the accident to identify the fundamental causes of the explosion by analyzing the structure of the construction site and the properties of propane, which was the main component of LPG welding and cutting work used at the site. The range between the lower and upper explosion limits of leaking LPG for welding and cutting work was examined using Le Chatelier's formula; the behavior of LPG concentration change, which included dispersion and concentration change, was analyzed using the fire dynamic simulator (FDS). We concluded that the primary cause of the accident was combustible LPG that leaked from a welding and cutting torch and formed a explosion range between the lower and upper limits. When the LPG contacted the flame of the welding and cutting torch, LPG explosion occurred. The LPG explosion power calculation was verified by the blast effect computation program developed by the Department of Defense Explosive Safety Board (DDESB). According to the fire simulation results, we concluded that the welding and cutting torch LPG leak caused the gas explosion. This study is useful for safety management to prevent accidents caused by LPG welding and cutting work at construction sites.

• Journal of the Korean Society of Safety
• /
• v.32 no.5
• /
• pp.25-31
• /
• 2017

The flash point, explosion limits, autoignition temperature(AIT) are important combustible properties which need special concern in the chemical safety process that handle hazardous substances. For the evaluation of the flammable properties of n-butylacetate, this study was investigated the explosion limits of n-butylacetate in the reference data. The flash points, fire points and AIT by the ignition delay time of n-butylacetate were experimented. The lower flash points of n-butylacetate by using the Setaflash and Pensky-Martens closed-cup testers were $24^{\circ}C$ and $26^{\circ}C$, respectively. The flash points of n-butylacetate using the Tag and Cleveland open cup testers are measured $31^{\circ}C$ and $40^{\circ}C$, respectively. And the fire points of n-butylacetate by the Tag and Cleveland open cup testers were measured $32^{\circ}C$ and $41^{\circ}C$. The AIT of n-butylacetate measured by the ASTM 659E tester was measured as $411^{\circ}C$. The lower explosion limit of lower flash point $24^{\circ}C$, which was measured by the Setaflash tester, was calculated to be 1.40 vol%. Also, the upper explosion limit of upper flash point $67^{\circ}C$ the Setaflash tester was calculated to be 12.5 vol%.

• Journal of the Korean Society of Safety
• /
• v.8 no.4
• /
• pp.107-113
• /
• 1993

Small rectangular explosion chamber of its size 25cmX25cmX32cm with a circular bursting diaphram at the top was used to study the mechanism of gas explosion to fire transition phenomena, the process of ignition of solid combustibles during a gas explosion. To visulize the explosion to fire transition phenomena, transparent acryl window and high speed camera system were used. The test piece of solid combustible in this experiments was a 5cm$\times$5cm square sheet of newspaper which was placed in the explosion chamber filled with a LPG-air mixture. The mixture was ignited by an electric spark at the center of the chamber. Explosion to fire transition phenomena and the behavior of out flow and in flow of gas through the opening yielded by bursting the diaphram was visualized with shlieren system and without shlieren system. Diameter of a bursting dlaphram at the top of the explosion chamber was varied 5cm, 10cm, and 15cm, and the position of test piece were varied with 6 point. Explosion pressure was measured with strain type pressure transducer, and the weight difference of the test piece before and after each experimental run was measured. By comparing the weight difference of solid combustibles before and after the experiment and the behavior of out flow and inflow of gas after explosion, it was found that the possibility of ignition was depends on the LPG-air mixture concentration and the exposure period of test piece to the burnt gas. Test result of this experiments it was found that the main factor of this phenomena are that heat transfer to the test piece, and the pyrolysis reaction of test piece. Based on the results, the mechanism of the explosion to fire transition phenomena were inferred ; gas explosion- heat transfer to solid combustibiles ; pyrolysis reaction of solid combutibles : air inflow ; mixing of the pyroly gas with air ignition.