• Title/Summary/Keyword: Fire- and explosion safety

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Case Study on Advanced Fire and Explosion Index (화재폭발지수 개선에 대한 사례 연구)

  • Na, Gun Moon;Seoe, Jae Min;Lee, Mi Jeong;Baek, Jong-Bae
    • Journal of the Korean Society of Safety
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    • v.35 no.6
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    • pp.78-84
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    • 2020
  • The F&EI technique is one of the risk assessments with many advantages. It can save time and effort compared to quantitative risk assessment (QRA). By using the evaluation result of this technique, it is possible to check the effectiveness of the investment cost. In addition, a relative risk ranking can be created and used to establish the facility management cycle and to prioritize investment. However, evaluating the target process can be evaluated more than the actual risk since the LCCF, a loss prevention measure, is too limited. In addition, calculating premiums via this method can result in excessive premiums, making it difficult to evaluate the risk precisely. Therefore, new safety guard was added to the LCCF of the F&EI risk assessment with reference to HAZOP and LOPA techniques. Newly added LCCFs are Deflagration arrester, Check valve, SIS, and Vacuum beaker, etc. As a case study, F&EI risk assessment was performed on Acetone storage tank of a API (Active pharmaceutical ingredient) plant to compare actual MPPD. The estimated loss amount was 592,558$ for the existing technique and 563,571$ for the improved technique, which was reduced by about 5% compared to the previous one.This proved that a more precise evaluation is possible and that the efforts for safety at the workplace are reflected in the evaluation results.

Review on the Process Safety of $SiH_{4}$ Gas used in Semiconductor and FPD Field (반도체 및 FPD 분야에 사용되는 $SiH_{4}$ 가스의 공정 안전 고찰)

  • Kim, Joung-Cho;Kim, Hong
    • Journal of the Korean Society of Safety
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    • v.22 no.4
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    • pp.32-36
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    • 2007
  • When the vacuum system for the process of $SiH_{4}$ gas used in the semiconductor and FPD field is partially vented from vacuum to atmospheric state, a fire often occurs due to auto-ignition of $SiH_{4}$ gas. In order to prevent the fire, the concentration of $SiH_{4}$ should be kept under LFL. This means that the higher capacity pump is needed to meet the process conditions as well as the condition that the concentration of $SiH_{4}$ should be kept under LFL. In this article, we conducted the injection of the dilution gas at the manifold between booster pump and dry pump compared with the typical method that the dilution gas was injected into inlet port of booster pump using computer simulation. According to the result, we can flow further more purge gas for safety without any change of the condition in the process chamber, which means that the higher capacity pump is not required for safety in some cases.

Dependence of Explosion Overpressure of Flammable Gas on the Change of Volume Blockage Ratio of Facilities (설비 혼잡도에 따른 가연성 증기운의 폭발과압의 변화)

  • Lee, Seung Kuk;Lee, Da Eun;Kim, Sung Chan;Yoon, Kee Bong
    • Journal of the Korean Institute of Gas
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    • v.19 no.6
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    • pp.54-61
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    • 2015
  • A series of CFD calculation has been conducted to investigate the effect of facility confinement on explosion power for process plant facility. The level of confinement of a facility was simplified with VBR(volume blockage ratio) and averaged size of obstacles. FLACS which is 3D CFD code of gas dispersion and the explosion was used for simulating the explosion phenomena in the idealized domain with different confinement level. The CFD results showed a tendency that the overpressure increases with increasing VBR and number of obstacles. The effect of VBR on the overpressure was relatively small for the case of number of obstacle less than 25. The results of this study can be used to provide a safety guideline considering the facility confinement in case of leakage accident of flammable gas and vapor in process plants.

A Study on the Prevention Measures against Fire and Explosion Accidents during Splash Filling in Batch Process (회분식 공정에서 스플래쉬 필링(Splash Filling) 작업으로 인한 화재·폭발 사고 예방대책에 관한 연구)

  • Kim, Sang Ryung;Lee, Dae Jun;Kim, Jung Duk;Kim, Sang Gil;Yang, Won Baek;Rhim, Jong Guk
    • Journal of the Korean Institute of Gas
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    • v.24 no.3
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    • pp.33-39
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    • 2020
  • In general, in a batch reaction process in which products are made using flammable liquids, splash filling is used to clean the walls of the reactor by spraying flammable liquids, which are raw materials used for product, during cleaning of the reactor after work. During this process, mist of flammable liquid is generated, the lower limit of explosion is lowered, and fire·explosion may occur due to discharges caused by various types of complex charges, such as flow charge, collision charge, and ejection charge. Therefore, based on the recent accident case, to identify the risk when working in the form of splash filling with toluene in a batch process and perform an explosion impact analysis using the TNT equivalent method After that, we will analyze the accident results and suggest preventive measures such as constant purge system, improvement of cleaning method, and use of tantalum to prevent such accident.

A Study on Safety Policies for a Transition to a Hydrogen Economy (수소경제로의 이행을 위한 안전관리 정책 연구)

  • Jun, Daechun
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.2
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    • pp.161-172
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    • 2014
  • Hydrogen, which can be produced from abundant and widely distributed renewable energy resources, seems to be a promising candidate for solving the concerns for improving energy security, urban air pollution, and reducing greenhouse gas emissions. The two primary motivating factors for hydrogen economy are fossil fuel supply limitations and concerns about global warming. But the safety issues associated with hydrogen economy need to be investigated and fully understood before being considered as a future energy source. Limited operating experience with hydrogen energy systems in consumer environments is recognised as a significant barrier to the implementation of hydrogen economy. To prevent unnecessary restrictions on emerging codes, standards and local regulations, safety policies based on real hazards should be developed. This article studies briefly the direct impact-distances from hazard events such as hydrogen release and jet fire, and damage levels from hydrogen gas explosion in a confined space. Based on the direct impact-distances indicated in the accident scenarios and consumer environments in Korea, the safety policies, which are related to hydrogen filling station, hydrogen fuel cell car, portable fuel cell, domestic fuel cells, and hydrogen town, are suggested to implement hydrogen economy. To apply the safety policies and overcome the disadvantages of prescriptive risk management, which is setting guidance in great detail to management well known risk but is not covering unidentified risk, hybrid risk management model is also proposed.

Consequence Analysis for Fire and Explosion Accidents in Propylene Recovery Process (프로필렌 회수공정에서 화재 및 폭발 사고의 피해영향 해석)

  • Han, Seong-Hwan;Lee, Hern-Chang;Park, Kyoshik;Kim, Tae-Ok
    • Journal of the Korean Institute of Gas
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    • v.18 no.1
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    • pp.52-60
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    • 2014
  • This study aims to suggest risk management plan including safety measures through hazard identification followed by consequence analysis in petrochemical plants. Consequence analysis was performed through practical release scenario by using PHAST RISK(ver. 6.7) software in the propylene recovery process(PRP). As results, consequences by fire or explosion accidents in the depropanizer zone, deethanizer zone and heat pump zone were relatively larger than other else zones among six process zones in the PRP. In the case of jet fire, it is recommendable not to install residence building within 200 m of the process zone. Additionally, process zones having large inventory or high pressure must be prevented from accidents and required to establish quick response against accidents.

Measurement and Prediction of Autoignition Temperature (AIT) and Ignition Delay Time of n-Pentanol and p-Xylene Mixture (n-Pentanol p-Xylene 과 혼합물의 최소자연발화온도와 발화지연시간의 측정 및 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.31 no.5
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    • pp.1-6
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    • 2017
  • The fire and explosion properties of combustible materials are necessary for the safe handling, storage, transportation and disposal. Typical combustion characteristics for process safety include auto ignition temperature(AIT). The AIT is an important index for the safe handling of combustible liquids. The AIT is the lowest temperature at which the material will spontaneously ignite. In this study, the AITs and ignition delay times of n-pentanol and p-xylene mixture were measured by using ASTM E659 apparatus. The AITs of n-pentanol and p-xylene which constituted binary system were $285^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs and ignition delay times of n-pentanol and p-xylene mixture were a good agreement with the calculated AITs and ignition delay times by the proposed equations with a few A.A.D. (average absolute deviation). Therefore, it is possible to estimate the AITs and ignition delay times in other compositions of n-pentanol and p-xylene mixture by using the predictive equations which presented in this study.

A Study on Total Hazard Level Algorithm Development for Hazardous Chemical Substances (유해화학물질의 종합위해등급 알고리즘 개발에 관한 연구)

  • 고재선;김광일;정상태
    • Fire Science and Engineering
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    • v.14 no.4
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    • pp.7-16
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    • 2000
  • In the study, three criteria(toxicity, fire & explosion, environment) and damage prediction method for each case was set up, and all these criteria were applied to the subject substance that was selected as hazardous level by integrating all criteria through Algorithm. Particularly, the environment criterion is a comprehensive concept, environment index modeling by combining USCG(United State Coast Guard) & MSDS(Material Safety Data Sheet) environment criteria classifications and the environment part of MFPA's health hazardousnes(Nh). And for damage prediction method of each criterion were adopted and they were applied to hazardous chemical substances in use or stored by chemical substance related enterprises located in each region that made possible to set up total hazard level of used substances(inflammability, poisonousness and counteraction on a unit substance, and hazard level & display modeling on environment) & damage prediction in case of accident & solidity setup(CPQRA: Chemical Process Quantitative Risk Assessment, IAEA: International Atomic Energy Agency, VZ eq: Vulnerable Zone) risk counter. Thus it is deemed that it can be applied to toxic substance leakage that can happen during any chemical processing & storage, application as a tool for prior safety evaluation through potential dangerousness computation of fire & explosion.

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Fire Safety evaluation of High Pressure Hydrogen System for FCEV (연료전지차량용 고압수소저장시스템의 화재 안전성 평가)

  • Choi, Young-Min;Jang, Gyu-Jin;Kim, Sang-Hyun;Hang, Ki-Ho;Hang, In-Cheol;Ahn, Byung-Ki;Lim, Tae-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.3
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    • pp.188-193
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    • 2009
  • Fuel cell vehicles are equipped with Pressure Relief Devices(PRDs) installed in pressure tank cylinder to prevent the explosion of the tank during a fire. PRDs are safety devices that perceive a fire and release gas in the pressure tank cylinder before it is exploded. But if the PRD does not actuate, because either the PRD fails or can't be surrounded by the flame of a fire, the tank will rupture and produce a blast wave and hydrogen fire ball. In this paper, we observed the fire behavior of actual fuel cell vehicle, comparing with that of gasoline vehicle.

Prediction and Measurement of Flash Point and Fire Point of Aromatic Hydrocarbons (방향족탄화수소의 인화점과 연소점 측정 및 예측)

  • Ha Dong-Myeong;Han Jong-Geun
    • Journal of the Korean Institute of Gas
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    • v.9 no.3 s.28
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    • pp.21-26
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    • 2005
  • The flash points and the fire points are one of the most important combustible properties used to determine the potential for the fire and explosion hazards of flammable substances. In this study, the flash points of aromatic hydrocarbons, were measured by using Pensky-Martens Closed Cup apparatus(ASTM-D93) and Tag Open-Cup apparatus(ASTM D 1310-86). Also the fire points of aromatic hydrocarbons, were measured by using Tag Open-Cup apparatus. The measured flash points were in good agreement with reference values. The measured fire points compared with the estimated values based on 1.23 times stoichiometric concentration. The values calculated by the proposed equation were in agreement with measured values.

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