• Title/Summary/Keyword: Fire- and explosion safety

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A Study on the Analysis and Protection of Lightning Accident in Petrochemical Plant Wastewater Storage Tank (석유화학공장 폐수 저장 탱크의 낙뢰사고 분석과 보호방안에 관한 연구)

  • Song, Bang-Un;Oh, Gil-Jung;Woo, In-Sung
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.107-113
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    • 2019
  • Recently, due to global warming, the trend shows an increase in number of lightning strikes which increase risk regarding industry infrastructures. Especially in case where the lightning strikes infrastructures including refinery, petorchemical plant facilities or storage tanks, it can cause power failures, electrical machine malfunction and damage which can lead to fire explosion and multiple calamities. Therefore, detailed case studies must be conducted through a systematic research regarding lightning strike accidents in order to understand its mechanism and devise preventive measures. This paper aims to study cases of explosion regarding waste water storage tanks in refineries and petrochemical plants in order to analyze its root cause and provide preventive measures for avoiding lightning related incidents.

An Accident Investigation of Fire and Explosion Case During Painting Work in the Tank of the Crude Oil Carrier (선박 탱크 내부 도장작업 중 발생한 화재·폭발 사고원인 분석)

  • Ahn, Byung-Joon;Jung, Ki-Hyuk;Rhim, Jong-Kuk
    • Journal of the Korean Institute of Gas
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    • v.22 no.3
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    • pp.20-31
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    • 2018
  • There was an amazing growth in the korean shipbuilding industry considering the industrial magnitude and the technical level. On the contrary of the growth, there are a number of accidents in the shipbuilding yard. According to the statistic data of the industrial accident in the last 7 years, the number of accidental fatalities in shipbuilding industries are 1.48 ‱ which are over more than doubles of the average in the Korean industries, 0.66 ‱. Thus, through an accident investigation of fire and explosion case during painting work in the tank of the crude oil carrier, it have been tried to diagnose actual conditions in the shipbuilding yards.

Prediction of Autoignition Temperatures of Gasoline-Ethanol Blended Fuels (휘발유/에탄올 혼합연료의 자연점화온도 예측)

  • Kim, Shin-Woo;Lee, Eui-Ju
    • Fire Science and Engineering
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    • v.33 no.5
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    • pp.1-6
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    • 2019
  • The recent development of biofuel production technology facilitates the widespread use of bioethanol and biodiesel by mixing them with fossil fuels. However, the use of these new blended fuels in combustion could result in severe safety problems, such as fire and explosion. In this study, numerical simulation was performed on the well-stirred reactor (WSR) to simulate the autoignition temperature (AIT) in homogeneous combustion and clarify the effect of ethanol addition on the AIT, the most important property for assessing the potential for fire and explosion. Response surface methodology (RSM) was introduced as a design of experiment (DOE), enabling the AIT to be predicted and optimized systematically with respect to three independent variables: ethanol mole fraction, equivalence ratio, and pressure. The results show that the autoignition temperature primarily depends on the ethanol mole fraction and pressure, while the effects of the equivalence ratio are independent of the AIT. RSM accurately predicted the experimental AIT, indicating that this method can be used to effectively predict the key properties involved in fires and explosions.

The Prediction and Measurement of Combustible Properties for Bromobenzene (브로모벤젠의 연소특성치의 측정 및 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.29 no.4
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    • pp.21-25
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    • 2015
  • The usage of the correct combustion characteristics of the treated substance for the safety of the process is critical. For the safe handling of bromobenzene being used in various ways in the chemical industry, the flash point and the autoignition temperature (AIT) of bromobenzene was experimented. And, the lower explosion limit of bromobenzene was calculated by using the lower flash point obtained in the experiment. The flash points of bromobenzene by using the Setaflash and Pensky-Martens closed-cup testers measured $44^{\circ}C$ and $50^{\circ}C$, respectively. The flash points of bromobenzene by using the Tag and Cleveland automatic open cup testers are measured $56^{\circ}C$ and $64^{\circ}C$. The AIT of bromobenzene by ASTM 659E tester was measured as $573^{\circ}C$. The lower explosion limit by the measured flash point $44^{\circ}C$ was calculated as 1.63 Vol%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.

The Measurement of Combustible Characteristics of n-Undecane (노말언데칸의 연소특성치의 측정)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.27 no.2
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    • pp.11-17
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    • 2013
  • For the safe handling of n-undecane, the lower flash points and the upper flash point, fire point, AITs (auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-undecane were calculated. The lower flash points of n-undecane by using closed-cup tester were measured $59^{\circ}C$ and $67^{\circ}C$. The lower flash points of n-undecane by using open cup tester were measured $67^{\circ}C$ and $72^{\circ}C$, respectively. The fire point of n-undecane by using Cleveland open cup tester was measured $74^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-undecane. The experimental AIT of n-undecane was $198^{\circ}C$. The estimated lower and upper explosion limit by using measured lower flash point $59^{\circ}C$ and upper flash point $83^{\circ}C$ for n-undecane were 0.65 Vol.% and 2.12 Vol.%.

Consequence Analysis of the Fire & Explosion on the Flammable Liquid Handling Facility and LPG Station (제 4류 위험물 취급소 및 LPG 충전소의 화재$\cdot$폭발 피해 영향분석)

  • Lee Su-Kyung;Lee Chang-Wook
    • Journal of the Korean Institute of Gas
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    • v.3 no.2 s.7
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    • pp.77-84
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    • 1999
  • The XX company that is handling the class IV hazardous materials, located in Bu-Chon City and the LPG station in front of the XX company which is about 20 meters apart, was chosen as the standard model for this study In carrying out the consequence analysis, PHAST and Super-Chems were used for the study and utilizing the output of the simulation, we have evaluated the consequences throughout the probit analysis and explosion overpressure analysis. In case of Acetone, the effect distance of the damage on facilities-that is the result of radiation heat flux of $37.5kW/m^2$ by TNO model-is 68.51m by PHAST model and 40.93m by Super-Chem model. The risk assessment of the LPG station which is based on the explosion resulted as the analysis of the fire ball showed the diameter 125.2m, the height 206.2m and the duration 11.28sec and the effect distance for the radiant heat flux $37.5kW/m^2$ was 137.0m.

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Investigation of Reliability of Flash Points and Autoignition Temperatures of Acids (산류(Acids)의 인화점과 최소자연발화온도의 신뢰성 고찰)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.24 no.2
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    • pp.42-47
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    • 2009
  • The flash point and the AIT(auto-ignition temperature) are the most important combustible properties used to determine the potential for the fire and explosion hazards of flammable material. In order to know the accuracy of data in MSDS(Material Safety Data Sheet), the flash point of n-acids were measured by using Pensky-Martens closed cup tester(ASTM D93), Setaflash closed cup tester(ASTM D3278), Tag open cup tester(ASTM D1310) and Cleveland open cup tester(ASTM D92). Also, the AIT of n-acids were measured by using ASTM E659-78 tester. The measured the flash points and the AIT were compared with literatures and MSDS in KOSHA. The measured the flash points and the AIT were different from those in literatures and MSDS. Therefore, This paper shows that it is needed to investigate the MSDS compatibility of n-acids for the fire safety objectives.

A Study on the Establishment of Process Safety Management (PSM) System for Small and Medium Size Chemical Plants (중소화학공장의 공정안전관리(PSM)시스템 구축에 관한 연구)

  • Baek Jong-Bae;Ko Jae-Wook
    • Journal of the Korean Institute of Gas
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    • v.3 no.1
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    • pp.8-13
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    • 1999
  • The article 49-2 of Industrial Safety Law requires that all the owners of industrial plants which contains dangerous facilities perform the process safety management. That is, this law requires the owners of industrial plants to take necessary measures to prevent fire, harmful gas leaking, explosion, and other serious accidents that could cause demage and injuries to the employees. So far, domestic chemical plants have tried to invest money and time in safety management. But, such efforts have been made only in chemical plants that were subsidiaries of large business groups. Moreover, since the economic crisis of Korea which is symbolized by the IMF bailout, small and medium size companies could not afford to invest in safety management. Their major concern is to increase productivity and thereby, survive in this crisis. The goal of this research is to develop the process safety management system that can help small and medium size companies to positively secure the process safety management. So, in developing the process safety management system, the financial and practical difficulties of such companies are fully taken into consideration.

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A Study on Estimation of Lower Explosive Limits of Alcohol Compounds (알코올화합물의 폭발하한계 추산에 관한 연구)

  • Dong-Myeong Ha;Yong-Chan Choi;Haejin Oh;Su-kyung Lee
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2002.11a
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    • pp.291-296
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    • 2002
  • Flammable compounds are indispensible in domestic as well as in industrial fields as fuel, solvent and raw materials. The fire and explosion properties necessary for safe storage, transport, process design and operation of handling flammable substances are lower explosive limits(LEL), upper explosive limits(UEL), flash point, fire point, AIT(auto ignition temperature), MIE(minimum ignition energy), MOC(minimum oxygen concentration) and heats of combustion.

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