• Fire Science and Engineering
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• v.32 no.2
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• pp.30-37
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• 2018

This study is an analysis of combustion characteristics of synthetic insulation materials such as houses and warehouses. Using combustion cone calorimeter and SEM, the researching has experimented combustion characteristics of four kinds of materials such as flame retardant styrofoam, general styrofoam, urethane and gypsum board. And analyzed. As a result of the test, the ignition time (TTI) for the thermal insulation material was found at 27 s~43 s, and the flame retardant styrofoam was ignited at the lowest TTI at 27 s and disappears at 28 s. In addition, the maximum heat release rate (peak HRR) and average heat release rate (mean HRR) of each material were expressed in the following order: urethane> flame retardant styrofoam> styrofoam> gypsum board. Also, the total smoke release ($m^2/m^2$) was the largest at $30.798m^2/m^2$ in flame-retardant styrofoam. The general CO concentration of styrofoam was 0.275 kg/kg and the emission concentration was 12.807 kg/kg. The residues showed the highest 0.029 g in the gypsum board among the above materials.

• Journal of the Mineralogical Society of Korea
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• v.22 no.2
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• pp.153-162
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• 2009

The main compositions of "Seokganju", a Korean traditional red mineral pigment, are iron oxides. To investigate its mineralogical and functional properties, we had got its ore from Juto cave in Ulreoung island, which was a famous field of it in Korean documents. The ore occurs as a paleosol between the olivine basalt and amphibole trachyte in discontinuously. It is reddish brown and yellowish brown and consists mainly of clay minerals with minor debris. Its reddish and yellowish brown color are due to the hematite and ferrihydrate, respectively. These iron oxides are precipitated as ferrihydrate from the ferrous water in the paleosol and partly changed to hematite. The color reproduced in timber by using seokganju pigment with traditional tools and methods is similar to that in heritage building. The moistureproofing and fire resistance of Ulreungdo seokganju is far better than that of artificial seokganju. Moreover, the combustion tests show that the artificial seokganju promote the ignition and combustion of the timber. Ulreungdo seokganju is regarded as a pigment with fungicidal efficacy because growth of two wood decay fungi (cov. and typ.) are inhibited in solid medium with it.

• Clean Technology
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• v.25 no.2
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• pp.140-146
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• 2019

Flammable substances, such as organic solvents, are commonly used in laboratories and industrial processes. The flash point of flammable liquid mixtures is a very important parameter for characterizing the ignition and explosion hazards, and the flash points of mixtures of $C_2{\sim}C_3$ alcohols and 2,2,4-trimethylpentane were measured in the present study. The 2,2,4-trimethylpentane is an important component of gasoline and is frequently used in the petroleum industry as a solvent. Lower flash point data were measured for the binary systems {ethanol + 2,2,4-trimethylpentane}, {1-propanol + 2,2,4-trimethylpentane}, and {2-propanol + 2,2,4-trimethylpentane}. The flash point measurements were carried out according to the standard test method (ASTM D3278) using a Stanhope-Seta closed cup flash point tester. The measured flash points were compared with the predicted values calculated using Raoult's law and also following $G^E$ models: Wilson, Non-Random Two Liquid (NRTL) and UNIversal QUAsiChemical (UNIQUAC). These models were able to predict the experimental flash points for different compositions of {$C_2{\sim}C_3$ alcohols + 2,2,4-trimethylpentane} mixtures with minimal deviations. The average absolute deviation between the predicted and measured lower flash point was less than 1.28 K. A minimum flash point behaviour was observed in all of the systems as in the many observed cases for the hydrocarbon and alcohol mixtures.

• Journal of the Korean Wood Science and Technology
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• v.30 no.2
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• pp.172-179
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• 2002

In this study, two materials treated with a flame retardant were examined for their fire resistance. The first, MDF (medium density fiberboard) was overlaid by an oak sliced veneer, which was either treated by soaking in a 6wt.% solution of flame retardant chemicals (pentabromine-chlorinated paraffin) or non-treated and then was coated with either a flame retardant polyurethane coating or with a common polyurethane coating. The second material, Pinus koraiensis penal was either treated by a spray treatment using a flame retardant solution or non-treated and then was coated with either a flame retardant polyurethane coating or with a common polyurethane coating. Pentabromine-chorinated paraffin chemicals were added (6 part of urethane resin) as the flame retardant chemicals in the polyurethane coatings. In the fire resistance test, the th𝜃(℃·min) decreased with the flame retardant treatment or/and the flame retardant coatings, compared to the untreated sample Weight loss (%) decreased with the flame retardant treatment or/and the flame retardant coatings. The ignition time (sec.) increased and the residual flame time (sec.) decreased with the flame retardant treatment or/and flame retardant coatings. Therefore, the flame retardant treatment or/and flame retardant polyurethane coatings have excellent incombustibility.

• Journal of the Society of Disaster Information
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• v.16 no.4
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• pp.701-711
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• 2020

Purpose: In this study, the risk of flammability of a liquid mixture was experimentally confirmed because the purpose of this study was to confirm the increase or decrease of the flammability risk in a mixture of two substances (combustible+combustible) and to present the risk of the mixture. Method: Flash point test method and result processing were tested based on KS M 2010-2008, a tag sealing test method used as a flash point test method for crude oil and petroleum products. The manufacturer of the equipment used in this experiment was Japan's TANAKA. The flash point was measured with a test equipment that satisfies the test standards of KS M 2010 with equipment produced by the company, and LP gas was used as the ignition source and water as the cooling water. In addition, when measuring the flash point, the temperature of the cooling water was tested using cooling water of about 2℃. Results: First of all, in the case of flammable + combustible mixtures, there was little change in flash point if the flash point difference between the two substances was not large, and if the flash point difference between the two substances was low, the flash point tended to increase as the number of substances with high flash point increased. However, in the case of toluene and methanol, the flash point of the mixture was lower than that of the material with a lower flash point. Also, in the case of a paint thinner, it was not easy to predict the flash point of the material because it was composed of a mixture, but as a result of experimental measurement, it was measured between -24℃ and 7℃. Conclusion: The results of this study are to determine the risk of mixtures through experimental studies on flammable mixtures for the purpose of securing the effectiveness of the details of the criteria for determining dangerous goods in the existing dangerous goods safety management method and securing the reliability and reproducibility of the determination of dangerous goods Criteria have been presented, and reference data on experimental criteria for flammable liquids that are regulated in firefighting sites can be provided. In addition, if this study accumulates know-how on differences in test methods, it is expected that it can be used as a basis for research on risk assessment of dangerous goods and as a basis for research on dangerous goods determination.

• Analytical Science and Technology
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• v.28 no.6
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• pp.398-408
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• 2015

Carbon monoxide (CO) intoxication, arising from CO from an ignited charcoal briquette (ICB), is a popular means of committing suicide in Korea. Most CO intoxications are related to suicide attempts; however, the possibility of a homicide disguised as a suicide cannot be ruled out. Therefore, forensic investigation of the deceased and the crime scene is crucial to confirm that the deceased committed suicide. Detection of the components of an ICB on the objects suspected of being contacted by the deceased, such as the hands, nostrils, and doorknobs, is essential for linking the crime scene to the victim in the case of suicides by ignited ICBs. The traces from an ICB were analyzed by investigating the morphological characteristics and obtaining elemental compositions. The ICBs were completely different from blackened wood, as detected by discriminant analysis with the elements of carbon and oxygen. We analyzed one case of CO intoxication to demonstrate an excellent procedure for verifying whether a suicide occurred with an ICB. We employed SEM-EDX for the analysis of an ICB, microscope-FT/IR and pyrolysis-GC/MS for a partly burnt resin-type substance, GC/MS for diphenhydramine (a sleeping drug), and GC/TCD for the CO-Hb level. We detected traces of an ICB on the hands, nostrils, and doorknobs, which were all discriminated into an ICB group. Detection of ICB traces from the nostrils could indicate that the deceased started the fire themselves to commit suicide. The partially burnt black material was analyzed as an acrylronitrilestyrene polymer, which is normally used to make bags for carrying or wrapping and could be assumed to have been used to transport the ICB. Diphenhydramine, a sleeping drug, was detected at a level of 2.3 mg/L in the blood, which was lower than that in fatal cases (8-31 mg/L; mean 16 mg/L). A CO-Hb level of 79% was found in the blood, which means that the cause of death was CO intoxication. The steps shown here could represent an ideal method for reaching a verdict of suicide by CO intoxication produced by burning an ICB in a sealed room or a car.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.3
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• pp.275-283
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• 2013

An injector that uses methane gas ($CH_4$) and liquid oxygen ($LO_x$) as propellants was designed to verify the combustion characteristics of an engine that uses methane, which is one of the next-generation propellants. A swirl/shear coaxial-type injector was used, and flow analysis was performed using Fluent to determine the main design parameters of the injector. A hydraulic test was performed to understand the atomization and spray pattern characteristics of the injector. Next, a combustion test was performed at the design point to understand the ignition and combustion stability. Additional combustion tests were performed according to the O/F ratio to investigate the combustion characteristics and stabilities using the characteristic exhaust velocity ($C^*$) and fluctuation of the chamber pressure. The experimental results showed that the combustion efficiency was greater than 90%, and the pressure fluctuation was lower than 2% under all conditions.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.12 no.2
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• pp.99-107
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• 1998

This dissertationhas confirmed the non-flam mability of cast mold transformer that is increasingly used lately. As a research progress, the investigation has been performed on the installation status and each line of the subway system which have the most mold transformer accidents, and the impediment status of the transformer for rectifier and the high-voltage distribution transformer per each manufacturer. Then, a high voltage mold of the actual mold transformer has been installed in the horiwntal heating furnace and the heat has been applied by the standard heating temperature curve of KSF 2257(Fireproof testing meth od of the construction structures: 1993). Accordingly, the combustibility of the mold transformer based on the test results has been found that 78 minutes has been required for the complete burning per the KSF 2257 combustion test curve and that, after stopping the heat application of the horizontal furnace after ignition, the flame progress has not been made but shown as the self-extinguishing characteristics when the flame progress has been checked. Thus, the non-flammability and self-extinguishability of the mold transformer have been confirmed. The result of this dissertation has indicated that the accident involving mold transformer has been progressed and expanded by the dielectric breakdown or void due to the crack in the mold rather than a fire accident caused by a short-circuit or an overload.r an overload.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.1
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• pp.54-59
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• 2011

This test established the bioavailability and sample input by mixing the maintaining the microbial machine parts and food waste leachates in weight of 2:1 as advanced experiment, maintaining the constant temperature, agitating and observing its weight and property change for 60 hours. And, I injected daily the established microbial machine parts and food waste leachates rate, maintained the temperature in the reactor with $55{\sim}65^{\circ}C$, and agitated with constant speed. I studied the recycling possibility of food waste leachates by extracting the sample after 24 hours, verifying its characteristics, and repeating the food waste leachates input and sample extraction for about 40 days. Considering all about the results of this study, I saw that 87.32% of food waste leachates was reduced, and the solid of bluebug or food included in the food waste leachates was decomposed within 24 hrs. pH for 43 days after 9 days of stabilization period was maintained from 3.7~3.9 and the ignition loss from 88.67~87.3%, and the quantity of organic matter from 77.6~80.88%. With the similar result daily maintained, it is considered to progress more the minimization by inputting the future food waste leachates. C/N rate satisfies the less than 25 that is the composting basis within 8 days, maintaining between 13~15, with 2% of salt not exceeded, it is able to recycle as the compost of food waste leachates as based on the composting with no extracted heavy metal content.

• Korean Journal of Materials Research
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• v.32 no.1
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• pp.9-13
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• 2022

Bullets flying with a light from the back are called "tracers". Tracers are ignited by the combustion gas of the propellant and emit bright light that allows the shooter to visually trace the flight path. Therefore, tracers mark the firing point for allies to assist shooters to hit target quickly and accurately. Conventional tracers are constructed with a mixture of an oxidizing agent, raw metal, and organic fuel. Upon ignition, the inside of the gun can be easily contaminated by the by-products, which can lead to firearm failure during long-term shooting. Moreover, there is a fire risk such as forest fires due to residual flames at impact site. Therefore, it is necessary to develop non-combustion type luminous material; however, this material must still use the heat generated from the propellant, so-called "thermoluminescence (TL)". This study aims to compare the TL emission of Dy³⁺, La³⁺ and Ho³⁺ doped MgB₄O₇ phosphors prepared by solid state reaction. The crystal structures of samples were determined by X-ray diffraction and matched with the standard pattern of MgB₄O₇. Luminescence of various doses (200 ~ 15,000 Gy) of gamma irradiated Dy³⁺, La³⁺ and Ho³⁺ (at different concentrations of 5, 10, 15 and 20 %) doped MgB₄O₇ were recorded using a luminance/color meter. The intensity of TL yellowish (CIE x = 0.401 ~ 0.486, y = 0.410 ~ 0.488) emission became stronger as the temperature increased and the total gamma-ray dose increased.