• Journal of the Korean Institute of Gas
• /
• v.5 no.2 s.14
• /
• pp.9-13
• /
• 2001

A complete spectrum of risk assessment including qualitative and quantitative approaches were performed for the POSCO's Batch Annealing Furnace (BAF) gas systems. The purpose of BAF is to enhance the quality of steel by annealing it with either hydrogen/nitrogen mixture gas or pure hydrogen gas. Number of gas leak scenarios were identified to generate frequency of their occurrences. With the hypothetical accident scenarios given, fire/explosion impact studies were performed to estimate magnitude of significant consequences. Several different indices were also presented from which practical safety improvement action items could be established.

• Fire Science and Engineering
• /
• v.14 no.4
• /
• pp.7-16
• /
• 2000

In the study, three criteria(toxicity, fire & explosion, environment) and damage prediction method for each case was set up, and all these criteria were applied to the subject substance that was selected as hazardous level by integrating all criteria through Algorithm. Particularly, the environment criterion is a comprehensive concept, environment index modeling by combining USCG(United State Coast Guard) & MSDS(Material Safety Data Sheet) environment criteria classifications and the environment part of MFPA's health hazardousnes(Nh). And for damage prediction method of each criterion were adopted and they were applied to hazardous chemical substances in use or stored by chemical substance related enterprises located in each region that made possible to set up total hazard level of used substances(inflammability, poisonousness and counteraction on a unit substance, and hazard level & display modeling on environment) & damage prediction in case of accident & solidity setup(CPQRA: Chemical Process Quantitative Risk Assessment, IAEA: International Atomic Energy Agency, VZ eq: Vulnerable Zone) risk counter. Thus it is deemed that it can be applied to toxic substance leakage that can happen during any chemical processing & storage, application as a tool for prior safety evaluation through potential dangerousness computation of fire & explosion.

• Fire Science and Engineering
• /
• v.31 no.5
• /
• pp.1-6
• /
• 2017

The fire and explosion properties of combustible materials are necessary for the safe handling, storage, transportation and disposal. Typical combustion characteristics for process safety include auto ignition temperature(AIT). The AIT is an important index for the safe handling of combustible liquids. The AIT is the lowest temperature at which the material will spontaneously ignite. In this study, the AITs and ignition delay times of n-pentanol and p-xylene mixture were measured by using ASTM E659 apparatus. The AITs of n-pentanol and p-xylene which constituted binary system were $285^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs and ignition delay times of n-pentanol and p-xylene mixture were a good agreement with the calculated AITs and ignition delay times by the proposed equations with a few A.A.D. (average absolute deviation). Therefore, it is possible to estimate the AITs and ignition delay times in other compositions of n-pentanol and p-xylene mixture by using the predictive equations which presented in this study.

• Journal of the Korean Society of Safety
• /
• v.35 no.6
• /
• pp.78-84
• /
• 2020

The F&EI technique is one of the risk assessments with many advantages. It can save time and effort compared to quantitative risk assessment (QRA). By using the evaluation result of this technique, it is possible to check the effectiveness of the investment cost. In addition, a relative risk ranking can be created and used to establish the facility management cycle and to prioritize investment. However, evaluating the target process can be evaluated more than the actual risk since the LCCF, a loss prevention measure, is too limited. In addition, calculating premiums via this method can result in excessive premiums, making it difficult to evaluate the risk precisely. Therefore, new safety guard was added to the LCCF of the F&EI risk assessment with reference to HAZOP and LOPA techniques. Newly added LCCFs are Deflagration arrester, Check valve, SIS, and Vacuum beaker, etc. As a case study, F&EI risk assessment was performed on Acetone storage tank of a API (Active pharmaceutical ingredient) plant to compare actual MPPD. The estimated loss amount was 592,558$ for the existing technique and 563,571$ for the improved technique, which was reduced by about 5% compared to the previous one.This proved that a more precise evaluation is possible and that the efforts for safety at the workplace are reflected in the evaluation results.

• Journal of the Korean Institute of Gas
• /
• v.25 no.1
• /
• pp.40-47
• /
• 2021

In this study, hazards of decomposition and explosion for tert-butylperoxymaleate(TBPM), an organic peroxide, were evaluated by using various equipment to determine the cause of a fire explosion accident. As a result of DSC analysis, the instantaneous power density of TBPM was 26,401 kW/ml, and the NFPA reactive index(Nr) was classified as 4. And the positive value of EP(explosive propagation) and SS(shock sensitivity) showed that the TBPM had a potential hazard of explosion. From the experimental results, the shock sensitivity and friction sensitivity was rated as class 4 and 5, respectively. In the pressure vessel test, TBPM was ranked USA-PVT No.4 and evaluated as a self-reactive substance. In the combustion rate test, TBPM had the combustion rate of 167 mm/sec and was evaluated as the flammable solid classification 2 in GHS.

• Korean Chemical Engineering Research
• /
• v.57 no.6
• /
• pp.790-803
• /
• 2019

The dioctyl terephthalic acid (DOTP) process produces plastic plasticizers by esterification of terephthalic acid with powder in the form of octanol. In this study, the dust explosion characteristics of terephthalic acid directly injected into the manhole in the form of powder in the presence of flammable solvent or vapor in the reactor of this process were investigated. Dust particle size and particle size distribution dust characteristics were investigated, and pyrolysis characteristics of dust were investigated to estimate fire and explosion characteristics and ignition temperature. Also, the minimum ignition energy experiment was performed to evaluate the explosion sensitivity. As a result, the average particle size of terephthalic acid powder was $143.433{\mu}m$. From the thermal analysis carried out under these particle size and particle size distribution conditions, the ignition temperature of the dust was about $253^{\circ}C$. The lower explosive limit (LEL) of the terephthalic acid was determined to be $50g/m^3$. The minimum ignition energy (MIE) for explosion sensitivity is (10 < MIE < 300) mJ, and the estimated minimum ignition energy (Es) based on the ignition probability is 210 mJ. The maximum explosion pressure ($P_{max}$) and the maximum explosion pressure rise rate $({\frac{dP}{dt}})_{max}$ of terephthalic acid dust were 7.1 bar and 511 bar/s, respectively. The dust explosion index (Kst) was 139 mbar/s, corresponding to the dust explosion grade St 1.

• Korean Chemical Engineering Research
• /
• v.62 no.1
• /
• pp.27-35
• /
• 2024

Fuel gases such as methane and propane are used in explosion hazardous area of domestic plants and can form non-uniform mixtures with the influence of process conditions due to leakage. The fire-explosion risk assessment using literature data measured under uniform mixtures, damage prediction can be obtained the different results from actual explosion accidents by gas leaks. An explosion characteristics such as explosion pressure and flame velocity of non-uniform gas mixtures with concentration change similar to that of facility leak were examined. The experiments were conducted in a closed 0.82 m long stainless steel duct with observation recorded by color high speed camera and piezo pressure sensor. Also we proposed the quantification method of non-uniform mixtures from a regression analysis model on the change of concentration difference with time in explosion duct. For the non-uniform condition of this study, the area of flame surface enlarged with increasing the concentration non-uniform in the flame propagation of methane and was similar to the wrinkled flame structure existing in a turbulent flame. The time to peak pressure of methane decreased as the non-uniform increased and the explosion pressure increased with increasing the non-uniform. The ranges of K_G (Deflagration index) of methane with the concentration non-uniform were 1.30 to 1.58 [MPa·m/s] and the increase rate of K_G was 17.7% in methane with changing from uniform to non-uniform.

• Safety and Health at Work
• /
• v.11 no.3
• /
• pp.322-334
• /
• 2020

Background: Spontaneous combustion of coal is one of the factors which causes direct or indirect gas and dust explosion, mine fire, the release of toxic gases, loss of reserve, and loss of miners' life. To avoid these incidents, the prediction of spontaneous combustion is essential. The safety of miner's in the mining field can be assured if the prediction of a coal fire is carried out at an early stage. Method: Adularya Underground Coal Mine which is fully mechanized with longwall mining method was selected as a case study area. The data collected for 2017, by sensors from ten gas monitoring stations were used for the simulation and prediction of a coal fire. In this study, the fuzzy logic model is used because of the uncertainties, nonlinearity, and imprecise variables in the data. For coal fire prediction, CO, O₂, N₂, and temperature were used as input variables whereas fire intensity was considered as the output variable.The simulation of the model is carried out using the Mamdani inference system and run by the Fuzzy Logic Toolbox in MATLAB. Results: The results showed that the fuzzy logic system is more reliable in predicting fire intensity with respect to uncertainties and nonlinearities of the data. It also indicates that the 1409 and 610/2B gas station points have a greater chance of causing spontaneous combustion and therefore require a precautional measure. Conclusion: The fuzzy logic model shows higher probability in predicting fire intensity with the simultaneous application of many variables compared with Graham's index.

• Journal of the Korean Society of Safety
• /
• v.10 no.2
• /
• pp.92-96
• /
• 1995

The flash point is generally used as a hazardous index of fire or explosion of a flammable liquid. In this study, the lower flash points and the upper flash points according to the composition of Toluene-o-Xylene and Toluene-Methyl Ethyl Ketone mixtures are determined by air-blowing method. As results, relations between the flash points and the compositions of mixtures ; (1) for Toluene-o-Xylene mixtures $T_{fL}$=25.23 $\alpha$ ＋5.34 $T_{fu}$=27.36 $\alpha$ ＋40.50 (2) for Toluene-Methyl Ethyl Keton mixtures $T_{fL}$=10.00 $\beta$-5.00 $T_{fu}$=16.91 $\beta$＋20.45.

• Fire Science and Engineering
• /
• v.13 no.1
• /
• pp.11-19
• /
• 1999

The flash point is generally used as a hazardous index of fire and explosion of a flammable liquid. A classification of the flash points is important for the safe handling of flammable liquids such as solvent mixtures. The flash points of pure substances and solvent mixtures can be c calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and a activity coefficient models. In this study, experimentally determined lower and upper flash points w were compared with the calculated values by using Raoult's law and van Laar equation. The flash points of pure substances were in agreement with the calculated values by vapor pressure and e explosive limits. Also, the lower flash points of M.E.K(methylethylketone)-toluene system were i in agreement with the predicted values by Raoult’s law, and the upper flash points were in a agreement with the predicted values by van Laar equation. By means of this methodology, it is possible to evaluate reliability of expermental data of the flash points of the flammable mixtures.