• Title/Summary/Keyword: Fire & Explosion

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A Study on the Damage Range of Chemical Leakage in Polysilicon Manufacturing Process (폴리실리콘 제조 공정에서 화학물질 누출 시 피해범위에 관한 연구)

  • Woo, Jongwoon;Shin, Changsub
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.55-62
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    • 2018
  • There is growing interest in solar power generation due to global warming. As a result, demand for polysilicon, which is the core material for solar cells, is increasing day by day. As the market grows, large and small accidents occurred in the production process. In 2013, hydrochloric acid leaked from the polysilicon manufacturing plant in SangJu. In 2014, a fire occurred at a polysilicon manufacturing plant in Yeosu, and in 2015, STC(Silicon Tetrachloride) leaked at a polysilicon manufacturing plant in Gunsan City. Leakage of chemicals in the polysilicon manufacturing process can affect not only the workplace but also the surrounding area. Therefore, in this study, we identified the hazardous materials used in the polysilicon manufacturing process and quantitatively estimate the amount of leakage and extent of damage when the worst case scenario is applied. As a result, the damage distance by explosion was estimated to be 726 m, and the damage distance to toxicity was estimated to be 4,500 m. And, if TCS(Trichlorosilane), STC(Silicon Tetrachloride), DCS(Dichlorosilane) leaks into the air and reacts with water to generate HCl, the damage distance is predicted to 5.7 km.

Risk Analysis for Installation Types of Pressure Safety Valve used in the High-pressure Gas Facility (고압가스 사용시설 내 안전밸브 설치유형별 리스크 분석)

  • Kim, Myung-Chul;Woo, Jeong-Jae;Lee, Hyung-Sub;Baek, Jong-Bae
    • Journal of the Korean Society of Safety
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    • v.32 no.4
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    • pp.129-136
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    • 2017
  • This study investigated the probability of possible accident through qualitative and quantitative analysis of the pressure safety valve types installed in facilities using high pressure gas to compare the installation domestic and foreign pressure safety valve standards sought the safety characteristics and safety improvement direction accordingly. The three types are the case where the shut-off valve is not installed at the front of the PSV (Case A), If a shut-off valve is installed at the front of the PSV for inspection (Case B) and If a shut-off valve is installed in front of PSV (C.S.O), PSV is installed in parallel (Case C). Three types of cases were compared with FTA and HAZOP. The results of study of the possible accidents due to over-pressure safety valve installation type, used in a high-pressure gas facilities was shows in the following order Case B > Case A > Case C. The results of analysis through FTA was in order to protect the reservoir for the possible occurring of accident the safety valve installation is depend on its type. In the FTA analysis, defects in the device itself which attached to the storage tank as a substitute for analysis of the probability of operator mistakes was Case B with as high as $2.01{\times}10^{-6}$. Depending on the type of installation analysis of Case B in order to ensure safety is prohibited to install shut-off valve and believes that mandatory regulations are needed. Rationally installing of pressure safety valve in the high pressure using facilities will be expected to improve the industrial safety from severe accidents such as high-pressure gas fire explosion.

A Study of Liquid Nitrogen Inert Gas System for LNGC Diesel Engine Crank Chamber (LNGC 디젤기관 크랭크 챔버용 액체질소 불활성가스 시스템에 관한 연구)

  • Choi, Bu-Hong;Kim, Hyun-Soo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.3
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    • pp.279-285
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    • 2012
  • It is necessary to install the inert gas system(IGS) for preventing fire and explosion in LNGC main diesel engine crankcase besides oil mist detector(OMD) unit with $CO_2$ gas injector. Therefore, to design the liquid nitrogen IGS, analytical work is conducted for predicting the heat input load of liquid nitrogen heater with two-phase stratified flow model. This paper also presents the effects of changes in pipe diameter, saturated pressure, and inclination angle by ship's movement on cryogenic two-phase stratified flows. It is found that the stratified model gives reasonable predictions, and the model is effective to predict the heat input load of liquid nitrogen IGS.

A Study on Ignition Hazard Caused by Electrostatic Discharge of Gasoline Used in the Gas Station (주유소에서 사용하는 휘발유의 정전기 방전으로 인한 점화위험성에 관한 연구)

  • Moon, Kyoon-Tae;Chung, Jae-Hee;Mizuki, Yamaguma;Choi, Kwang-Seok
    • Journal of the Korean Society of Safety
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    • v.25 no.4
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    • pp.13-18
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    • 2010
  • To investigate electrostatic ignition hazards of commercial gasoline used in the gas station, experiments were conducted dealing with the minimum ignition energy(MIE) of several kinds of gasoline under the various temperature. The conductivity of gasoline that was required for an accurate risk assessment as well as the MIE were also examined. The solvent ignitability apparatus which can heat up the inside of the vessels up to $210^{\circ}C$ was used in this study. Four kinds of premium gasoline and four kinds of regular gasoline, differing with respect to the companies, were used as test specimens. The following results were obtained: (1) all gasoline specimens were so sensitive that even an electrostatic discharge with a very low energy, such as about 0.5mJ, could ignite them. The ignitability of premium gasoline was constant irrespective of the companies. On the other hand, the ignitability of regular gasoline was variable depending on the company. (2) The MIE of all specimens depended markedly on the temperature; in other words, an increase in temperature decreases the ignition energy value. (3) The conductivity values of all specimens were low. Those must be taken into consideration in electrostatic risk assessment.

The implementation of liquefaction equipment monitoring system based on Android (안드로이드 기반의 유증기 액화장치 모니터링 시스템 구현)

  • Park, Man-Kyu;Tack, Han-Ho;Kim, Gwan-Hyung
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.3
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    • pp.583-589
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    • 2016
  • Volatile organic compounds(VOCs) are regarded as a harmful cause substance not only causing air pollutions but also causing global warming phenomenon. For this reason, VOCs are managed politically to reduce emissions by each country. In particular, the vapor from the gas station contains VOCs which is harmful to the human body such as carcinogens benzene and pollute the atmosphere, the Ministry of Environment defined every gas station must install vapor recovery equipment to recover volatile organic compounds. Recently, there are many accidents caused by existing vapor treatment methods, the liquefaction recovery technology is getting the spotlight to cool the vapor at the field. However, because the liquefaction recovery technology have risks of fire or explosion in accordance with temperature, the real time monitoring is critical factor. In this paper, we implement an Android-based monitoring application for liquified vapor recovery device which attached sensor module for temperature and power to monitoring real time information.

A Study on the Shelf-Life Prediction of the Domestic Single Base Propellants Ammunition : Based on 105mm High Explosive Propellants (국내 단기추진제 탄약의 저장수명 예측에 관한 연구 : 105미리 고폭탄 추진체를 중심으로)

  • Choi, Myoungjin;Park, Hyungju;Yang, Jaekyung;Baek, Janghyun
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.37 no.3
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    • pp.36-42
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    • 2014
  • Domestic 105mm HE (High Explosive) shell is composed of three parts that are Fuze, Projectile and Propellants. Among three parts, propelling charge of propellants part consists of single base propellants. It has been known that the lifespan of single base propellants is affected by a storage period. These are because Nitrocellulose (NC) which is the main component of propelling gunpowder can be naturally decomposed to unstable substances similar with other nitric acid ester. Even though it cannot be prevented fundamentally from being disassembled, a decomposition product ($NO_2$, $NO_3$, and $HNO_3$) and tranquillizer DPA (Diphenylamine) having high reactivity are added into a propellant to restrain induction of automatic catalysis by a decomposition product. The decay rate of the tranquillizer is also affected by a production rate of the decomposition product of NC. Therefore, an accurate prediction of the Self-Life is required to ensure against risks such as explosion. Hereupon, this paper presents a new methodology to estimate the shelf-life of single base propellants using data of ASRP (Ammunition Stockpile Reliability Program) to domestic 105mm HE (propelling charge of propellants part). We selected four attributes that are inferred to have influence on distribution of the DPA amount in a propellant from the ASRP dataset through data mining processes. Then the selected attributes were used as independent variables in a regression analysis in order to estimate the shelf-life of single base propellants.

Kinetic Analysis of Energetic Materials Using Differential Scanning Calorimetry (DSC를 이용한 고에너지 물질의 반응속도식 추출과 활용)

  • Kim, Yoocheon;Park, Jungsoo;Yang, Seungho;Park, Honglae;Yoh, Jai-Ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.1
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    • pp.33-41
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented on $B/KNO_3$ for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

Efficient Fluid Simulation through Various User Design-type Emission Control Solutions (사용자 설계형의 방출 제어 솔루션을 통한 효율적인 유체 시뮬레이션 구현)

  • Hwang, Min-Sik;Lee, Hyun-Seok
    • Journal of Digital Convergence
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    • v.16 no.6
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    • pp.197-204
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    • 2018
  • The realistic Visual Effects using fluid simulation in 3D computer graphics are operated as important factors to improve the quality of images. The process of creating realistic motions of water, fire, explosion by controlling each property of fluid is called fluid simulation. In general, the creation of a fluid simulation concentrates on the main simulation work phase, however an effective method for initial set up is important for the main simulation work. The purpose of this study is to analyze the factors involved in the initial emission motion and shape of fluid and propose methods that can efficiently apply this into the initial set up. For the process of the research, first, problems are raised based on related researches, and second, two experiments, 'Dynamic Fluid Emitter Creation' and 'User Design Type Emission Velocity Solution', are conducted for more effective fluid simulation. Through this research, the effective fluid simulation of initial set up phase will be suggested through the user design-type emission control solutions.

Initiating Events Study of the First Extraction Cycle Process in a Model Reprocessing Plant

  • Wang, Renze;Zhang, Jiangang;Zhuang, Dajie;Feng, Zongyang
    • Journal of Radiation Protection and Research
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    • v.41 no.2
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    • pp.117-121
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    • 2016
  • Background: Definition and grouping of initiating events (IEs) are important basics for probabilistic safety assessment (PSA). An IE in a spent fuel reprocessing plant (SFRP) is an event that probably leads to the release of dangerous material to jeopardize workers, public and environment. The main difference between SFRPs and nuclear power plants (NPPs) is that hazard materials spread diffusely in a SFRP and radioactive material is just one kind of hazard material. Materials and Methods: Since the research on IEs for NPPs is in-depth around the world, there are several general methods to identify IEs: reference of lists in existence, review of experience feedback, qualitative analysis method, and deductive analysis method. While failure mode and effect analysis (FMEA) is an important qualitative analysis method, master logic diagram (MLD) method is the deductive analysis method. IE identification in SFRPs should be consulted with the experience of NPPs, however the differences between SFRPs and NPPs should be considered seriously. Results and Discussion: The plutonium uranium reduction extraction (Purex) process is adopted by the technics in a model reprocessing plant. The first extraction cycle (FEC) is the pivotal process in the Purex process. Whether the FEC can function safely and steadily would directly influence the production process of the whole plant-production quality. Important facilities of the FEC are installed in the equipment cells (ECs). In this work, IEs in the FEC process were identified and categorized by FMEA and MLD two methods, based on the fact that ECs are containments in the plant. Conclusion: The results show that only two ECs in the FEC do not need to be concerned particularly with safety problems, and criticality, fire and red oil explosion are IEs which should be emphatically analyzed. The results are accordant with the references.

Enhancing the Blast Resistance of Structures Using HPFRCC, Segmented Composites, and FRP Composites (HPFRCC, 분절 복합체 및 FRP를 활용한 구조물의 내폭 성능 향상)

  • Yoon, Young-Soo;Yang, Jun-Mo;Min, Kyung-Hwan;Shin, Hyun-Oh
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.745-748
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    • 2008
  • The past structures were just required bearing capacity to service load, serviceability, and resistance to corrosion. However this point of view has changed after 9.11 terrorism, capacities which can bear impact loading by explosion, and heat by fire happening at the same time, become to be important as a basic condition. The blast resistance capacity of structures is very important part against all over the world is intimidated by terrorism everyday in current point of time. The target of this research is a development of segmented composites and layered structures with high blast resistance using cementitious composites, concrete and FRP composites, which has high tensile strength and ductility, to apply in not only existing facilities but also new ones. Through the improvement of blast resistance, casualties and economic loss can be minimized, and it is possible to diminish the structure collapse and delay the time of structure collapse by thermal effect, impact loading, dynamic loading and high strain.

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