• Title/Summary/Keyword: Filling of inorganic fillers

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Fire-Retardation Properties of Polyurethane Nanocomposite by Filling Inorganic Nano Flame Retardant (폴리우레탄 복합체의 무기난연재료 충전에 의한 난연 특성)

  • Son, Bok-Gi;Hwang, Taek-Sung;Goo, Dong-Chul
    • Polymer(Korea)
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    • v.31 no.5
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    • pp.404-409
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    • 2007
  • Polyurethane nanocomposites with inorganic nano fillers for the improvement thermal stability were prepared by the urethane reaction. Fire retardation properties of polyurethane nanocomposites were investigated by cone calorimeter and limited oxygen index (LOI). Maximum heat release rate of MMT-PU and $Bi_2O_3-PU$ polyurethane nanocomposites were decreased as 50% than polyurethane matrix and fire retardation properties of $MMT/Bi_2O_3-PU$ nanocomposte had the best improvement. The LOI of polyurethane nanocomposites also were improved as filling fillers in the nanocomposites over 20. The maximum heat release rates of MMT-PU, $Bi_2O_3-PU\;and\;MMT/Bi_2O_3-PU$ polyurethane nanocomposites were 764, 707, $635kW/m^2$, respectively and $MMT/Bi_2O_3-PU$ polyurethane nanocomposite exhibited the highest value of fire-retardant. We confirmed that polyurethane nanocomposites improved the fire retardation properties.

Impregnation Effects of Water Soluble Organic and Inorganic Chemicals into Micropore of Cell Wall of Waste Paper fiber(I) (페지섬유의 세포벽 Micropore 속으로 수용성 유기 및 무기화합물 충전효과(제1보))

  • 이병근
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.1
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    • pp.36-42
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    • 1997
  • The fiber wall filling(FWF) technology, which is based on Precipitatin of fillers in the micropores of the cell wall structure of never-dried chemical pulp fiber, has been developed to improve filling and loading process in papermaking. In presenting FWF technique here, micropores of pulp fiber are first impregnated with an ionic solution of water soluble salt and consecutively impregnated with the second salt solution. This procedure generates an insoluble precipitate within the micropores of cell wall by chemical interaction of these two ionic salt solutions This is the first attempts to use FWF technology for the quality of waste paper grade which is recycled in papermaking, even though this FWF technology has been impressively improved for never-dried chemical pulp in filling and loading process of papermaking. The precipitated amount of CaCO$_3$ and SrCO$_3$ reached 5-6% and 4-5% of the waste paper weight respectively, which was measured by ash content of the burned waste paper fiber. On the other way the precipitated amounts of those materials impregnated into never-dried chemical pulp fiber have reached 17-18% and 16-18% respectively. The micropore loading technique gives optical and physical properties to the handsheets formed with celt-wall-filled fibers which are better than those handsheet properties resulting from conventional loading. The papers made from the cell-wall-filled pulps are stronger than those with the customary location of filler between the fibers.

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Effects of Chemical Composition and Particle Size of Starting Aluminum Source on the Spheroidization in the Flame Fusion Process (화염용융법에 의한 구상 알루미나 제조에 미치는 초기 알루미나 원료의 화학조성과 입도의 영향)

  • Eom, Sun-Hui;Pee, Jae-Hwan;Lee, Jong-Keun;Hwang, Kwang-Taek;Cho, Woo-Seok;Kim, Kyeong-Ja
    • Journal of Powder Materials
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    • v.16 no.6
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    • pp.431-437
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    • 2009
  • Various inorganic fillers improve the thermal conductivity and physical properties of organic products. Alumina has been used a representative filler in the heat radiation sheet for the heat radiation of electric device. The high filling rate of alumina increases the thermal conductivity and properties of products. We successfully developed the spherical alumina by flame fusion process using the oxygen burner with LPG fuel. In the high temperature flame (2500$\sim$3000$^{\circ}C$) of oxygen burner, sprayed powders were melting and then rotated by carrier gas. This surface melting and rotation process made spherical alumina. Especially effects of chemical composition and particle size of stating materials on the melting behavior of starting materials in the flame and spheroidization ratio were investigated. As a result, spheroidization ratio of boehmite and aluminum hydroxide with endothermic reaction of dehydration process was lower than that of the sintered alumina without dehydration reaction.

Compressive Strength Evaluation of Concrete with Mixed Plastic Waste Aggregates Filled with Blast Furnace Slag Fine Powder (무기충진재를 혼입한 복합 폐플라스틱 골재를 활용한 콘크리트 압축강도 특성)

  • Lee, Jun;Kim, Kyung-Min;Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Wook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.253-259
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    • 2021
  • Plastic wastes generated from household waste are separated by mixed discharge with foreign substances, and recycling is relatively low. In this study, the effect of the ratio and content of mixed plastic waste coarse aggregate(MPWCA)s and mixed plastic waste fine aggregate(MPWFA)s filled with blast furnace slag fine powder on the slump and compressive strength of concrete was evaluated experimentally. The MPWCAs were found to have a similar fineness modulus, but have a single particle size distribution with a smaller particle size compared to coarse aggregates. However, the MPWFAs were found to have a single particle size distribution with a larger fineness modulus and particle size compared to fine aggregates. Meanwhile, the effect of improving the density and filling pores by the blast furnace slag fine power was found to be greater in the MPWFA compared to the MPWCA. As the amount of the mixed plastic waste aggregate(MPWA)s increased, the slump and compressive strength of concrete decreased. In particular, the lower the slump and compressive strength of concrete was found to decrease the greater the amount of MPWFA than MPWCA when the amount of MPWA was the same. This is because of the entrapped air and voids formed under the angular- and ROD-shaped aggregates among the MPWFAs. On the other hand, the addition of the admixture and the increase in the unit amount of cement were found to be effective in improving the compressive strength of the concrete with MPWAs.