• Title/Summary/Keyword: Filler material

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Interfacial Phenomena of Lignocellulose Fiber/Thermoplastic Polymer Composites (리그노셀룰로오스 섬유/열가소성 고분자 복합재의 계면 현상)

  • Son, Jungil;Yang, Han-Seung;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.3 no.4
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    • pp.44-52
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    • 2002
  • Composite materials are created by combining two or more component to achieve desired properties which could not be obtained with the separate components. The use of reinforcing fillers, which can reduce material costs and improve certain properties, is increasing in thermoplastic polymer composites. Currently, various inorganic fillers such as talc, mica, clay, glass fiber and calcium carbonate are being incorporated into thermoplastic composites. Nevertheless, lignocellulose fibers have drawn attention due to their abundant availability, low cost and renewable nature. In recent, interest has grown in composites made from lignocellulose fiber in thermoplastic polymer matrices, particularly for low cost/high volume applications. In addition to high specific properties, lignocellulose fibers offer a number of benefits for lignocellulose fiber/thermoplastic polymer composites. These include low hardness, which minimize abrasion of the equipment during processing, relatively low density, biodegradability, and low cost on a unit-volume basis. In spite of the advantage mentioned above, the use of lignocellulose fibers in thermoplastic polymer composites has been plagued by difficulties in obtaining good dispersion and strong interfacial adhesion because lignocellulose fiber is hydrophilic and thermoplastic polymer is hydrophobic. The application of lignocellulose fibers as reinforcements in composite materials requires, just as for glass-fiber reinforced composites, a strong adhesion between the fiber and the matrix regardless of whether a traditional polymer matrix, a biodegradable polymer matrix or cement is used. Further this article gives a survey about physical and chemical treatment methods which improve the fiber matrix adhesion, their results and effects on the physical properties of composites. Coupling agents in lignocellulose fiber and polymer composites play a very important role in improving the compatibility and adhesion between polar lignocellulose fiber and non-polar polymeric matrices. In this article, we also review various kinds of coupling agent and interfacial mechanism or phenomena between lignocellulose fiber and thermoplastic polymer.

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Fundamental study on the development of Filling materials for Trenchless Emergency Restoration of Ground cavity (비개착식 지반공동 긴급복구를 위한 충전재료 개발에 관한 기초 연구)

  • YU, Nam-Jae;Choi, Ju-Hyun;Lee, Kang-Il
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.2
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    • pp.97-107
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    • 2017
  • Recently, there have been a lot of incidents related to ground sinks in urban areas, but restoration work is complicated and inconvenience due to on-site control, and particularly, grouting and soil filling are generally applied as recovery measures, but when the grouting or the soil filling is carried out, material segregation phenomenon occurs in the ground or a lot of restoration amount is often required, depending on the state of sinks and the existence of groundwater under the ground and the soil can be lost due to the flow of the ground water, and thus the purpose of this study is to develop a pouch-type filler applied to a trenchless method for emergency reinforcement of the ground sinks with the aim of quick recovery of the ground sink in urban areas, and as a result, it was confirmed that compression strength and the expansion ratio were different according to the temperature of ground water and the compression strength and the expansion ratio could be controlled by mixing alumina powder.

Experimental Study on Dry Waterproofing Technology Using Synthetic Polymer Sheet Comprised of Synthetic Resin Metal Sheets and Tri-Layered Filler (합성수지 메탈시트와 3면겹침용 채움재가 공법화된 합성고분자계 시트를 이용한 건식화 방수기술에 대한 실험적 연구)

  • Koo, Ja-Ung;Kim, Bum-Soo;Lee, Jung-Hun;Song, Je-Young;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.139-140
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    • 2017
  • This technology employs a method of forming a single-ply PLUS waterproofing sheet layer comprised of applying a single-ply synthetic polymer layer on a vibrating structure (steel frame, RC) or an inclined surface by using a T joint lap-filling coil and an embedded metal coated sheet. The T - joint reinforcing lap-filling coil was used to block the ingress channel of the rainwater by applying the material in the vulnerable area where the three sides of the waterproof sheet overlapped. Conventional waterproofing techniques have a problem in that the waterproof sheet is pierced because the end portion of the waterproof sheet applied to the vertical portion is fixed by a nail, and the sealant applied to the end portion of the sheet cannot easily secure long-term waterproof durability due to the influence of the external environment. Therefore, the developed technology secured the waterproof durability against the vertical part by using the embedded metal sheet. In addition, automatic hot-air fusing is used to improve the quality of waterproof construction and point fixation method using fixed hardware. This is a technology that is not significantly restricted in the high degradation level regions of domestic waterproof construction environments in Korea such as low-temperature environment, wet floor.

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Effect of Particle Size and Dispersion on Dielectric Properties in ZnO/Epoxy Resin Composites

  • Yang, Wenhu;Yi, Ran;Yang, Xu;Xu, Man;Hui, Sisi;Cao, Xiaolong
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.3
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    • pp.116-120
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    • 2012
  • In this paper, ZnO-Epoxy nanocomposites (NEP) were prepared and epoxy composites that contain 5 wt% micro ZnO (MEP) and deliberately not well dispersed nano ZnO (NDNEP) were also prepared for purpose of comparison. The effects of the particle size and dispersion of ZnO on dielectric properties of epoxy resin were chiefly studied. Test results showed that: at a loading of 5 wt%, the three epoxy composites seem to have no significant difference on resistivity compared to epoxy resin; Dielectric constants of all the epoxy composites are also basically the same but they are bigger compared to that of the pure epoxy resin (unfilled); Dielectric dissipation factors ($tan{\delta}$) of NDNEP is greater than that of NEP and MEP. NEP has the minimum dielectric loss factor, whereas dielectric loss factors of the three epoxy composites are larger than that of the pure epoxy resin. The decreasing order of electrical breakdown strength for the three epoxy composites and for the pure epoxy resin is as follows: NEP>MEP>NDNEP>EP. Finally, in order to explain the experimental results the aggregation interface phase was proposed. Furthermore, addition of well dispersed nano filler has proved to have a positive effect on the improvement of the dielectric properties of epoxy resin.

EFFECT OF PH AND STORAGE TIME ON THE ELUTION OF RESIDUAL MONOMERS FROM POLYMERIZED COMPOSITE RESINS (산도변화와 침지시간이 광중합 복합레진의 잔류단량체 유출에 미치는 영향)

  • Jeon, Cheol-Min;Yoo, Hyun-Mi;Kwon, Hyuk-Choon
    • Restorative Dentistry and Endodontics
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    • v.29 no.3
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    • pp.249-266
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    • 2004
  • The purpose of this study was to determine whether pH and time has any influence on the degradation behavior of composite restoration by analyzing the leached monomers of dental composites qualitatively and quantitatively after storage in acetate buffer solution as a function of time using high performance liquid chromatography (HPLC) / mass spectrometer. Materials and Methods:Three commercial composite restorative resin materials (Z-250, Heliomolar and Aeliteflo) with different matrix structure and filler composition were studied. Thirty specimens (7mm $diameter{\times}2mm$ thick) of each material were prepared. The cured materials were stored in acetate buffer solution at different pH (4, 7) for 1, 7 and 45days. As a reference, samples of unpolymerized composite materials of each product were treated with methanol (10mg/ml). Identification of the various compounds was achieved by comparison of their mass spectra with those of reference compound, with literature data. and by their fragmentation patterns. Data were analysed statistically using ANOVA and Duncan's test. Results:1. Amounts of leached TEGDMA in Aeliteflo were significantly larger than those of UDMA in Z-250 and Heliomolar at experimental conditions of different storage time and pH variation (p<0.001). 2. As to comparison of the amounts of leached monomers per sorage time, amounts of leached TEGDMA in Aeliteflo and UDMA in Z-250 and Heliomolar were increased in the pH 4 solution more significantly than in the pH 7 solution after 1day, 7days and 45days, respectively (p<0.001). 3. In total amounts of all the leached monomers with storage times, the overall amounts of pH 4 extracts were larger than those of pH 7 extracts for all resin groups, but there was no significant difference (p>0.05).

Development of Feature-based Encapsulation Process using Filler Material (충진재를 이용한 특징형상 가공용 RFPE 공정 개발)

  • Choe, Du-Seon;Lee, Su-Hong;Sin, Bo-Seong;Yun, Gyeong-Gu;Hwang, Gyeong-Hyeon;Lee, Ho-Yeong
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.1
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    • pp.98-103
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    • 2001
  • Machining is the commonly used process in the manufacturing of prototypes. This process offers several advantages, such as rigidity of the machine, precision of the machine, precision of the operation and specially a quick delivery. The weight and immobility of the machine support and immobilize the part during the operation. However, despite these advantages it shows, machining still presents several limitations. The immobilization, location and support of the part are referred to as fixturing or workholding and present the biggest challenge for time efficient machining. So it is important to select and design the appropriate fixturing assembly. This assembly depends on the complexity of the part and the tool paths and may require the construction of dedicated fixtures. With traditional techniques, the range of fixturable shapes is limited and the identification of suitable fixtures in a given setup involves complex reasoning. To solve this limitation and to apply the automation, this paper presents the Reference Free Part Encapsulation(RFPE) and implementation of the encapsulation system. The feature-based modeling system and the encapsulation system are implemented. The small part of which it is difficult to find out the appropriate fixturing assembly is made by this system.

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Micro Joining Process Using Solderable Anisotropic Conductive Adhesive (Solderable 이방성 도전성 접착제를 이용한 마이크로 접합 프로세스)

  • Yim, Byung-Seung;Jeon, Sung-Ho;Song, Yong;Kim, Yeon-Hee;Kim, Joo-Heon;Kim, Jong-Min
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.73-73
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    • 2009
  • In this sutdy, a new class ACA(Anisotropic Conductive Adhesive) with low-melting-point alloy(LMPA) and self-organized interconnection method were developed. This developed self-organized interconnection method are achieved by the flow, melting, coalescence and wetting characteristics of the LMPA fillers in ACA. In order to observe self-interconnection characteristic, the QFP($14{\times}14{\times}2.7mm$ size and 1mm lead pitch) was used. Thermal characteristic of the ACA and temperature-dependant viscosity characteristics of the polymer were observed by differential scanning calorimetry(DSC) and torsional parallel rheometer, respectively. A electrical and mechanical characteristics of QFP bonding were measured using multimeter and pull tester, respectively. Wetting and coalescence characteristics of LMPA filler particles and morphology of conduction path were observed by microfocus X-ray inspection systems and cross-sectional optical microscope. As a result, the developed self-organized interconnection method has a good electrical characteristic($2.41m{\Omega}$) and bonding strength(17.19N) by metallurgical interconnection of molten solder particles in ACA.

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A Study on the Insulation Characteristics of Epoxy Composites Using Electric Field Simulation

  • Lee, Deok-Jin
    • Journal of the Korea Society of Computer and Information
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    • v.26 no.2
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    • pp.53-60
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    • 2021
  • In this paper, we aimed to identify the insulation characteristics and reliability of Epoxy composites, which are widely used as insulation material for electrical & electronic components and electric appliance. To this end, it was necessary to predict variations of electric field due to the distribution of fillers that must be added by economic and mechanical factors. So, we verified the result using an electric field analysis Simulator. Furthermore, under the condtion of DC voltage application, an dielectirc breakdown test was performed according to ambient temperature changes and the distribution of fillers, and the changes were observed. Three types of specimens were manufactured by adding 0, 50 and 100[phr] filling to Epoxy resin. In all specimens, as temperature was increased, the strength of the dielectric strength was decreased. When comparing the simulation results with the actual dielectric breakdown test results, we was able to confirm the technical applicability required for Insulation design of electric appliance.

Efficient Management of the pH of the Wet Scrubber Washing Water for Risk Mitigation (리스크 완화를 위한 Wet Scrubber 세정수 pH의 효율적 관리)

  • Joo, Dong-Yeon;Seoe, Jae Min;Kim, Myung-Chul;Baek, Jong-Bae
    • Journal of the Korean Society of Safety
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    • v.35 no.6
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    • pp.85-92
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    • 2020
  • Wet Scrubber reacts the incoming pollutant gas with cleaning water (water + absorbent) to absorb pollutants and release the clean air to the atmosphere. Wet scrubbers and packed tower scrubbers using this principle are widely used in businesses that emit acid gases. In particular, in the etching process using hydrochloric acid (HCl), alkaline washing water (NaOH) having a pH of about 8 to 11 is used to absorb a large amount of acid gas. However, These salts are attached to the injection nozzle (nozzle), filling material (packing), and the demister (Demister), causing air pollution, human damage, and inoperability due to clogging and acid gas discharge. Therefore, In this study, an improvement plan was proposed to manage the washing water with pH 3~4 acidic washing water. The test method takes samples from the Wet Scrubber flue measurement laboratory twice a month for 1 year. Hydrogen chloride (HCl) concentration (ppm) was measured, and nozzle clogging and scale conditions were measured, compared, and analyzed through a differential pressure gauge and a pressure gauge. As a result of the check, it was visually confirmed that the scale was reduced to 50% or less in the spray nozzle, filler, and demister. In addition, the emission limit of hydrogen chloride in accordance with the Enforcement Regulation of the Air Quality Conservation Act [Annex 8] met 3 ppm or less. Therefore, even if the washing water is operated in an acidic pH range of 3 to 4, it is expected to reduce air pollution and human damage due to clogging of internal parts, and it is expected to reduce maintenance costs such as regular cleaning or replacement of parts.

A Study on the Possibility of Bulk Graphite Manufacturing using Coal Tar as a Binder and an Impregnant (콜타르를 결합재 및 함침재로 이용한 벌크 흑연 제조)

  • Lee, Sang-Min;Lee, Sang-Hye;Kang, Dong-Su;Roh, Jae-Seung
    • Composites Research
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    • v.34 no.1
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    • pp.51-56
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    • 2021
  • This paper studied the possibility of manufacturing bulk graphite using coal tar, a precursor of coal tar pitch, as a binder and impregnant. Carbonization was conducted after mixing and molding with natural graphite as a filler and coal tar as a binder. Impregnation-recarbonization was performed five times after carbonization. Coal tar used as impregnant. Measuring density, porosity, compressive strength, and anisotropy ratio was conducted. The maximum density of bulk graphite specimen was 1.76 g/㎤ and the minimum porosity was 15.6% which could be controlled by process control. The highest compressive strength was 20.3 MPa. Then the maximum anisotropic ratio of bulk was shown 0.34 through XRD analysis. Therefore, it was confirmed that it was possible to manufacture artificial graphite in a bulk form by using coal tar as a binder and an impregnant.