• Title/Summary/Keyword: Filler material

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Study on lowering the percolation threshold of carbon nanotube-filled conductive polypropylene composites

  • Park, Seung Bin;Lee, Moo Sung;Park, Min
    • Carbon letters
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    • v.15 no.2
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    • pp.117-124
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    • 2014
  • Conductive polymer composites (CPCs) consist of a polymeric matrix and a conductive filler, for example, carbon black, carbon fibers, graphite or carbon nanotubes (CNTs). The critical amount of the electrically conductive filler necessary to build up a continuous conductive network, and accordingly, to make the material conductive; is referred to as the percolation threshold. From technical and economical viewpoints, it is desirable to decrease the conductive-filler percolation-threshold as much as possible. In this study, we investigated the effect of polymer/conductive-filler interactions, as well as the processing and morphological development of low-percolation-threshold (${\Phi}c$) conductive-polymer composites. The aim of the study was to produce conductive composites containing less multi-walled CNTs (MWCNTs) than required for pure polypropylene (PP) through two approaches: one using various mixing methods and the other using immiscible polymer blends. Variants of the conductive PP composite filled with MWCNT was prepared by dry mixing, melt mixing, mechanofusion, and compression molding. The percolation threshold (${\Phi}c$) of the MWCNT-PP composites was most successfully lowered using the mechanofusion process than with any other mixing method (2-5 wt%). The mechanofusion process was found to enhance formation of a percolation network structure, and to ensure a more uniform state of dispersion in the CPCs. The immiscible-polymer blends were prepared by melt mixing (internal mixer) poly(vinylidene fluoride) (PVDF, PP/PVDF, volume ratio 1:1) filled with MWCNT.

Development of Statistical Model and Neural Network Model for Tensile Strength Estimation in Laser Material Processing of Aluminum Alloy (알루미늄 합금의 레이저 가공에서 인장 강도 예측을 위한 회귀 모델 및 신경망 모델의 개발)

  • Park, Young-Whan;Rhee, Se-Hun
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.4 s.193
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    • pp.93-101
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    • 2007
  • Aluminum alloy which is one of the light materials has been tried to apply to light weight vehicle body. In order to do that, welding technology is very important. In case of the aluminum laser welding, the strength of welded part is reduced due to porosity, underfill, and magnesium loss. To overcome these problems, laser welding of aluminum with filler wire was suggested. In this study, experiment about laser welding of AA5182 aluminum alloy with AA5356 filler wire was performed according to process parameters such as laser power, welding speed and wire feed rate. The tensile strength was measured to find the weldability of laser welding with filler wire. The models to estimate tensile strength were suggested using three regression models and one neural network model. For regression models, one was the multiple linear regression model, another was the second order polynomial regression model, and the other was the multiple nonlinear regression model. Neural network model with 2 hidden layers which had 5 and 3 nodes respectively was investigated to find the most suitable model for the system. Estimation performance was evaluated for each model using the average error rate. Among the three regression models, the second order polynomial regression model had the best estimation performance. For all models, neural network model has the best estimation performance.

The Development of Outsole for Wet Traction Enhancement (습윤 접지력 향상을 위한 안전화 겉창 개발 연구)

  • Kim, Jung Soo
    • Journal of the Korean Society of Safety
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    • v.28 no.3
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    • pp.33-38
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    • 2013
  • Many occupational workers or professionals have to walk on the various floors for a long period of time. The objective of this study was to develop the safety shoes with increased traction through the material selection. In order to fulfill our objective, first, two kinds of filler were selected to compare the wear mechanism at outsole surface. The developed rubber materials were tested with two kinds of portable slip meters. The sample safety shoes with developed rubber materials were also tested with subject in the laboratory. During walking, the safety shoes were naturally abraded with counter surface. The coefficient of friction(COF) was gradually decreased with number of steps to 30,000, while the COF was abruptly increased from 30,000 to 40,000. The experimental results showed that COF tested with silica rubber was at least 10% higher than that with carbon black rubber in wet or detergent condition. It has been well recognized that filler properties play a important role in wet traction in the tire industry. However it has been unclear that filler properties would be decisive factor in safety shoes. Our study shows that silica exhibits a higher slip resistance than carbon black without reference to wear states in wet or detergent condition. So, this results will provide guides for outsole compounders to develop new products and improve product performance.

Dispersibility, Electrical Property of Nano-Composite by Solution Mixing Method (용액혼합법에 따른 나노복합재료 분산성 및 전기적 특성)

  • Yang, Hoon;Park, Dae-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.73-74
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    • 2008
  • In this paper, we have investigated dispersibility, volume resistivity of nano-composite by solution mixing method. Dispersibility measured by FE-SEM(Field Emission Scanning Electron Microscope. And volume resistivity measured by ASTM D991. To expect interaction used dual filler system. But, dual filler system had influence on polymer complex. So, polymer chain mobility doesn't resist.

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A study on Effect of humidity on Electric Properties in Epoxy Resin (에폭시 수지의 전기 특성에 미치는 습도의 영향에 관한 연구)

  • 이성일;박일규
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.303-306
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    • 2001
  • Composite insulating materials used in outdoor high voltage equipment are required to have high electric performance because of the miniaturization. The frequence dependence of the permittivity and the loss tangent have important information. In this paper we describe the frequency dependence of the permittivity and the loss tangent for epoxy resin filled with silica and the influence of filler shape on the dielectric properties. The increment of tan $\delta$ in the low frequency region is caused by the increment of both of the electrical conductivity and the polarization due to the shape of filler and water sbsorbed in and near the interface between the fillers and resins. Result of charge current and discharge measure, electric conduction increased according to voltage.

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Filtration Characteristics of Magnetic Fibrous Polymeric Filter Elements for Industrial Lub-systems (산업용 자성폴리머 필터소재의 여과특성 연구)

  • 안병길;최웅수;이용훈;정용진;권오관
    • Tribology and Lubricants
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    • v.12 no.3
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    • pp.39-47
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    • 1996
  • The magnetic fibrous polymeric oil filter elements for industrial lub-systems were obtained by pneumoextrusion processing prepared from thermoplastic pqlymer (polyamide) containing a magnetic particulate filler (Ba ferrite), and treated subsequently in a magnetic fields. Using the standard laboratory oil filtration test rig, metallic particle quantifier and image analyser system, the dependence of filtration charateristics of the magnetic filter media on the parameters of porosity and magnetic properties was investigated. The pressure drops and efficiencies of lubricating filter elements were measured on the packing density and magnetised filler content of filter element. Also, the industrial lub-systems such as lubricant filters for gear test rig and electric discharge processing machine were used for testing the flitrational characteristics of tl, c magnetised filter elements. The magnetic fibrous polymeric filter material was shown to possess a highly filtration efficiency in filtering the fine ferrous particles with increasing the magnetic force of filter element. Therefore, it is expected that the magnetic fibrous polymeric filter material should be used for effective oil filrers on the industrial lub-systems.

Development of a New Sealing Material for PDP

  • Kim, Yu-Jin;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1245-1247
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    • 2005
  • Glass frit was selected to be a $Bi_2O_3-RO-R_2O_3$ system as a sealing material to replace the current PbO system in PDP. Fillers such as a zircon, cordierite and ${\beta}-eucryptite$ were added for the control of thermal expansion coefficient (CTE), flowability and strength for sealing. At $450-500^{\circ}C$, reaction of frit and filler and interface were evaluated by a flow button test and SEM observation. The composite (frit and filler) showed CTE in the range of 70-83 x $10^{-7}/K$ and flowability of 14-20mm. It can be a candidate for the replacement of PbO system.

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Investigation on DC Breakdown Strength Characteristics of Power Cable Insulation (전력 케이블 절연재에 대한 DC절연파괴강도특성 고찰)

  • Lee, Han-Joo;Jung, Eui-Hwan;Joe, Sung-Hoon;Yoon, Jae-Hoon;Lim, Kee-Joe
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.86-86
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    • 2010
  • Recently, CV, CNCV, CNCV-W cable are used to transmit and distribute electric power. And a lot of researchers put more effort to realize high performance. The dielectric breakdown strength characteristic is a standard to design insulators. Examination of that is a main factor to determine long term insulation performance, which is used to diagnose Insulation deterioration. In this paper, we prepared XLPE, XLPE/nano-filler, LDPE/nano-filler for comparing each of the dielectric breakdown strength characteristics.

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A Study on Electrical Degradation Properties of Epoxy Resin due to Moisture Absorption (흡습에 의한 에폭시 수지의 전기적 열화 특성에 관한 연구)

  • Lee, Sung Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.9
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    • pp.656-661
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    • 2013
  • In this study, the moisture content, charge discharge current, electrostatic capacity and dielectric loss tangent are measured for the specimen of bisphenol type epoxy resin which is mixed with squared amorphous silica filler and dipped in hot water of $50^{\circ}C$ for 169 days. The results of this study are listed below. The longer of deposition day, the charge and discharge current was increased. It is considered that the reason is because there was water attack through the squared silica surface. The longer of deposition day, the absorption rate of all specimens was increased. It found that the absorption rate reached saturated state after 100 days. The higher frequency and the longer of deposition day, the $tan{\delta}$ was decreased. Also, It found that the $tan{\delta}$ and electrostatic capacity of the specimen which is mixed with squared filler are greater.

The Change of Electrical Properties on Silicone Rubber Contained ATH under Cyclic Aging(I) (ATH를 첨가한 실리콘고무의 반복열화에 따른 전기적 특성변화(I))

  • Oh, Tae-Seung;Lee, Chung;Kim, Ki-Yup;Park, Soo-Gil;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.258-261
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    • 2001
  • In this paper, aging characteristics of silicone rubber used for outdoor insulation have been investigated with regards to salt fog condition and heat aging effect. We look over the change of properties of silicone rubber in salt fog chamber with average leakage current monitoring for observing the transformation of surface degradation properties of silicone rubber with different ATH(alumina trihydrate, $Al_2O_3{\cdot}3H_2O$) filler contents. Surface resistivity, SEM(Scanning Electro Microscope) were measured.

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