• Title/Summary/Keyword: Fill-Factor

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Characterization of substrates using Fluor-doped Tin Oxide and Gallium-doped Zinc Oxide for Dye Sensitized Solar cells

  • Gong, Jae-Seok;Choe, Yun-Su;Kim, Jong-Yeol;Im, Gi-Hong;Jeon, Min-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.318.2-318.2
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    • 2013
  • 기존의 염료감응형 태양전지(Dye Sensitized Solar Cells; DSSCs)는 최대 효율 11~12%의 광전변환효율을 가지고 있다. 이러한 한계를 극복하기 위해서 광흡수 층 최적화, 상대전극의 촉매성 증대, 전해질의 산화 환원 반응 최적화 등의 많은 연구가 이루어지고 있다. 본 연구에서는 DSSCs의 광전변환효율을 증가시키고자 기존의 투명전극 및 기판으로 사용되는 FTO(Fluor-doped Tin Oxide)를 GZO(Gallium-doped Zinc Oxide)를 사용하여 투명전극기판에 따른 계면 저항, 전류손실 등 DSSCs에 미치는 영향을 분석하였다. 본 연구에 사용된 FTO는 ${\sim}7{\Omega}/{\square}$의 면저항과 80%이상의 투과도를 갖고 있으나 Ion-Sputtering 법으로 증착된 GZO는 열처리 과정을 통하여 $3{\sim}4{\Omega}/{\square}$의 면 저항을 나타내고 80%이상의 우수한 투과도를 가지고 있다. 이러한 두 기판의 특성 비교를 위해, UV-Visble Spectrophotometer를 사용하여 광학적 특성을 분석하고, SEM(Scanning Electron Microscope), AFM(Atomic Force Microscope)를 사용하여 표면 특성을 평가하였다. 또한 전기적 특성을 분석하기 위하여 4-Point-probe를 이용하여 면 저항을 측정하였고, DSSCs의 효율 및 Fill Factor를 분석하기 위하여 Solar Simulator의 I-V measurement를 이용하였다.

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The New Design of Dye-Sensitized Solar Cell Adopted by Sputter Deposition of Counter Electrode (상대전극을 스퍼터링 증착한 염료 감응형 태양전지의 새로운 디자인)

  • Kim, Hee-Je;Song, Keun-Ju;Jeon, Jin-An;Lee, Dong-Yun;Kim, Whi-Young;Choi, Jin-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.154-157
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    • 2006
  • The counter electrode widely used in DSCs (Dye-sensitized Solar Cells) is constructed of conducting glass substrates coated with Pt films, where the platium acts as a catalyst. Pt counter electrodes in DSCs are one important component. It is expected that characteristics of Pt electrodes strongly depend on fabrication process and its surface condition. In this study, Pt counter electrode surface of DSC is deposited by reactive RF magnetron sputtering under the conditions of Ar 5mtorr, RF power of 120w and substrate temperature of $100^{\circ}C$. Surface morphology of Pt electrodes was investigated by FE-SEM and AFM. And this paper shows our recent results and technology to fabricate the new designed cell with Pt electrodes deposited by sputtering method. We have achieved fill factor 65% and photoelectric conversion efficiency around 2.6% as the best results of new designed DSCs structure.

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High-performance photovoltaics by double-charge transporters using graphenic nanosheets and triisopropylsilylethynyl/naphthothiadiazole moieties

  • Agbolaghi, Samira;Aghapour, Sahar;Charoughchi, Somaiyeh;Abbasi, Farhang;Sarvari, Raana
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.293-300
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    • 2018
  • Reduced graphene oxide (rGO) nanosheets were patterned with poly[benzodithiophene-bis(decyltetradecyl-thien) naphthothiadiazole] (PBDT-DTNT) and poly[bis(triiso-propylsilylethynyl) benzodithiophene-bis(decyltetradecyl-thien) naphthobisthiadiazole] (PBDT-TIPS-DTNT-DT) and used in photovoltaics. Conductive patternings changed via surface modification of rGO; because polymers encountered a high hindrance while assembling onto grafted rGO. The best records were detected in indium tin oxide (ITO):poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS):PBDTDTNT/rGO:PBDT-DTNT:LiF:Al devices, i.e., short current density $(J_{sc})=11.18mA/cm^2$, open circuit voltage $(V_{oc})=0.67V$, fill factor (FF) = 62% and power conversion efficiency (PCE) = 4.64%. PCE increased 2.31 folds after incorporation of PBDT-DTNT into thin films. Larger polymer assemblies on bared-rGO nanosheets resulted in greater phase separations.

A Study about the Efficiency of Organic Photovoltaic Device as a function of the Material Concentration (박막의 조성비율에 따른 유기태양전지의 효율성 연구)

  • Kim, Seung-Ju;Lee, Dong-Keun;Park, Jae-Hyung;Gong, Su-Cheol;Kim, Won-Ki;Ryu, Sang-Ouk
    • Journal of the Semiconductor & Display Technology
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    • v.8 no.3
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    • pp.1-5
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    • 2009
  • In this study, we have shown the power conversion efficiency of organic thin film photovoltaic devices utilizing a conjugated polymer/fullerene bulk-hetero junction structure. We use MDMO-PPV(Poly[2-methoxy-5-(3,7-dimethyloctyloxy -1,4-phenylenevinylene) as an electron donor, PCBM([6,6]-Phenyl C61 butyric acid methyl ester) as an electron accepter, and PEDOT:PSS used as a HTL(Hole Transport Layer). We have fabricated OPV(Organic Photovoltaic) devices as a function of the MDMO-PPV/PCBM concentration from 1:1 to 1:5. The electrical characteristics of the fabricated devices were investigated by means of I-V, P-V, F·F(Fill Factor) and PCE(power conversion efficiency). The power conversion efficiency was gradually increased until 1:4 ratio, also the highest efficiency of 0.4996% was obtained at the ratio.

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Polarization-Dependent Microlens Array Using Reactive Mesogen Aligned by Top-Down Nanogrooves for Switchable Three-Dimensional Applications

  • Son, Ki-Beom;Kim, Mugeon;Park, Min-Kyu;Kim, Hak-Rin
    • Journal of the Optical Society of Korea
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    • v.19 no.3
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    • pp.265-271
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    • 2015
  • We propose a reactive mesogen (RM) lens array to obtain good focusing behavior along with a short focal plane, where the focusing behavior is switchable according to the polarization state of incident light. Polarization-dependent focusing behavior is obtained using a planoconvex RM microlens array on a planoconcave isotropic lens template. Even though the sagitta of our RM lens is high, to obtain the short focal length, the RM layer can be aligned well by introducing a top-down alignment effect, using a nanogrooved template. The optical noise due to the $moir{\acute{e}}$ effect generated by the nanogrooves on the surface of the planoconvex RM layer can be removed simply by overcoating a thin RM layer, which is self-aligned by the geometric surface effect, without an additional alignment process. We demonstrate a hexagonal-packed RM lens array that has a very high fill factor and symmetric phase profile, for an ideal lens.

The Effect of eWOM on Purchase Intention for Korean-brand Cars in Russia: The Mediating Role of Brand Image and Perceived Quality

  • Evgeniy, Yu;Lee, Kangmun;Roh, Taewoo
    • Journal of Korea Trade
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    • v.23 no.5
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    • pp.102-117
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    • 2019
  • Purpose - This paper tried to identify the impact of electronic word of mouth (eWOM) on purchase intention (PI) of Korean-brand cars in the context of Russian consumers, taking into consideration the credibility, quality, and quantity of eWOM while also considering the mediation effects of brand image (BI) and perceived quality (PQ). Although there is a considerable number of studies discussing the impact of eWOM determinants on PI, not many studies were conducted focusing on the Russian market. Design/methodology - This paper is considered to fill this gap between eWOM and (PI) and, in order to do so, 211 Russian respondents were randomly selected. Descriptive analysis, factor, and reliability analysis were conducted using SPSS version 22.0. While structural equation modeling was conducted using AMOS version 24.0. Findings - The results display that, in terms of Russian consumers' perception, eWOM credibility, quality, and quantity for Korean-brand cars show a substantial impact on PI. The mediation effects of brand image, as well as perceived quality, were also supported by analysis. In the final part of the paper, theoretical and managerial implications alongside limitations with further research suggestions are presented. Originality/value - This study endeavored to explore the degree of impact of eWOM and mediating roles of BI and PQ on Russian customer intentions to buy Korean-brand cars.

Efficiency Characteristics of DSSC Using TiO2 Paste for Low Temperature Annealing with TTIP (TTIP가 첨가된 저온소성용 TiO2 Paste를 이용한 DSSC의 효율 특성)

  • Kwon, Sung Yeol;Sim, Chang Soo;Yang, Wook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.1
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    • pp.53-57
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    • 2019
  • Recently, the application field of solar panels is increasing. Accordingly, the demand for flexible devices is also steadily increasing. It is therefore necessary to develop $TiO_2$ paste for low-temperature annealing for flexible DSSC fabrication. In this study, the $TiO_2$ paste for low-temperature annealing with varying molar ratio of titanium isopropoxide (TTIP) was prepared, and DSSC was fabricated and its characteristics were compared. As a result, there was no deformation of the particles on the surface in the SEM data. However, the highest open circuit voltage, short circuit current, and fill factor were measured in the DSSC unit cell prepared by adding 0.5 mol of TTIP to the $TiO_2$ paste, and the highest efficiency was 4.148%.

The Effect of PEDOT:PSS Thickness on the Characteristics of Organic-Inorganic Hybrid Solar Cells (PEDOT:PSS의 두께가 유무기 하이브리드 태양전지 성능에 미치는 영향)

  • Kim, Souk Yoon;Han, Joo Won;Oh, Joon-Ho;Kim, Yong Hyun
    • Current Photovoltaic Research
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    • v.7 no.3
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    • pp.61-64
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    • 2019
  • In this study, we investigate organic-inorganic hybrid solar cells with a very simple three-layer structure (Al/n-Si/PEDOT:PSS). The performance of hybrid solar cells is optimized by controlling the sheet resistance and optical transmittance of the PEDOT:PSS layers. As the thickness of the PEDOT:PSS layer decreases, the optical absorption of the n-Si increases, which greatly improves the short-circuit current density ($J_{SC}$) of devices, but the increase in sheet resistance leads to a decrease in the open-circuit voltage ($V_{OC}$) and the fill factor (FF). The solar cell with the 180-nm thick PEDOT:PSS layer shows a highest efficiency of 8.45% ($V_{OC}$: 0.435 V, $J_{SC}$: $33.7mA/cm^2$, FF: 57.5%). Considering these results, it is expected that the optimizing process for the sheet resistance and transmittance of the PEDOT:PSS layer is essential for producing high-efficiency organic-inorganic hybrid solar cells and will serve as an important basis for achieving low-cost, high-efficiency solar cells.

Estimation of spatial parameters to be included in 3D mapping for long-term forest road management

  • Choi, Sung-Min;Kweon, Hyeongkeun;Lee, Joon-Woo
    • Korean Journal of Agricultural Science
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    • v.47 no.4
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    • pp.727-742
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    • 2020
  • Point cloud-based 3D maps can obtain many kinds of information for maintenance work on forest road networks. This study was conducted to compare the importance of each factor to select the factors required for the mapping of 3D forest road maps. This can be used as basic data for attribute information required to maintain forest road networks. The results of this study found that out of a total of 30 indexes extracted for mapping 3D forest roads, a total of 21 indexes related to stakeholder groups were significantly different. The importance of the index required by the civil service group was significantly higher than that of the other groups overall. In the case of the academic group, the index importance for cut slope, fill slope, and drainage facility was significantly higher. On the other hand, the index importance for the forestry cooperative and forest professional engineer group was mostly distributed between the civil servants' group and the academic group. In particular, the type of drainage system showed the highest value among the detailed indexes. Overall, drainage related factors in this survey had high coefficient values. The impact of water on forest roads was the most important part in road maintenance. In addition, the soil texture had a high value in relation to slope stability. This is thought to be because the texture of the soil affects the stability of the slope.

A Study on Correlation Peel Strength and the Efficiency of Shingled Modules According to Curing Condition of Electrically Conductive Adhesives (슁글드 모듈에서 경화조건에 따른 ECA 접합강도와 효율의 상관관계에 관한 연구)

  • Jun, Dayeong;Son, Hyoungin;Moon, Jiyeon;Cho, Seonghyeon;Kim, Sung hyun
    • Current Photovoltaic Research
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    • v.9 no.2
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    • pp.31-35
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    • 2021
  • Shingled module shows high ratio active area per total area due to more efficient packing without inactive space between cells. The module is fabricated by connecting the pre-cut cells into the string using electrically conductive adhesives (ECA). ECAs are used for electric and structural connections to fabricate the shingled modules. In this work, we investigated a correlation between ECA peel strength and the efficiency of pre-cut 5 cells module which are fabricated according to ECA interconnection conditions. The curing conditions are varied to determine whether ECA interconnection properties can affect module properties. As a result of the peel test, the highest peel strength was 1.27 N/mm in the condition of 170℃, the lowest peel strength was 0.89 N/mm in the condition of 130℃. The efficiency was almost constant regardless of the curing conditions at an average of 20%. However, the standard deviation of the fill factor increased as the adhesive strength decreased.