• Title/Summary/Keyword: Field-enhanced

검색결과 1,500건 처리시간 0.029초

Ligand Field Approach to $4d^{1}$ Magnetism Based on Intermediate Field Coupling Scheme

  • 최진호;김종영
    • Bulletin of the Korean Chemical Society
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    • 제18권9호
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    • pp.976-981
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    • 1997
  • The magnetic susceptibilities of molybdenum ions with 4d1 electronic configuration in the octahedral crystal field were calculated on the basis of ligand field theory. The experimental magnetic susceptibilities for molybdenum ions, which are stabilized at the octahedral site in the perovskite lattice of Ba2ScMoⅤO6 and Sr2YMoⅤO6, were compared with the theoretical ones. We have tried to fit their temperature dependence of magnetic susceptibility with ligand field parameters, spin-orbit coupling constant ζSO, and orbital reduction parameter κ according to intermediate field coupling and strong field theory. Strong field coupling theory could not explain experimental curves without unrealistically large axial ligand field, since it ignores the mixing up between different state via spin-orbit interaction and ligand field. On the other hand, the intermediate field coupling theory could successfully reproduce experimental data in octahedral and trigonal ligand field. The fitting result demonstrates not only the fact that spin-orbit interaction is primarily responsible for the variation of magnetic behavior but also the fact that effective orbital overlap, enhanced by cubic crystal structure, reduces significantly orbital angular momentum as indicated by κ parameter.

Patterned free-standing diamond field emitters for iarge area field emission display applications

  • Kim, Sung-Hoon
    • Journal of Korean Vacuum Science & Technology
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    • 제3권1호
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    • pp.10-15
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    • 1999
  • Using micro-wells on the Mo substrate, we could obtain various tubular-volcano-types of free-standing diamond field emitters by depositing a diamond film detaching the film and turning the film upside down. The field emission characteristics of these structures were investigated as a function of size, shape and the number density of the tubular-volcano-type diamond field emitters. The field emission characteristics, especially the current density, were greatly enhanced with increasing the number density of the tubular-volcano-type diamond field emitters on the Mo substrate. Based on these results, we suggest that the reduction of the well size can give better field emission characteristics by the increase in the number density of the tubular-volcano-type diamond field emitters. Finally, we suggest the feasibility of fabricating a large-area field emission display using our patterned tubular-volcano-type free-standing diamond field emitters.

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Design of steel frames by an enhanced moth-flame optimization algorithm

  • Gholizadeh, Saeed;Davoudi, Hamed;Fattahi, Fayegh
    • Steel and Composite Structures
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    • 제24권1호
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    • pp.129-140
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    • 2017
  • Structural optimization is one of the popular and active research areas in the field of structural engineering. In the present study, the newly developed moth-flame optimization (MFO) algorithm and its enhanced version termed as enhanced moth-flame optimization (EMFO) are employed to implement the optimization process of planar and 3D steel frame structures with discrete design variables. The main inspiration of this optimizer is the navigation method of moths in nature called transverse orientation. A number of benchmark steel frame optimization problems are solved by the MFO and EMFO algorithms and the results are compared with those of other meta-heuristics. The obtained numerical results indicate that the proposed EMFO algorithm possesses better computational performance compared with other existing meta-heuristics.

크기가 조절된 성게 모양의 실버나노 입자의 합성과 표면 라만 증강 (Synthesis of Size-Controlled Urchin Ag Nanoparticles and Surfcace Enhanced Raman Spectroscopy (SERS))

  • 이영욱;신태호
    • 한국전기전자재료학회논문지
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    • 제32권6호
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    • pp.454-457
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    • 2019
  • Controlling the shape of Ag nanoparticles (NPs) is very difficult. In the present work, urchin Ag NPs with different sizes and pod length control have been synthesized successfully in high yield by the concentration of a reducing agent. Unique Ag NPs were observed by TEM and SEM. These nanocrystals exhibit tunable surface plasmon resonance properties from the visible to near-infrared regions. They were applied to surface-enhanced Raman scattering (SERS) substrates using rhodamine 6G (R6G), benzenethiol (BT), and 4-amino benznethiol (4-ABT) molecules. The enhanced local field effect due to the sharp pod length, size, and surface plasmon of the urchin Ag NPs resulted in enhanced SERS properties and can serve as high-sensitivity substrates for SERS measurements.

10kW급 HVAC 시스템을 위한 Enhanced Interleaved PFC Boost 컨버터 형태의 650V IPM 개발 (Development of Enhanced Interleaved PFC Boost Converter typed 650V Intelligent Power Module for up to 10kW HVAC Systems)

  • 이기현;홍승현;김태현;정진용;권태성
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2018년도 전력전자학술대회
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    • pp.536-538
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    • 2018
  • This paper introduces an enhanced interleaved (IL) PFC (Power Factor Correction) boost converter typed 650V Intelligent Power Module (IPM), which is fully optimized hybrid IGBT converter modules; Silicon (Si) IGBT and Silicon Carbide (SiC) diode, for up to 10kW HVAC (Heating, Ventilation, and Air Conditioning) systems. It utilizes newly developed $4^{th}$ Generation Field Stop (FS) trench IGBTs, $EXTREMEFAST^{TM}$ anti-paralleled diodes, SiC Junction Barrier Schottky (JBS) diodes, Bridge rectifiers, Multi-function LVIC, and Built-in thermistor provide good reliable characteristics for the entire system. This module also takes technical advantage of DBC (Direct Bonded Copper) substrate for the better thermal performance. It is shown that the Si IGBT/SiC diode hybrid IL PFC module can achieve excellent EMI performance and greatly enhance the power handling capability or switching frequency of various applications compared to the Si IGBT/Diode. This paper provides an overall description of the newly developed 650V/50A Hybrid SiC IL PFC IPM product.

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Effect of Gold Substrates on the Raman Spectra of Graphene

  • Kim, Na-Young;Oh, Min-Kyung;Park, Sung-Ho;Kim, Seong-Kyu;Hong, Byung-Hee
    • Bulletin of the Korean Chemical Society
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    • 제31권4호
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    • pp.999-1003
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    • 2010
  • Raman spectra of a single layer graphene sheet placed in different gold substrates were obtained and are discussed in the context of surface enhanced Raman scattering (SERS). The gold substrates were composed of a combination of a thermally deposited gold film and a close-packed gold nanosphere layer. The SERS effects were negligible when the excitation wavelength was 514 nm, while the Raman signals were enhanced 3-to 50-fold when the excitation wavelength was 633 nm. The large SERS enhancement accompanied a spectral distortion with appearance of several unidentifiable peaks, as well as enhancement of a broadened D peak. These phenomena are interpreted as the local field enhancement in the nanostructure of the gold substrates. The difference in the enhancement factors among the various gold substrates is explained with a model in which the spatial distribution and polarization of the local field and the orientation of the inserted graphene sheet are considered important.

절연유의 유동대전특성에 미치는 직류전계의 영향에 관한 연구 (DC Field Effect on Streaming Electrification in Insulating Oil)

  • 정광현;김용운;김두석;황락훈;임헌찬;박재윤;김종택;이덕출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 D
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    • pp.1436-1437
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    • 1998
  • In this paper, the result of experimental investigation into the streaming electrification phenomena of insulating oil under an external dc field effect is described. Energization by positive dc voltage enhanced the streaming electrification. but when the applied voltage was negative, the polarity of streaming current was field strength dependent.

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항만콘크리트의 내구실험과 현장적용 (Durablity Test and Field Application of Marine Concrete)

  • 강희철;정원기;이규정;박우선
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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    • pp.676-681
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    • 2000
  • This paper covers durability and field application of marine concrete which have been enhanced the resistance against deterioration in seawater. Fly ash concrete is applied to make the concrete with good durability. It is well known fly ash in concrete has a good performance preventing fro a sulphate attack and a steel corrosion. Several durability tests were performed to find characteristics of marine concrete which is proposed in this paper comparing with normal concrete. Field application was executed to compare results with laboratory test and to give a reliability to engineers. The project was supported by Ministry of Marine Affairs and Fisheries for two years.

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자계가 인가된 공기청정장치의 가스 제거 특성 (Gas Removal Characteristics of Air Clean System Applying a Magnetic Field)

  • 신수연;문재덕
    • 전기학회논문지
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    • 제56권5호
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    • pp.921-925
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    • 2007
  • Gas removal characteristics of an air clean system, consisted of a filter and a nonthermal discharge plasma reactor with a magnetic field, have been investigated with emphasis on the enhancing gas removal efficiency of the applied magnetic field. It is found that the magnetic field influenced significantly to the corona discharge characteristics, decreasing the corona onset voltage and increasing the corona current. As a result, the proposed air clean system with the magnetic field showed the higher removal efficiency of the gas (e.g., trimethlyamine) than that of without the magnetic field. This would be because the magnetic field applied to the discharge plasma reactor of the air clean system can elevate the corona characteristics, and activate the generation of ozone, thus the removal efficiency of the gas was concurrently enhanced. This reveals that the proposed air clean system with the magnetic field could be used as an effective means of removal an indoor pollutant gas.