• 천문학회지
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• 제31권2호
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• pp.161-171
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• 1998

We have mapped about 1.5 square degree regions of Lynds 1299, a well isolated dark cloud in the Outer Galaxy (l = $122^{\circ}$, b = $-7^{\circ}$), in the J = 1- 0 transition of $^{12}CO$ and $^{13}CO$ with the 13.7 m radio telescope at Taeduk Radio Astronomy Observatory (TRAO). We found that there are two velocity components in the molecular emission, at $V_{LSR} = -52 km S^{-1}$ (Cloud A) and -8.8 km $s^{-1}$ (Cloud B), respectively. We have derived physical parameters of two molecular clouds and discussed three different mass estimate techniques. We found that there are large discrepancies between the virial and LTE mass estimates for both clouds. The large virial mass estimate reflects the fact that both are not gravitationally bound. We adopt the mass of $5.6 {\times}10^3 \;M{\bigodot}$ for Cloud A and $1.2{\times}10^3 \;M{\bigodot}$) for Cloud B using conversion factor. Cloud A is found to be associated with a localized star forming site, and its morphology is well matching with that of far-infrared (FIR) dust emission. It shows a clear ring structure with an obvious velocity gradient. We suggest that it may be a remnant cloud from a past episode of massive star formation. Cloud B is found to be unrelated to Cloud A (d = 800 pc) and has no specific velocity structure. The average dust color temperature of the uncontaminated portion of Cloud A is estimated to be 24$\~$27.4 K. The low dust temperature may imply that there is no additional internal heating source within the cloud. The heating of the cloud is probably dominated by the interstellar radiation field except the region directly associated with the new-born B5 star. Overall, the dust properties of Cloud A are similar to those of normal dark cloud even though it does have star forming activity.

• 한국재료학회지
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• 제27권7호
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• pp.386-391
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• 2017

Using a customized diffusion bonder, we executed diffusion bonding for ring shaped white gold and red gold samples (inner, outer diameter, and thickness were 15.7, 18.7, and 3.0 mm, respectively) at a temperature of $780^{\circ}C$ and applied pressure of 2300 N in a vacuum of $5{\times}10^{-2}$ torr for 180 seconds. Optical microscopy, field emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDS) were used to investigate the microstructure and compositional changes. The mechanical properties were confirmed by Vickers hardness and shear strength tests. Optical microscopy and FE-SEM confirmed the uniform bonding interface, which was without defects such as micro pores. EDS mapping analysis confirmed that each gold alloy was 14K with the intended composition; Ni and Cu was included as coloring metals in the white and red gold alloys, respectively. The effective diffusion coefficient was estimated based on EDS line scanning. Individual values of Ni and Cu were $5.0{\times}10^{-8}cm^2/s$ and $8.9{\times}10^{-8}cm^2/s$, respectively. These values were as large as those of the melting points due to the accelerated diffusion in this customized diffusion bonder. Vickers hardness results showed that the hardness values of white gold and red gold were 127.83 and 103.04, respectively, due to solid solution strengthening. In addition, the value at the interface indicated no formation of intermetallic compound around the bonding interface. From the shear strength test, the sample was found not to be destroyed at up to 100,000 gf due to the high bonding strength. Therefore, these results confirm the successful diffusion bonding of 14K white-red golds with a diffusion bonder at a low temperature of $780^{\circ}C$ and a short processing time of 180 seconds.

• Bulletin of the Korean Chemical Society
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• 제24권3호
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• pp.269-273
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• 2003

The synthesis and properties of 2,13-bis(3'-pyridylmethyl) $(L^3)$, 2,13-bis(4'-pyridylmethyl) $(L^4)$, and 2,13-bis(phenylmethyl) $(L^5)$ derivatives of 5,16-dimethyl-2,6,13,17-tetraazatrcyclo$[16.4.0.^{1.18}0^{7.12}]$docosane are reported. The 3- or 4-pyridylmethyl groups of $[ML^3](ClO_4)_2\;or\;[ML^4](ClO_4)_2$ (M = Ni(Ⅱ) or Cu(Ⅱ)) are not involved in coordination, and the coordination geometry (square-planar) and ligand field strength of the complexes are quite similar to those of $[ML^5](ClO_4)_2$, bearing two phenylmethyl pendant arms. However, the complex formation reactions of $L^3\;and\;L^4$ are strongly influenced by the pyridyl groups, which can interact with a proton or metal ion outside the macrocyclic ring. The macrocycle $L^5$ exhibits a high copper(Ⅱ) ion selectivity against nickel(Ⅱ) ion; the ligand readily reacts with copper(Ⅱ) ion to form $[CuL^5]^{2+}$ but does not react with hydrated nickel(Ⅱ) ion in methanol solutions. On the other hand, $L^3\;and\;L^4$ form their copper(Ⅱ) and nickel(Ⅱ) complexes under a similar condition, without showing any considerable metal ion selectivity. The ligands $L^3\;and\;L^4$ react with copper(Ⅱ) ion more rapidly than does $L^5$ at pH 6.4. At pH 5.0, however, the reaction rate of the former macrocycles is slower than that of the latter. The effects of the 3- or 4-pyridylmethyl pendant arms on the complex formation reaction of $L^3\;and\;L^4$ are discussed.

• 한국임상수의학회지
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• 제22권3호
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• pp.220-227
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• 2005

Although ketamine has been used in the field of anesthetic medicine for its safety and favourable respiratory effects, the cardiovascular effects of ketamine is still controversial. To clarify the action and mechanism of ketamine upon cardiovascular system, arterial blood pressure, tension of aortic ring, left ventricular developed pressure and heart rate were measured in rats, Ketamine produced two types of effects on arterial blood pressure in anesthetized rats; monophasic effect (blood pressure lowering) and biphasic effect (initial transient blood pressure increasing following sustained lowering), The ketamine-induced lowering of aterial blood pressure showed a concentration-dependent manner, inhibited by the pretreament of $MgCl_2$ and potentiated by the pretreatment of $CaCl_2$. The ketamine-induced lowering of aterial blood pressure was suppressed by the pretreatment of nifedipine, verapamil or lidocaine. In phenylephrine-precontracted endothelium intact (+E) aortic rings, ketamine sometimes caused a small enhancement of contraction ($112.5{\pm}3.6{\%}$). However, in many experiments, ketamine produced a concentration-dependent relaxation in +E aortic rings precontracted with either phenylephrine or KCl. Ketamine-induced relaxation was significantly greater in KCl-precontracted strips than phenylephrine-precontracted strips. In phenylephrine-precontracted +E aortic rings, the ketamine-induced vasorelaxation was not suppressed by endothelium removal or by the pretreatment of a nitric oxide synthase inhibitors, L-$N^G$-nitro-arginine and a guanylate cyclase inhibitors, methylene blue, suggesting that the ketamine-induced vasorelaxation is not dependent on the endothelial function. In addition, ketamine elicited an increase in left ventricular developed pressure in perfused hearts accompanied by decrease in heart rate. These results suggest that ketamine could evoke a hypotension due to vasorelaxation and decrease in heart rate in rats. The inhibitory effect of cardiovascular system might be associated with modulation of $Ca^{2+}$ homeostasis.

• 한국응용곤충학회지
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• 제31권4호
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• pp.536-542
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• 1992

비 이앙직전 carbofuran 토양혼화처리의 본논초기 발생해충 방제효과 및 비래성 해충인 벼멸구에 대한 약효지속효과를 조사하여 다음과 같은 결과를 얻었다. 포장에서 5월 하순 이앙직전 carbofuran 토양혼화처리는 6월 중순 carfuran 수면시용처리나 diazinon (3G) +BPMC (50% EC) 2회처리보다 본논초기 발생해충인 애멸구, 끝동매미충, 이화명나방 1화기에 대한 방제효과가 우수하였다. 폿트에서 carfuran 토양혼화처리의 벼멸구 암컷성충에 대한 직접살충효과는 약처리 1개월후에 50%정도로 떨어졌으나 그의 차세대에 대한 밀도억제효과는 약처리 37일후까지 90%이상, 46일후에도 70%정도를 유지하였다. 따라서 이상의 결과로부터 이앙직전 carfuran 토양혼화처리는 본논초기 발생해충 전반에 대한 효과적인 방제수단이 될 수 있으며 6월중 비래하는 벼멸구에 대해서 90%이상 그리고 7월 초순에 비래하는 벼멸구에 대해서도 어느정도의 밀도 억제효과를 발휘할 수 있을 것으로 생각된다.

• 대한화학회지
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• 제37권1호
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• pp.62-67
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• 1993

Quinoline계 화합물인 미시적 비선형 광학 특성을 설명하기 위해 반경험적인 AMI 방법을 사용하여 초분극률을 계사하였다. Quinoline 고리에서 이차 비선형 특성에 기여하는 전자공여체, 아미노기와 전자수여체, 니트로기의 반응 위치를 변경하여 미시적 비선형 상수에 대한 이론적 영향을 조사해 보았다. 이차와 삼차 비선형 주쇄고분자로서 물리적, 기계적 성질이 우수한 polyquinoline계 고분자를 이용하기 이해 polyquinoline계 반복단위와 유사한 단분자 quinoline들을 설계하여 각각의 미시적 비선형 상수 및 바닥상태의 쌍극자 모멘트 등을 유한 전기장하에서 계산하여 서로 평가 비교해 보았다.

• 천문학회지
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• 제44권4호
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• pp.115-123
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• 2011

To perform imaging observations of optically red objects such as high redshift quasars and brown dwarfs, the Center for the Exploration of the Origin of the Universe (CEOU) recently developed an optical CCD camera, Camera for QUasars in EArly uNiverse (CQUEAN), which is sensitive at 0.7-1.1 ${\mu}m$. To enable observations with long exposures, we develop an auto-guiding system for CQUEAN. This system consists of an off-axis mirror, a baffle, a CCD camera, a motor and a differential decelerator. To increase the number of available guiding stars, we design a rotating mechanism for the off-axis guiding camera. The guiding field can be scanned along the 10 arcmin ring offset from the optical axis of the telescope. Combined with the auto-guiding software of the McDonald Observatory, we confirm that a stable image can be obtained with an exposure time as long as 1200 seconds.

• Bulletin of the Korean Chemical Society
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• 제25권10호
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• pp.1525-1530
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• 2004

Mutagen X (MX) exists in our drinking water as the bi-products of chlorine disinfection. Being one of the most potent mutagen, it attracted much attention from many researchers. MX and its analogs are synthesized and modeled by quantitative structure activity relationship (QSAR) methods. As a result, factors affecting this class of compounds have been found to be steric and electrostatic effects. We tried to collect all the data available from the literature. With both CoMFA and CoMSIA various combinations of physiochemical parameters were systematically studied to produce reasonable 3-dimensional models. The best model for CoMFA gave $q^2$ = 0.90 and $r^2$ = 0.97, while for CoMSIA $q^2$ = 0.85 and $r^2$ = 0.94. So the models seem to be reasonable. Unlike previous result of CoMFA, in our case steric parameter alone gave the best statistics. Although the steric contribution was found to be the most important in both CoMFA and CoMSIA, steric parameter along with electrostatic parameter produced slightly better model in CoMSIA. Overall, steric contribution is clearly the most important single factor. However, when we compare chlorine and bromine substitution, chlorine substitution can be more mutagenic. This indicates that other factors such as electrostatic effect also influence the mutagenicity. From the contour maps, steric contribution seems to be focused on rather small area near C6 substituent of the furanone ring, rather than C3 substituent. Therefore the locality of steric contribution can play a significant role in mutagenicity.

• 대한전자공학회논문지
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• 제27권11호
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• pp.9-19
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• 1990

원통형 및 환형 유전체공진기의 복소유전율과 투자율을 측정하기 위한 이론적인 해석과 측정방법을 제시하였다. 두 개의 평면도체 사이에 유전체공진기를 놓고 공진주파수와 무부하 Q, 그리고 치수를 측정하면 복소유전율과 투자율을 구할 수 있으며 이 방법을 고차모우드에 대하여 반복적으로 행하면 더 넓은 주파수 범위에서 측정이 가능하다. 이 때 각각의 공진모우드는 유전체공진기의 방위각과 축방향에 대한 전계 세기의 변화를 측정함으로써 결정할 수 있다. 그리고 여러가지 오차의 요인들을 고려한 측정오차의 해석으로부터 $TE_{0np}$ 또는 quasi-TE 모우드를 측정에 이용할 경우 복소유전율의 실수부분은 $0.5{\%}$, 허수부분은 $4{\%}$ 이내의 측정오차를 가짐이 밝혀졌다.

• 농약과학회지
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• 제11권3호
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• pp.138-143
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• 2007

감수성(SBC) 및 저항성(RBC) 잿빛곰팡이병균(Botrytis cinerea)에 대한 N-phenyl-O-phenylthionocarbamate 유도체들의 선택적인 살균활성에 대한 3차원적인 구조와 활성과의 관계(3D-QSAR)를 CoMFA와 CoMSIA 방법으로 검토하였다 그 결과, 통계적으로 CoMFA 모델(M5)보다 CoMSIA 모델(M7)이 양호하였으며 살균활성의 선택성에 미치는 요소는 CoMSIA 모델(M7)의 정전기장에 의존적이었다. 그러므로 CoMSIA 모델(M7)의 등고도로부터 N-phenyl 고리의 meta-위치에 음하전을 띄는 수소결합 주게에 의하여 선택성이 개선될 것으로 예상되었다.