• Title/Summary/Keyword: Fibrous material

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Studies of Purifying Waste Cotton for Esterification & Molecular Weight Distribution Curve of Cellulose Acetate (落綿의 精製 및 이를 原料로 하는 醋酸纖維素의 分子量 分配曲線에 關한 硏究)

  • Kim, Dong-Il;Noh, Ick-Sam
    • Journal of the Korean Chemical Society
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    • v.4 no.1
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    • pp.38-43
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    • 1957
  • Purified cellulosic materials suitable for the production of cellulose esters can be prepared from waste cotton (carding waste from textile mill). The most desirable conditions in purifying waste cotton were obtained. Waxy materials were removed by boiling in 2-3% soda ash solution for more than 30 minutes in open vessel at atmospheric pressure. As for bleaching, it is desirable to use the bleaching powder solution containing 1%, available chlorine for 60 minutes at 35 deg. C. Purified cellulosic material was acetylated to fibrous cellulose triacetate, which was fractionated in the solution of 70% monochloroacetic acid using water as a precipitant, and the degree of polymerizaion and molecular weight of each fraction were measured viscometrically, thereon, molecular weight distribution curve was drawn. Analyzing the shape of this curve, most of the polymers were concentrated on the part of higher degree of polymerization. Purified waste cotton was also analysed, the result was that this cellulosic material can be used as a raw material for cellulose esters and ethers.

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THE EFFECTS OF HEAT TREATMENT ON THE MECHANICAL PROPERTIES OF THE ELGILOY WIRE (열처리가 Elgiloy 선재의 기계적 성질에 미치는 영향)

  • Hur, Tack;Rhee, Byung-Tae;Choi, Seok Kyu;Kim, Hyung-Il
    • The korean journal of orthodontics
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    • v.22 no.3 s.38
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    • pp.557-578
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    • 1992
  • Heat treatment which removes internal stress enhances the mechanical properties of the orthodontic arch wire. The main purpose of this experiment was to investigate the effects of the heat treatment on the mechanical properties of the Elgiloy wire. The Elfiloy wire, 0.016' X 0.022' and 0.018' X 0.025', were heat treated in an electric oven for 5, 10 and 15 minutes at selected temperatures between 300 and $900^{\circ}C$. Tensile strength and load deflection rate were measured to reveal the changes of mechanical property at various conditions, and each specimen was observed under metallurgic microscope. Also to trace the precipitation material due to overheat treatment, a qualitative analysis was carried out with EDS system. It was found that heat treatment at a low temperature caused an increase in the tensile strength and bending resistance, and a maintenance in the fibrous in the tensile strength and bending resistance, and a maintenance in the fibrous structure of both sizes of wire. The changes observed in properties and appearance were probably due to the relief of internal stresses incurred in the metal during cold working. In both sizes of wire the tensile strength and the bending resistance continued to decrease at high temperature, and the fibrous structure continued to disappear then was not observed at $900^{\circ}C$. The carbide precipitation founded in grain boundary at $750^{\circ}C$ probably was other elements carbide (Ni, Co) except Cr. The grain growth was observed at $1100^{\circ}C$. Optimum heat treatment for the 0.016' X 0.022' Elgiloy wire was 10 minutes at $500^{\circ}C$, and for the 0.018' X 0.025' Elgiloy wire it was 5 to 15 minutes at $500^{\circ}C$.

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Solitary Fibrous Tumor of the Ischiorectal Fossa : CT and MRI Findings (좌골직장와에서 기원하는 고립섬유종양: CT, MR 영상소견의 증례 보고)

  • Kim, Ki-Hwan;Cha, Sang-Hoon;Yeom, Suk-Keu;Lee, Seung-Hwa;Chung, Hwan-Hoon
    • Investigative Magnetic Resonance Imaging
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    • v.15 no.1
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    • pp.72-76
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    • 2011
  • Solitary fibrous tumor (SFT) is a rare neoplasm, which is usually presented as a pleural based mass, but can also occur in unusual locations based on its mesenchymal origin. However, the radiologic features of SFT occurred in the ischiorectal fossa have been rarely reported. In this case, we describe the MRI findings in a case of a SFT involving the ischiorectal fossa of a 36-year-old man. The tumor appeared as homogeneous iso-signal intensity relative to the adjacent muscle on T1 weighted images, a mixed high signal intensity on the T2 weighted images, and heterogeneous enhancement following the administration of the contrast material.

New constitutive models for non linear analysis of high strength fibrous reinforced concrete slabs

  • Yaseen, Ahmed Asaad;Abdul-Razzak, Ayad A.
    • Structural Engineering and Mechanics
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    • v.82 no.1
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    • pp.121-131
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    • 2022
  • The main goal of this study is to prepare a program for analyzing High Strength Steel Fibrous Reinforced Concrete (HSSFRC) slabs and predict the response and strength of the slab instead of preparing a prototype and testing it in the laboratory. For this purpose, new equations are proposed to represent the material properties of High Strength Steel Fibrous Reinforced Concrete. The proposed equations obtained from performing regression analysis on many experimental results using statistical programs. The finite element method is adopted for non-linear analysis of the slabs. The eight-node "Serendipity element" (3 DoF) is chosen to represent the concrete. The layered approach is adopted for concrete elements and the steel reinforcement is represented by a smeared layer. The compression properties of the concrete are modeled by a work hardening plasticity approach and the yield condition is determined depending on the first two stress invariants. A tensile strength criterion is adopted in order to estimate the cracks propagation. many experimental results for testing slabs are compared with the numerical results of the present study and a good agreement is achieved regarding load-deflection curves and crack pattern. The response of the load deflection curve is slightly stiff at the beginning because the creep effect is not considered in this study and for assuming perfect bond between the steel reinforcement and the concrete, however, a great agreement is achieved between the ultimate load from the present study and experimental results. For the models of the tension stiffening and cracked shear modulus, the value of Bg and Bt (Where Bg and Bt are the curvature factor for the cracked shear modulus and tension stiffening models respectively) equal to 0.005 give good results compared with experimental result.

Some Physical and Chemical Properties of Synthesized Dawsonite (합성 Dawsonite의 물리적, 화학적 성질)

  • Kwon Sang Wook
    • Journal of the Korean Chemical Society
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    • v.13 no.2
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    • pp.149-156
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    • 1969
  • $NaAl(OH)_2CO_3$was synthesized using colloidal earth (Allophane) as the starting material and some of its were studied in detail. It was found that Dawsonite was formed in the pH range (pH 12.5~12.0) that the concentration of $HCO_3^-$ was just begun to increase and the presence of $HCO_3^-$ in the product was clarified from the infrared absorption spectrum. The chemical formular of Dawsonite was therefore presumed as $NaAlO (OH) HCO_3$. From toahhe results of X-ray powder diffraction, both peaks at 5.7 $\AA$ and 2.8 $\AA$ were observed, and fibrous crystalline structure was observed from electron micrograph and also found from the microscopic electron diffraction at 5.7 $\AA.$ Therefore the fibrous axis was considered as =Al=O2=Al=O2=Al=(*image) direction. True specific gravity of Dawsonite was 2.44 and its porosity was 91.4%. It was practically insoluble in water, but decomposed in the boiling water to form Pseudo Boehmite. Stable pH range of Dawsonite was about 4.5~11.5. From the results of D.T.A. and T.G.A., it was observed that $CO_2$was liberated at $350^{\circ}C$, and $H_2O$ at $650^{\circ}C$, and converted into strongly hygroscopic $NaAlO_2$, which was easily decomposed in water into $\beta-Al(OH)_3(Bayerite)$ and NaOH.

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The Quality Evaluation of Korean Traditional Hanji by Different Sheet-making Processes

  • Kim Hyoung Jin;Jo Byoung Muk;Lee Yong Moo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.5 s.108
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    • pp.44-52
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    • 2004
  • It is well known that Korean traditional Hanji have lots of predominant physical and optical properties such as high density, high air permeability, long lasting quality and lightness. The paper-making raw materials of traditional Korean Hanji are the bast fibre cooked from the Korean paper mulberry as a fibrous materials and sticky aqueous material from the root of Hibiscus anihot L. as additives for good dispersion of stock. Additionally, the mechanical properties of Hanji varies according to the cooking methods of bast tissues of Korean paper mulberry, the treatment methods of fibrous raw materials such as bleaching and refining, the wet formation types of sheet-making such as 'Oebal-chiji' and 'Ssangbal-choji', and the finishing treatment like stamping. This study was carried out to investigate and evaluate the quality properties of Korean traditional hand-made Hanji, and compared with commercial machine-made paper and modified prepared sheets. The physical quality comparisons of different kinds of Hanji were focused on the methods of hand-sheet making, the types of raw materials, the treatment of stamping, and the properties of ink reception and spreading.

Filtration Performance of Fibrous Air Filter under External Electric Field using Insulated Electrodes (외부전기장 적용 섬유상 에어필터의 절연 전극 사용에 따른 여과특성)

  • Ji, Sung-Mi;Sohn, Jong-Ryeul;Park, Hyun-Seol
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.6
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    • pp.675-687
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    • 2012
  • Applying an external electric field across air filter media is one of methods to improve the filtration performance. Metal wire meshes have been commonly used as electrodes situated on both sides of a thick filter pad. For a thin filter medium a short circuit, known as the biggest drawback for applying an external electric field to air filter, can occur at the closest point between electrodes. In this study several types of insulated meshes were prepared by coating #50 meshes with a dielectric material, Nylon 66, and the filtration property of air filter was evaluated at the presence of external electric field using those insulated meshes as electrodes and compared with that of filters using bared meshes. The collection efficiency of tested filter was increased from 78% to 95% for singly charged 100 nm particles by application of external electric field. As a result, there was no significant difference in collection efficiency between filters with insulated and bared electrodes. Similar results could be also seen from the tests using polydisperse particles. Finally, through this study, we found that the insulation of mesh electrodes doesn't affect the filtration performance of fibrous air filter under external electric field.

Effect of Ensiling with Acremonium Cellulase, Lactic Acid Bacterial and Formic Acid on Tissue Structure of Timothy and Alfalfa

  • Asian, Aniwaru;Okamoto, M.;Yoshihira, T.;Ataku, K.;Narasaki, N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.10 no.6
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    • pp.593-598
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    • 1997
  • The changes of tissue structure in timothy and alfalfa during ensiling process with silage additives; lactic acid bacteria, cellulase and formic acid, were observed with a video microscope. Stem samples were obtained from the second internode, and cut to divide into 2 pieces. One piece was for observation of ensiled material and the other was for silage. The latter piece was put into a nylon cloth bag, and ensiled with grass for 50 days in a small experimental silo Lignification of the plant tissues was checked by acid phloroglucinol. Natural silage fermentation resulted in some degradation of less lignified parenchyma in both plant species. However, lignified sclerenchyma and vascular bundles remained intact. The cellulase enhanced the degradation of parenchyma tissue, while the formic acid suppressed the degradation. The effect of lactobacillus was small. The percentage of remained cross sectional area of stem and the loss of NDF and ADF by silage fermentation confirmed the observation. High negative correlations were obtained between the remained area and loss of fibrous components during silage fermentation in both plants, and between the loss of fibrous components and in vitro dry matter digestibility in timothy but not in alfalfa.

Fabrication and characterization of aligned crossply PHBV fibrous mat

  • Kim, Yang-Hee;Yang, Hun-Mo;Song, Ho-Yeon;Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.44.1-44.1
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    • 2010
  • poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) is a bacterially derived copolymer produced by fermentation. PHBV has been attractive because of its potential environmental, pharmaceutical and biomedical applications. Recently, the electrospinning technique has been used to fabricate fibrous mat for biomedical applications such as artificial blood vessel, drug release and scaffolds, because this method is simple and easy to get ultrafine polymer fibers. Depending on speed of rotation drum collector, fiber structure was different. In this work, PHBV fiber was aligned by electrospinnning machine. Furthermore, alignment of PHBV fiber mats was given angle such as $45^{\circ}$, $60^{\circ}$ and $90^{\circ}$. The morphology of each aligned PHBV fiber mat was observed by SEM technique. The mechanical property was evaluated depending on alignment angle. Especially, cell attachment ability depending on alignment of PHBV fiber mats was carried out using MG- 63 osteoblast like cells.

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Preparation of Alginate-fibroin Beads with Diverse Structures (다양한 구조를 가진 알긴산-피브로인 비드 제조)

  • Lee, Jin-Sil;Lee, Shin-Young;Hur, Won
    • KSBB Journal
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    • v.26 no.5
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    • pp.422-426
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    • 2011
  • Alginate bead has been supplemented with various polymers to control permeability and to enhance mechanical strength. In this report, fibroin-reinforced alginate hydrogel was prepared, in which spatial localization of fibroin molecules was investigated. Confocal laser scanning microscopy revealed that fibroin molecules formed a fibrous network in the alginate-fibroin beads, which was expected to enhance mechanical strength as same as in many composite materials. Uniaxial compression test showed that fibroin-reinforced alginate beads had increased mechanical strength only after methanol treatment that caused ${\beta}$-sheet formation among fibroin molecules. Simultaneous curing and dialysis of alginate beads were carried out to remove excesscalcium but to retain fibroin in the dialysis chamber, which fabricated beads without internal fibrous fluorescent stains. Fibroin molecules were only found beneath the surface of the beads. The fibroin-diffused shell was further processed to form a thick wall after drying or was mobilizedto the centre of the bead by methanol treatment. Accordingly, the structure analyses provide processing methods of fibroin to form a wall or center clumps, which could be applied to design controlled delivery device.