• Title/Summary/Keyword: Fiber surface engineering

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SALS Study on Transcrystallization and Fiber Orientation in Glass Fiber/Polypropylene Composites

  • Na, Kun;Park, Han-Soo;Won, Hong-Youn;Lee, Jong-Kwan;Lee, Kwang-Hee;Nam, Joo-Young;Jin, Byung-Suk
    • Macromolecular Research
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    • v.14 no.5
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    • pp.499-503
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    • 2006
  • This report presents a new technical approach for evaluating the fiber orientation of composites using small-angle light scattering (SALS). Glass fiber (GF)/polypropylene (PP) composites with different fiber orientations were prepared by drawing compression-molded specimens. The drawn samples were remelted and then annealed at $150^{\circ}C$ in order to induce a crystalline structure on the fiber surface, and then underwent SALS analysis. The samples showed a combination of circular and streak patterns. The model calculations demonstrated that the number of nuclei on the fiber surface and the thickness of the transcrystalline layer affected the sharpness and intensity of the streak pattern. In addition, the azimuthal angle of the streak pattern was found to be dependent on the direction of the transcrystalline layer, which correlated with the fiber direction. This correlation suggests that the fiber orientation in the composites can be easily evaluated using SALS.

Interfacial and Thermal Characteristics of Natural Fiber Composites Reinforced with Henequen Surface-Treated with EBI

  • Pang Yansong;Han Seong Ok;Cho Donghwan;Drzal Lawrence T.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.88-91
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    • 2004
  • In this study, a number of natural fiber henequen reinforced polymer matrix composites were successfully fabricated by means of a compression molding technique using chopped henequen fibers surface-treated with different electron beam irradiation (EBI) dosages, thermoplastic poly(butylene succinate), thermosetting unsaturated polyester and phenolic resins. Their interfacial and thermal characteristics were studied in terms of interfacial shear strength, fracture surface, dynamic mechanical properties, dimensional stability, and thermal stability using single fiber microbonding test, SEM, DMA, TMA, and TGA. The results show that their interfacial and thermal properties significantly depend on the intensity of EBl treatment on the natural fiber surface.

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Development of Optical Fiber Coupled Displacement Probe Sensor with a New Compensation Method (보상법을 적용한 광섬유 변위센서의 개발)

  • ;;;P. Sainsot;L. Flamand
    • Journal of the Korean Society for Precision Engineering
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    • v.19 no.12
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    • pp.27-32
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    • 2002
  • The intensity modulated type (reflective method) optical fiber sensor is a well -known method and widely applied to the displacement measurements and other industrial purposes. This type sensor has the advantages of relatively cheap cost, small sensor size and easiness of operation. The sensitivity of the sensor is very dependent of several error terms; the variation in the intensity of the light source and the changes in the surface reflectivity of the object. An optical fiber coupled displacement probe with a new compensation method is presented in this paper. The proposed displacement sensor can measure the displacements of the target surface independent of surface reflectivity error that is caused by the materials and surface processing grade.

The Effect of Etching on Low-stress Mechanical Properties of Polypropylene Fabrics under Helium/Oxygen Atmospheric Pressure Plasma

  • Hwang, Yoon J.;An, Jae Sang;McCord, Marian G.;Park, Shin Woong;Kang, Bok Choon
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.145-150
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    • 2003
  • Polypropylene nonwoven fabrics were exposed to He/$O_2$ atmospheric pressure glow discharge plasma. Surface chemical analysis and contact angle measurement revealed the surface oxidation by formation of new functional groups after plasma treatment. Weight loss (%) measurement and scanning electron microscopy analysis showed a significant plasma etching effect. It was investigated in low-stress mechanical properties of the fabrics using Kawabata Evaluation System (KES-FB). The surface morphology change by plasma treatment increased surface friction due to an enhancement of fiber-to-fiber friction, resulting in change of other low-stress mechanical properties of fabric.

Effect of Specific Surface Area on the Reaction of Silicon Monoxide with Porous Carbon Fiber Composites

  • Park, Min-Jin;Lee, Jae-Chun
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.245-248
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    • 1998
  • Porous carbon fiber composites (CFCs) having variable specific surface area ranging 35~1150 $\m^2$/g were reacted to produce silicon carbide fiber composites with SiO vapor generated from a mixture of Si and $SiO_2$ at 1673 K for 2 h under vacuum. Part of SiO vapor generated during conversion process condensed on to the converted fiber surface as amorphous silica. Chemical analysis of the converted CFCs resulting from reaction showed that the products contained 27~90% silicon carbide, 7~18% amorphous silica and 3~63% unreacted carbon, and the composition depended on the specific carbide, 7~18% amorphous silica and 3~63% unreacted carbon, and the composition depended on the specific surface area of CFCs. CFC of higher specific surface area yielded higher degree of conversion of carbon to silicon and conversion products of lower mechanical strength due to occurrence of cracks in the converted caron fiber. As the conversion of carbon to silicon carbide proceeded, pore size of converted CFCs increased as a result of growth of silicon carbide crystallites, which is also linked to the crack formation in the converted fiber.

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Bond Properties of CFRP Rebar in Fiber Reinforced High Strength Concrete with Surface Treatment Methods of Reinforcing Fibers (보강섬유의 표면처리에 따른 섬유보강 고강도콘크리트와 CFRP 보강근의 부착특성)

  • Park, Chan-Gi;Won, Jong-Pil;Cha, Sang-Sun
    • Journal of the Korea Concrete Institute
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    • v.21 no.3
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    • pp.275-282
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    • 2009
  • The effects of surface treatment method of reinforcing fiber on the bonding strength between carbon fiber reinforced polymer rebar (CFRP rebar) and high strength concrete have been evaluated in this study. The structural PVA fiber is coated with a proprietary hydrophobicoiling agent and crimped type polyolefin based structural synthetic fiber is deformed with a geometrical modification were used for the reinforcing fiber. The compressive tests have been performed to evaluate the strength property of high strength concrete depending on the surface treatment method of fiber. The bonding property between the high strength concrete and the CFRP rebar was evaluated by means of direct bonding test. The test results indicated that the surface treatment method of fiber effect on the bonding behavior of high strength concrete and CFRP rebar. Also, as the development and propagation of splitting cracks were controled by adding fibers into the high strength concrete, the bonding behavior, bond strength and relative bonding strength of CFRP rebar and high strength concrete were significantly improved.

Surface Functionalization of Carbon Fiber for High-Performance Fibrous Supercapacitor (고성능 섬유형 슈퍼커패시터를 위한 탄소섬유의 표면 기능화)

  • Lee, Young-Geun;An, Geon-Hyoung
    • Korean Journal of Materials Research
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    • v.32 no.2
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    • pp.107-113
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    • 2022
  • Fibrous supercapacitors (FSs), owing to their high power density, good safety characteristic, and high flexibility, have recently been in the spotlight as energy storage devices for wearable electronics. However, despite these advantages, FCs face many challenges related to their active material of carbon fiber (CF). CF has low surface area and poor wettability between electrode and electrolyte, which result in low capacitance and poor long-term stability at high current densities. To overcome these limits, fibrous supercapacitors made using surface-activated CF (FS-SACF) are here suggested; these materials have improved specific surface area and better wettability, obtained by introducing porous structure and oxygen-containing functional groups on the CF surface, respectively, through surface engineering. The FS-SACF shows an improved ion diffusion coefficient and better electrochemical performance, including high specific capacity of 223.6 mF cm-2 at current density of 10 ㎂ cm-2, high-rate performance of 171.2 mF cm-2 at current density of 50.0 ㎂ cm-2, and remarkable, ultrafast cycling stability (96.2 % after 1,000 cycles at current density of 250.0 ㎂ cm-2). The excellent electrochemical performance is definitely due to the effects of surface functionalization on CF, leading to improved specific surface area and superior ion diffusion capability.

Surface Treatment of Carbon Fiber by Hydrogen Sulfide (탄소섬유 표면의 H2S 처리에 관한 연구)

  • Shin, Kyoung-Han;Han, Jeong-Ryeon
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.176-181
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    • 1990
  • For the purpose of the improvement of interfacial shear strength in carbon fiber/aluminum matrix composite material, polyacrylonitrile-based carbon fibers were surface treated by hydrogen sulfide gas continuously between 400 and $600^{\circ}C$. Surface treated carbon fibers were analysed by scanning electron microscope. The existence of sulfur compound on treated carbon fiber surfaces was confirmed, and carbon and oxygen contents of the fiber surfaces were examined by X-ray photoelectron spectroscopy. Optimum treating temperature for the adsorption of sulfur on the carbon fiber surface was $500^{\circ}C$. Sulfur compounds on the carbon fiber surfaces form the structures of disulfide, $(S)_n$ and thiophene. The decrease in the tensile strength of the carbon fibers was observed less than about 5%.

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Experimental analysis and modeling of steel fiber reinforced SCC using central composite design

  • Kandasamy, S.;Akila, P.
    • Computers and Concrete
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    • v.15 no.2
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    • pp.215-229
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    • 2015
  • The emerging technology of self compacting concrete, fiber reinforcement together reduces vibration and substitute conventional reinforcement which help in improving the economic efficiency of the construction. The objective of this work is to find the regression model to determine the response surface of mix proportioning Steel Fiber Reinforced Self Compacting Concrete (SFSCC) using statistical investigation. A total of 30 mixtures were designed and analyzed based on Design of Experiment (DOE). The fresh properties of SCC and mechanical properties of concrete were studied using Response Surface Methodology (RSM). The results were analyzed by limited proportion of fly ash, fiber, volume combination ratio of two steel fibers with aspect ratio of 50/35: 60/30 and super plasticizer (SP) dosage. The center composite designs (CCD) have selected to produce the response in quadratic equation. The model responses included in the primary stage were flowing ability, filling ability, passing ability and segregation index whereas in harden stage of concrete, compressive strength, split tensile strength and flexural strength at 28 days were tested. In this paper, the regression model and the response surface plots have been discussed, and optimal results were found for all the responses.