Journal of Korean Society of Occupational and Environmental Hygiene
/
v.23
no.3
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pp.184-195
/
2013
Objectives: The purpose of this study is to provide information in reference to the health hazards of asbestos substitutes. Methods: This study was conducted by reviewing the literature on the types of asbestos substitutes, product development using alternative materials and the health effects associated with asbestos substitutes. Results: Synthetic or natural fibers such as synthetic vitreous fiber, polyamide, attapulgite, sepiolite and wollastonite are known as asbestos substitutes. According to the patents data of the United States and Europe since the 1970s, many asbestos-free products have been developed in a variety of industries. Health hazards of some asbestos substitutes including synthetic vitreous fibers have been evaluated by many experts, however, additional researches are required to be carried out in the future. Conclusions: Alternatives to asbestos are necessary to develop the asbestos-free products. Health hazards for only several asbestos substitutes have been assessed so far and occupational exposure limit has not been established for many asbestos substitutes yet. Therefore, even though workers are handling asbestos-free products, it is recommended to control the working environment well enough in order to minimize the exposure of workers to dusts or fibers caused during the working process.
Over the past couple decades, externally bonded fiber reinforced polymer (FRP) composites have emerged as a repair and strengthening material for many concrete infrastructure applications. This paper presents an analytical investigation of the use of carbon FRP (CFRP) for a specific problem that occurs in concrete bridge girders wherein the girder ends are damaged by excessive exposure to deicing salts and numerous freezing/thawing cycles. A 3D finite element (FE) model of a full scale prestressed concrete (PC) I-girder is used to investigate the effect of damage to the cover concrete and stirrups in the end region of the girder. Parametric studies are performed using externally bonded CFRP shear laminates to determine the most effective repair schemes for the damaged end region under a short shear span-to-depth ratio. Experimental results on shear pull off tests of CFRP laminates that have undergone accelerated aging are used to calibrate a bond stress-slip model for the interface between the FRP and concrete substrate and approximate the reduced bond stress-slip properties associated with exposure to the environment that causes this type of end region damage. The results of these analyses indicate that this particular application of this material can be effective in recovering the original strength of PC bridge girders with damaged end regions, even after environmental aging.
Transactions of the Korean Society of Mechanical Engineers A
/
v.26
no.7
/
pp.1416-1425
/
2002
In this study, the effects of combined environmental factors on mechanical and thermal analysis properties of graphite/epoxy composites were evaluated by the use of an accelerated aging test. Environmental factors such as temperature, moisture. and ultraviolet were considered. A xenon-arc lamp was utilized for ultraviolet light. and exposure times of up to 3000 hours were applied. Several types of specimens - tensile. bending, and shear specimens those are transverse to the fiber direction, and bending specimens those are parallel to the tiber direction - were used to investigate the effects of environmental factors on mechanical properties of the composites. Also, glass transition temperature, storage shear modulus, loss shear modulus, and tan ${\delta}$ were measured as a function of exposure times through a dynamic mechanical analyzer. In addition. a suitable testing method for determining the effect of environmental factors on mechanical properties is suggested by comparing the results from using two different types of strain measuring sensors. Finally, composite surfaces exposed to environmental factors were examined using a scanning electron microscope.
Journal of The Korean Society of Grassland and Forage Science
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v.7
no.2
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pp.97-102
/
1987
To find out the nutrient contents of temperate grasses on the south and north slope, a field experiment was conducted with five forage species of Dactylis glomerata, Festuca arundinacea, Phleum pratense, Agrostis gigantea and Trifolium repens. It was treated by randomized block design with 4 replications and lasted from September, 1983 to October, 1986 in Suweon. The results obtained are summarized as follows: 1. Mean chemical compositions except NFE and crude fiber of the forage species on the south slope were a little more contented than that of north. But all crude components were significant difference among the species on the south and north exposure. 2. Production of TDN (total digestible nutrient), StE (starch equivalent) ME (metabolizable energy) and NEL (net energy lactation) of different grass species on the north slope were much more increased by 5-30% per ha (Dactylis glomerata by 5-876, Festuca arundinacea by 5%, Phleum pratense by 24-26% and Agrostis gigantea by 25-30%) than that of same grasses on the south, however, those of Trifolium repens were much more increased by 4 1-42% per ha in the south. 3. Mineral contents, Ca/P ratio and K/ (Ca + Mg) equivalent ratio of the species were slightly different between the exposures. But considering the factors of occuring grass tetany, those of the forage species on the north slope were better than that of same species on the south.
To prevent the explosive spalling of the high strength concrete and control the rise of temperature in the steel rebar during fire, a fiber cocktail method has been proposed simultaneously with the use of polypropylene and steel fiber. After applying the fiber cocktail (polypropylene and steel fibers) into the mixture of high strength concrete with a compressive strength of between 40 and 100 MPa and evaluating the thermal properties at elevated temperatures, the fire test was carried out on structural members in order to evaluate the fire resistance performance. Two column specimens were exposed to the fire without loading for 180 minutes based on the standard curve of ISO-834. No explosive spalling has been observed and the original color of specimen surface was changed to light pinkish grey. The inner temperature of concrete dropped rapidly starting from 60mm deep. After 60 minutes of exposure to the fire, the temperature gradient of fiber cocktail reinforced high strength concrete was measured as 2.2oC/mm, which is approximately 5 times less than that of normal concrete. The final temperatures of steel rebar after 180 minutes of fire test resulted in 488.0oC for corner rebar, 350.9oC for center rebar, and 419.5oC for total mean of steel rebar. The difference of mean temperature between corner and center rebar was 137.1oC The tendency of temperature rise in concrete and steel rebar changed between 100oC and 150oC The cause of decrease in temperature rise was due to the water vaporization in concrete, the lower temperature gradient of the concrete with steel and polypropylene fiber cocktails, the moisture movement toward steel rebars and the moisture clogging.
Dimas Hand Vidya Paradhipta;Myeong Ji Seo;Seung Min Jeong;Young Ho Joo;Seong Shin Lee;Pil Nam Seong;Hyuk Jun Lee;Sam Churl Kim
Animal Bioscience
/
v.36
no.5
/
pp.720-730
/
2023
Objective: This study investigated the effects of corn silage as a source of microbial inoculant containing antifungal and carboxylesterase-producing bacteria on fermentation, aerobic stability, and nutrient digestibility of fermented total mixed ration (FTMR) with different energy levels. Methods: Corn silage was used as a bacterial source by ensiling for 72 d with an inoculant mixture of Lactobacillus brevis 5M2 and L. buchneri 6M1 at a 1:1 ratio. The corn silage without or with inoculant (CON vs MIX) was mixed with the other ingredients to formulate for low and high energy diets (LOW vs HIGH) for Hanwoo steers. All diets were ensiled into 20 L mini silo (5 kg) for 40 d in quadruplicate. Results: The MIX diets had lower (p<0.05) acid detergent fiber with higher (p<0.05) in vitro digestibilities of dry matter and neutral detergent fiber compared to the CON diets. In terms of fermentation characteristics, the MIX diets had higher (p<0.05) acetate than the CON diets. The MIX diets had extended (p<0.05) lactic acid bacteria growth at 4 to 7 d of aerobic exposure and showed lower (p<0.05) yeast growth at 7 d of aerobic exposure than the CON diets. In terms of rumen fermentation, the MIX diets had higher (p<0.05) total fermentable fraction and total volatile fatty acid, with lower (p<0.05) pH than those of CON diets. The interaction (p = 0.036) between inoculant and diet level was only found in the immediately fermentable fraction, which inoculant was only effective on LOW diets. Conclusion: Application of corn silage with inoculant on FTMR presented an antifungal effect by inhibiting yeast at aerobic exposure and a carboxylesterase effect by improving nutrient digestibility. It also indicated that fermented feedstuffs could be used as microbial source for FTMR. Generally, the interaction between inoculant and diet level had less effect on this FTMR study.
Cho, ll Kyu;Kim, Su Jin;Kim, Ji Myung;Oh, Young Goun;Seol, Jae Ung;Lee, Ji Ho;Kim, Jeong Han
Korean Journal of Environmental Agriculture
/
v.37
no.4
/
pp.302-311
/
2018
BACKGROUND: Dithianon (75%) formulation were mixed and sprayed as closely as possible by normal practice on the ten farms located in the Mungeong of South Korea. Patches, cotton gloves, socks, masks, and XAD-2 resin were used for measurement of the potential exposure of dithianon on the applicators wearing standardized whole-body outer and inner dosimeter (WBD). This study has been carried out to determine the dermal and inhalation exposure to dithianon during preparation of spray suspension and application with a power sprayer on a apple orchard. METHODS AND RESULTS: A personal air monitor equipped with an air pump, IOM sampler and cassette, and glass fiber filter was used for inhalation exposure. The field studies were carried out in a apple orchard. The temperature and relative humidity were monitored with a thermometer and a hygrometer. Wind speed was measured using a pocket weather meter. All mean field fortification recoveries were between 85.1% and 99.1% in the level of 100 LOQ (limit of quantification), while the LOQ for dithianon was $0.05{\mu}g/mL$ using HPLC-DAD. The exposure to dithianon on arms of the mixer/loader (0.0794 mg) was higher than other body parts (head, hands, upper body, or legs). The exposure to dithianon on the applicator's legs (3.78 mg) was highest in the body parts. The dermal exposures for mixer/loader and applicator were 10 and 8.10 mg, respectively, from a grape orchard. The inhalation exposure during application was estimated as 0.151 mg, and the ratio of inhalation exposure was 11.2% of the dermal exposure (inner clothes). CONCLUSION: The dermal and inhalation exposure on the applicator appeared to be 4.203 mg - 25.064 mg and $0.529{\mu}g-116.241{\mu}g$, respectively. The total exposures on the agricultural applicators were at the level of 2.596 mg - 25.069 mg to dithianon during treatment for apple orchard. The TER showed 3.421 (>1) when AOEL of dithianon was used as a reference dose for the purpose of risk assessment of the mixing/loading and application.
Journal of Korean Tunnelling and Underground Space Association
/
v.25
no.4
/
pp.261-283
/
2023
This study aimed to review the performance stability of PET (Polyethylene terephthalate) fiber reinforcing materials among the synthetic fiber types for which the application of performance reinforcing materials to fiber-reinforced concrete is being reviewed by examining short-term and long-term performance changes. To this end, the residual performance was analyzed after exposing the PET fiber to an acid/alkali environment, and the flexural strength and equivalent flexural strength of the PET fiber-reinforced concrete mixture by age were analyzed, and the surface of the PET fiber collected from the concrete specimen was examined using a scanning microscope (SEM). The changes in were analyzed. As a result of the acid/alkali environment exposure test of PET fiber, the strength retention rate was 83.4~96.4% in acidic environment and 42.4~97.9% in alkaline environment. It was confirmed that the strength retention rate of the fiber itself significantly decreased when exposed to high-temperature strong alkali conditions, and the strength retention rate increased in the finished yarn coated with epoxy. In the test results of the flexural strength and equivalent flexural strength of the PET fiber-reinforced concrete mixture, no reduction in flexural strength was found, and the equivalent flexural strength result also did not show any degradation in performance as a fiber reinforcement. Even in the SEM analysis results, no surface damage or cross-sectional change of the PET reinforcing fibers was observed. These results mean that no damage or cross-section reduction of PET reinforcing fibers occurs in cement concrete environments even when fiber-reinforced concrete is exposed to high temperatures in the early stage or depending on age, and the strength of PET fibers decreases in cement concrete environments. The impact is judged to be of no concern. As the flexural strength and equivalent flexural strength according to age were also stably expressed, it could be seen that performance degradation due to hydrolysis, which is a concern due to the use of PET fiber reinforcing materials, did not occur, and it was confirmed that stable residual strength retention characteristics were exhibited.
Kim, Taeyoung;Lee, Songmin;Heo, Yongdae;Kim, Jinyoung;Joung, Yangjin
Journal of Korea Technical Association of The Pulp and Paper Industry
/
v.47
no.5
/
pp.23-32
/
2015
In this study, chemical and physical changes of dissolving pulps which have similar viscosity by dry milling and fractionation were investigated. We used two types of dissolving pulp made from wood and cotton linter fiber, respectively. Dry milling was executed by knife cutter and pulp powders were fractionated by sieve shaker into 4 grades. We analyzed fiber properties, crystallinity index, viscosity, molecular weight of pulp sheet and powders. It was found that poly-dispersity index of cotton linter pulp was smaller than that of wood pulp, meaning that cotton pulp has more narrow molecular weight distribution. It was assumed that these were related to exposure times to chemical treatment which cut cellulose chains not evenly. At least 4 times of chemical treatments for wood pulp were executed and only two times of chemical treatments for cotton linter pulp were done. After dry milling average molecular weight and crystallinity index of cotton linter pulp powders were reduced and these were related to fines content and shape of pulp powders.
In this study, an experimental study is performed to understand the effect of spalling on the structural behavior of fire damaged steel reinforced high strength concrete (SRHSC) columns, and the test results of temperature distributions and the displacements at elevated temperature are analyzed. Toward this goal, three long columns are tested to investigate the effect of various test parameters on structural behavior during the fire, and twelve short columns are tested to investigate residual strength and stiffness after the fire. The test parameters are mixture ratios of polypropylene fiber (0 and 0.1 vol.%), magnitudes of applied loads (concentric loads and eccentric loads), and the time period of exposure to fire (0, 30, 60 and 90 minutes). The experimental results show that there is significant effect of loading on the structural behaviors of columns under fire. The loaded concrete columns result more explosive spalling than the unloaded columns under fire. In particular, eccentrically loaded columns are severely spalled. The temperature distributions of the concrete are not affected by the loading state if there is no spalling. However, the loading state affects the temperature distributions when there is spalling occurred. In addition, it is found that polypropylene fiber prevents spalling of both loaded and unloaded columns under fire. From these experimental findings, an equation of predicting residual load capacity of the fire damaged column is proposed.
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