• Title/Summary/Keyword: Fiber Aspect Ratio

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Characterization of Electrospun Nanofibers of Cellulose Nanowhisker/Polyvinyl Alcohol Composites

  • Cho, Mi-Jung;Park, Byung-Dae;Kadla, John F.
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.2
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    • pp.71-77
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    • 2012
  • Cellulose nanowhisker (CNW) isolated from hardwood bleached kraft pulp (HW-BKP) using sulfuric acid hydrolysis was suspended in polyvinyl alcohol (PVA) and electrospun into composites nanofibers. Transmission electron microscopy (TEM) revealed the CNW to be rod-like, approximately of $16.1{\pm}4.6$ nm wide and $194{\pm}61$ nm long, providing an aspect ratio of about 12, with a particle size distribution range of $662.2{\pm}301.2$ nm. Uniform and high quality CNW/PVA composite nanofibers were successfully manufactured by the electrospinning method. As the CNW loading increases, the viscosity of CNW/PVA solutions shows a minimum at 1% CNW level which subsequently results in the smallest diameter (193 nm) of electrospun nanofibers. The average diameter of the nanofibers increased up to 284 nm with increasing CNW loading. These results suggest that the electrospinning method provides a great potential of manufacturing consistent and reliable nanofibers from CNW/PVA solution for the formation of scaffolds with potentials in future application.

Vibration analysis of functionally graded nanocomposite plate moving in two directions

  • Arani, Ali Ghorbanpour;Haghparast, Elham;Zarei, Hassan BabaAkbar
    • Steel and Composite Structures
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    • v.23 no.5
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    • pp.529-541
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    • 2017
  • In the present study, vibration analysis of functionally graded carbon nanotube reinforced composite (FGCNTRC) plate moving in two directions is investigated. Various types of shear deformation theories are utilized to obtain more accurate and simplest theory. Single-walled carbon nanotubes (SWCNTs) are selected as a reinforcement of composite face sheets inside Poly methyl methacrylate (PMMA) matrix. Moreover, different kinds of distributions of CNTs are considered. Based on extended rule of mixture, the structural properties of composite face sheets are considered. Motion equations are obtained by Hamilton's principle and solved analytically. Influences of various parameters such as moving speed in x and y directions, volume fraction and distribution of CNTs, orthotropic viscoelastic surrounding medium, thickness and aspect ratio of composite plate on the vibration characteristics of moving system are discussed in details. The results indicated that thenatural frequency or stability of FGCNTRC plate is strongly dependent on axially moving speed. Moreover, a better configuration of the nanotube embedded in plate can be used to increase the critical speed, as a result, the stability is improved. The results of this investigation can be used in design and manufacturing of marine vessels and aircrafts.

Influence of Organomodified Nanoclay on the Mechanical and Flammability behavior of Jute Fabric/Vinyl Ester Nanocomposites

  • Latif, M.;Prabhakar, M.N.;Nam, Gi-Beop;Lee, Dong-Woo;Song, Jung-Il
    • Composites Research
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    • v.30 no.5
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    • pp.303-309
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    • 2017
  • Organo-montmorillonite (OMMT) has attracted much attention for fiber-reinforced polymer composites as a filler material due to high aspect ratio and low charge density. The present study focused on the fabrication of nanocomposites using Vinyl ester and Jute fabric as matrix and reinforcement respectively. The OMMT was uniformly dispersed in vinyl ester resin at 1, 2 and 3 wt%, loading through high speed mechanical stirrer at room temperature and further nanocomposites were manufactured through vacuum assisted resin infusion (VARI) technique. Effects of OMMT on the mechanical properties of vinyl ester/Jute composites were carefully investigated through tensile, bending and Izod impact tests, which revealed significant improvement in mechanical properties. The morphology of the nanocomposites after tensile test was investigated by SEM which affirmed that OMMT filled nanocomposites has improved interactions with the host matrix than the pure composites. Based on the nature and flame retardancy mechanism, the OMMT slightly improved the flammability property which was clearly explained by horizontal burning test.

Stability of Cantilevered Laminated Composite Structures with Open Channel Section by Geometrical Shape Variations (채널단면의 기하학적 형상변화에 따른 캔틸레버 적층구조물의 안정성 연구)

  • Park, Won-Tae;Chun, Kyoung-Sik;Son, Byung-Jik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.2
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    • pp.169-175
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    • 2004
  • In this paper, the stability of cantilever composite laminated structures with open channel section is studied. This paper deals with the buckling behavior under the variation of the geometrical shape (length ratio, crank angle in the open channel section), the fiber reinforced angle, and so on in order to offer a effective and reliable design data. Also, sensitive analyses are carried out on the stability by the interaction of design factors. Based on this fact, the proper channel section and lamination scheme of composite material cantilever structures are considered in the engineering aspect.

A Fundamental Study on Effective Width Evaluation of Laminated Composite Box Girder (복합적층 박스거더의 유효폭 산정을 위한 기초연구)

  • Chun, Kyoung-Sik;Ji, Hyo-Seon;Park, Won-Tae
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.3
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    • pp.26-31
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    • 2015
  • The domestic and foreign specifications presented the effective width based on flange length to width ratio only. The existing paper on the effective width grasped of the effect of span, load type and cross-section properties, but localized steel bridges. Recently, The studies are going on in progress for the application of fiber reinforced composite material in construction field. Therefore, it is required to optimum design that have a good grasp the deformation characteristic of the displacements and stresses distribution and predict variation of the effective width for serviceability loading. This research addresses the effective width of all composite material box girder bridges using the finite element method. The characteristics of the effective width of composite structures may vary according to several causes, e.g., change of fibers, aspect, etc. Parametric studies were conducted to determine the effective width on the stress elastic analysis of all composite materials box bridges, with interesting observations. The various results through numerical analysis will present an important document for construct all composite material bridges.

Characterization of Carboxylated Cellulose Nanocrystals from Recycled Fiberboard Fibers Using Ammonium Persulfate Oxidation

  • KHANJANZADEH, Hossein;PARK, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.2
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    • pp.231-244
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    • 2020
  • As a way of finding value-added materials from waste medium density fiberboard (MDF), this study characterized cellulose nanocrystals (CNCs) isolated by ammonium persulfate (APS) oxidation using recycled MDF fibers. Chemical composition of the recycled MDF fibers was done to quantify α-cellulose, hemicellulose, lignin, nitrogen, ash and extractives. The APS oxidation was performed at 60 ℃ for 16 h, followed by ultrasonication, which resulted in a CNC yield of 11%. Transmission electron microscope images showed that rod-like CNCs had an average length and diameter of 167±47 nm and 8.24±2.28 nm, respectively, which gave an aspect ratio of about 20. The conductometric titration of aqueous CNCs suspension resulted in a carboxyl content of 0.24 mmol/g and the degree of oxidation was 0.04. Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy clearly showed the presence of carboxyl group on the CNCs prepared by the APS oxidation. The change of pH of the aqueous CNC suspension from 4 to 7 converted the carboxyl group to sodium carboxylate group. These results showed that the APS oxidation was facile and CNCs had a one-step preparation method, and thus suggested an optimization of the oxidation condition in future.

A hybrid DQ-TLBO technique for maximizing first frequency of laminated composite skew plates

  • Vosoughi, Ali R.;Malekzadeh, Parviz;Topal, Umut;Dede, Tayfun
    • Steel and Composite Structures
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    • v.28 no.4
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    • pp.509-516
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    • 2018
  • The differential quadrature (DQ) and teaching-learning based optimization (TLBO) methods are coupled to introduce a hybrid numerical method for maximizing fundamental natural frequency of laminated composite skew plates. The fiber(s) orientations are selected as design variable(s). The first-order shear deformation theory (FSDT) is used to obtain the governing equations of the plate. The equations of motion and the related boundary conditions are discretized in space domain by employing the DQ method. The discretized equations are transferred from the time domain into the frequency domain to obtain the fundamental natural frequency. Then, the DQ solution is coupled with the TLBO method to find the maximum frequency of the plate and its related optimum stacking sequences of the laminate. Convergence and applicability of the proposed method are shown and the optimum fundamental frequency parameter of the plates with different skew angle, boundary conditions, number of layers and aspect ratio are obtained. The obtained results can be used as a benchmark for further studies.

Viable Alternatives to in vivo Tests for Evaluating the Toxicity of Engineered Carbon Nanotubes

  • Kwon, Soon-Jo;Eo, Soo-Mi
    • Journal of Environmental Health Sciences
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    • v.38 no.1
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    • pp.1-7
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    • 2012
  • Carbon nanotubes (CNTs) stand at the frontier of nanotechnology and are destined to stimulate the next industrial revolution. Rapid increase in their production and use in the technology industry have led to concerns over the effects of CNT on human health and the environment. The prominent use of CNTs in biomedical applications also increases the possibility of human exposure, while properties such as their high aspect ratio (fiber-like shape) and large surface area raise safety concerns for human health if exposure does occur. It is crucial to develop viable alternatives to in vivo tests in order to evaluate the toxicity of engineered CNTs and develop validated experimental models capable of identifying CNTs' toxic effects and predicting their level of toxicity in the human respiratory system. Human lung epithelial cells serve as a barrier at the interface between the surrounding air and lung tissues in response to exogenous particles such as air-pollutants, including CNTs. Monolayer culture of the key individual cell types has provided abundant fundamental information on the response of these cells to external perturbations. However, such systems are limited by the absence of cell-cell interactions and their dynamic nature, which are both present in vivo. In this review, we suggested two viable alternatives to in vivo tests to evaluate the health risk of human exposure to CNTs.

Structural Performance of Flexural Dominant Reinforced Concrete Beams strengthened in Beam-Column Joint with SHCC (변형경화형 시멘트 복합체(SHCC)로 보-기둥 접합부 단면이 증설된 휨항복형 철근콘크리트 보의 구조성능)

  • Song, Seon-Hwa;Jang, Gwang-Soo;Kim, Yun-Su;Kim, Sun-Woo;Kim, Yong-Cheol;Yun, Hyun-Do
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.53-56
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    • 2008
  • Reinforced concrete rahmen structures has been required ductility as well as strength of beam-column joint in seismically hazard area. Some investigations have been presented for retrofitting and/or strengthening structural elements in structure. Strain-hardening cementitious composite(SHCC) has been expected excellent reinforcement performance in beam-column joint area. The properties of reinforcing fiber, as tensile strength, aspect ratio and elastic moudulus, have great effect on the fracture behavior of SHCC. The purpose of this experimental study is to evaluate structural performance of exterior reinforced concrete beam-column joint strengthened with SHCC under cyclic loading.

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Analysis of a functionally graded nanocomposite sandwich beam considering porosity distribution on variable elastic foundation using DQM: Buckling and vibration behaviors

  • Nejadi, Mohammad Mehdi;Mohammadimehr, Mehdi
    • Computers and Concrete
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    • v.25 no.3
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    • pp.215-224
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    • 2020
  • In the present study, according to the important of porosity in low specific weight in comparison of high stiffness of carbon nanotubes reinforced composite, buckling and free vibration analysis of sandwich composite beam in two configurations, of laminates using differential quadrature method (DQM) is studied. Also, the effects of porosity coefficient and three types of porosity distribution on critical buckling load and natural frequency are discussed. It is shown the buckling loads and natural frequencies of laminate 1 are significantly larger than the results of laminate 2. When configuration 2 (the core is made of FRC) and laminate 1 ([0/90/0/45/90]s) are used, the first natural frequency rises noticeably. It is also demonstrated that the influence of the core height in the case of lower carbon volume fractions is negligible. Even though, when volume fraction of fiber increases, the critical buckling load enhances smoothly. It should be noticed the amount of decline has inverse relationship with the beam aspect ratio. Investigating three porosity patterns, beam with the distribution of porosity Type 2 has the maximum critical buckling load and first natural frequency. Among three elastic foundations (constant, linear and parabolic), buckling load and natural frequency in linear variation has the least amount. For all kind of elastic foundations, when the porosity coefficient increases, critical buckling load and natural frequency decline significantly.