• Title/Summary/Keyword: Ferromagnetic phase

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Phase Stability of $Fe_{16}C_2$ and $Fe_{16}C_4$ from First-principles Calculations

  • Rahman, Gul;Kim, In-Gee
    • Proceedings of the Korean Magnestics Society Conference
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    • 2009.12a
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    • pp.74-75
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    • 2009
  • First-principles calculations were carried out to investigate the crystal stability and magnetism of $Fe_{16}C_2$ and $Fe_{16}C_2$. Our precise calculations show that the structure of high carbon phase is $Fe_{16}C_2$ and this structure is more stable in the ferromagnetic state than the nonmagnetic state. The Fe atoms induced negative magnetic moment at the C atoms, which interact with the nearest Fe atoms.

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Fabrication of Nano-sized Metal Dispersed Magnesia Based Composites and Related Mechanical and Magnetic Properties

  • Choa, Yong-Ho;Tadachika Nakayama;Tohru Sekino;Koichi Niihara
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.395-399
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    • 1999
  • MgO/metal nanocomposite powder mixtures were prepared by solution chemical processes to obtain suitable structure for ceramic/metal nanocomposites. Nickel or cobalt nitrate, as a source of metal dispersion, was dissolved into alcohol and mixed with magnesia powder. After calcined in air, these powders were reduced by hydrogen. Densified nanocomposites were successively obtained by Pulse Electric Current Sintering (PECS) process. The dispersed metal partical size depended on temperature and time in calcination and reduction processes. The phase analyses in the synthesized powders as a functioni of temperature were tracked using a dynamic high temperature X-ray diffractioni (HTXRD) system. Phase and crystallite size analyses were done using X-ray diffractioni and TEM. The MgO/metal nanocomposites were successfully fabricated, and ferromagnetic responses with enhanced coercive force were also investigated for these composites.

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Magnetoresistance behavior of $La_{1-\chi}Sr_\chiCoO_{3-\delta}$ films around the metal-insulator transition

  • Park, J. S.;Park, H. G.;Kim, C. O.;Lee, Y. P.;V. G. Prokhorov
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.100-103
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    • 2003
  • The magnetoresistance (MR) of $La_{1-\chi}S_{\chi}CoO_{3-\delta}$ films prepared by pulsed-laser deposition were investigated in order to clarify the magnetotransport properties around the metal-insulator transition. For the films in the metallic state ($\chi$ > 0.25), the MR(T) manifests a small peak at the Curie temperature due to the spin-disorder scattering. The transition of the film into the insulating state ($\chi\;\leq$ 0.25) is accompanied by an essential growth of the MR and results in a significant increase in the MR(T) with decreasing temperature, due to a phase separation into the ferromagnetic-metal clusters and the insulating matrix.

Finite Element Study of Ferroresonance in single-phase Transformers Considering Magnetic Hysteresis

  • Beyranvand, Morteza Mikhak;Rezaeealam, Behrooz
    • Journal of Magnetics
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    • v.22 no.2
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    • pp.196-202
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    • 2017
  • The occurrence of ferroresonance in electrical systems including nonlinear inductors such as transformers will bring a lot of malicious damages. The intense ferromagnetic saturation of the iron core is the most influential factor in ferroresonance that makes nonsinusoidal current and voltage. So the nonlinear behavior modeling of the magnetic core is the most important challenge in the study of ferroresonance. In this paper, the ferroresonance phenomenon is investigated in a single phase transformer using the finite element method and considering the hysteresis loop. Jiles-Atherton (JA) inverse vector model is used for modeling the hysteresis loop, which provides the accurate nonlinear model of the transformer core. The steady-state analysis of ferroresonance is done while considering different capacitors in series with the no-load transformer. The accurate results from copper losses and iron losses are extracted as the most important specifications of transformers. The validity of the simulation results is confirmed by the corresponding experimental measurements.

Electical Transport Properties of La$_{1.6}$Ca$_{1.4}$Mn$_2$O$_{7.07}$ System (La$_{1.6}$Ca$_{1.4}$Mn$_2$O$_{7.07}$의 전기전도특성)

  • 정우환
    • Journal of the Korean Ceramic Society
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    • v.36 no.8
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    • pp.843-847
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    • 1999
  • The dc resistivity dc magnetization and thermopower of layered perovskite La1.6Ca1.4Mn2O7.07 have been studied. The ceramic sample of La1.6Ca1.4Mn2O7.07 undergoes the metal-insulator transition at 120K while a first-order phase transition from a ferromagnetic phase to a paramagnetic phae is observed at 260 K=TC This behavior is quite different from that of the well-known double exchange ferromagnets such as La1-xCaxMnO3 This phenomenon could be understood by considering the effects of the anisotropic double exchange interaction caused by two dimensional Mn-O-Mn networks in this materials. The dc magnetization between 120K and 250K is nearly constant and decreases rapidly with increasing temperature above 250K The measurements of dc resistivity and thermopower indicate that Zener polaron hopping conduction takes place above 260 K.

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Syntheses and Characteristics of Layered Perovskite $La_{2-x}Ca_{1+x}Mn_{2}O_{7}$ (층상구조형 페롭스카이트 $La_{2-x}Ca_{1+x}Mn_{2}O_{7}$상의 합성 및 특성)

  • 서상일;이재열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.555-558
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    • 2000
  • Layered perovskite La$_{2-x}$Ca$_{l-x}$Mn$_2$O$_{7}$ phases were synthesized by solid state reaction. Single phase R-P could be obtained in the range of 0.4$_{2-x}$Ca$_{l-x}$Mn$_2$O$_{7}$. About 30% of MR ratio was obtained at 270K when 5 T of magnetic field was applied.ied.ied.ied.

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Influence of crystallization treatment on structure, magnetic properties and magnetocaloric effect of Gd71Ni29 melt-spun ribbons

  • Zhong, X.C.;Yu, H.Y.;Liu, Z.W.;Ramanujan, R.V.
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1289-1293
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    • 2018
  • The influence of crystallization treatment on the structure, magnetic properties and magnetocaloric effect of $Gd_{71}Ni_{29}$ melt-spun ribbons has been investigated in detail. Annealing of the melt-spun samples at 610 K for 30 min, a majority phase with a $Fe_3C$-type orthorhombic structure (space group, Pnma) and a minority phase with a CrB-type orthorhombic structure (space group, Cmcm) were obtained in the amorphous matrix. The amorphous melt-spun ribbons undergo a second-order ferromagnetic to paramagnetic phase transition at 122 K. For the annealed samples, two magnetic phase transitions caused by amorphous matrix and $Gd_3Ni$ phases occur at 82 and 100 K, respectively. The maximum magnetic entropy change $(-{\Delta}S_M)^{max}$ is $9.0J/(kg{\cdot}K)$ (5T) at 122 K for the melt-spun ribbons. The values of $(-{\Delta}S_M)^{max}$ in annealed ribbons are 1.0 and $5.7J/(kg{\cdot}K)$, corresponding to the two adjacent magnetic transitions.

Consolidation and magnetic properties of ferromagnetic Fe-MgO powders prepared by ball milling process (볼밀링법으로 제조된 강자성 Fe-MgO 분말의 벌크화 및 자기적 특성)

  • Chung-Hyo Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.34 no.4
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    • pp.125-130
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    • 2024
  • Preparation of ferromagnetic powders for the mixture of hematite and pure Mg powders by ball milling has been investigated. Also, consolidation of the ball-milled powders was performed in a spark plasma sintering machine at 800-1,000℃. It is found that a ferromagnetic Fe-MgO composite powders are obtained by ball milling of hematite and pure Mg powders before 1 hour. The magnetization and coercivity of ball-milled samples change at the results of the solid state reaction of hematite by pure Mg during ball milling. The saturation magnetization of ball-milled samples increases with increasing ball milling time and reaches to a maximum value of 93.4 emu/g after 5 hours of ball milling. Shrinkage change after sintering of ball-milled sample for 5 hours was significant above 300℃ and gradually increased with increasing temperature up to 800℃. X-ray diffraction result shows that the average grain size of Fe in Fe-MgO bulk sample sintered at 900℃ is 50 nm. It can be also seen that the coercivity of bulk sample sintered at 900℃ is still high value of 90 Oe, indicating that the grain growth of magnetic Fe phase during sintering process tend to be suppressed.

Magnetic Core Reactor for DC Reactor type Three-Phase Fault Current Limiter

  • Kim, Jin-Sa;Bae, Duck-Kweon
    • International Journal of Safety
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    • v.7 no.2
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    • pp.7-11
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    • 2008
  • In this paper, a Magnetic Core Reactor (MCR) which forms a part of the DC reactor type three-phase high-Tc superconducting fault current limiter (SFCL) has been developed. This SFCL is more economical than other types with three coils since it uses only one high-Tc superconducting (HTS) coil. When DC reactor type three-phase high-Tc SFCL is developed using just one coil, fewer power electronic devices and shorter HTS wire are needed. The SFCL proposed in this paper needs a power-linking device to connect the SFCL to the power system. The design concept for this device was sprang from the fact that the magnetic energy could be changed into the electrical energy and vice versa. Ferromagnetic material is used as a path of magnetic flux. When high-Tc superconducting DC reactor is separated from the power system by using SCRs, this device also limits fault current until the circuit breaker is opened. The device mentioned above was named Magnetic Core Reactor (MCR). MCR was designed to minimize the voltage drop and total losses. Majority of the design parameters was tuned through experiments with the design prototype. In the experiment, the current density of winding conductor was found to be $1.3\;A/mm^2$, voltage drop across MCR was 20 V and total losses on normal state was 1.3 kW.

Mechanically Driven Decomposition of Intermetallics

  • Kwon, Young-Soon;Kim, Hyun-Sik;Gerasimov, Konstantin B.
    • Journal of Powder Materials
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    • v.9 no.6
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    • pp.422-432
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    • 2002
  • Mechanically driven decomposition of intermetallics during mechanical milling(MM 1 was investigated. This process for Fe-Ce and Fe-Sn system was studied using conventional XRD, DSC, magnetization and alternative current susceptibility measurements. Mechanical alloying and milling form products of the following composition (in sequence of increasing Gecontent): $\alpha$(${\alpha}_1$) bcc solid solution, $\alpha$+$\beta$-phase ($Fe_{2-x}Ge$), $\beta$-phase, $\beta$+FeGe(B20), FeGE(B20), FeGe(B20)+$FeGe_2$,$FeGe_2$,$FeGe_2$+Ge, Ge. Incongruently melting intermetallics $Fe_6Ge_5$ and $Fe_2Ge_3$ decompose under milling. $Fe_6Ge_5$ produces mixture of $\hat{a}$-phase and FeGe(B20), $Fe_2Ge_3$ produces mixture of FeGe(B20) and $FeGe_2$ phases. These facts are in good agreement with the model that implies local melting as a mechanism of new phase for-mation during medchanical alloying. Stability of FeGe(B20) phase, which is also incongruently melting compound, is explained as a result of highest density of this phase in Fe-Ge system. Under mechanical milling (MM) in planetary ball mill, FeSn intermetallic decomposes with formation $Fe_5Sn_3$ and $FeSn_2$ phases, which have the biggest density among the phases of Fe-Sn system. If decomposition degree of FeSn is relatively small(<60%), milled powder shows superparamagnetic behavior at room temperature. For this case, magnetization curves can be fitted by superposition of two Langevin functions. particle sizes for ferromagnetic $Fe_5Sn_3$ phase determined from fitting parameters are in good agreement with crystalline sizes determined from XRD data and remiain approximately chageless during MM. The decomposition of FeSn is attributed to the effects of local temperature and local pressure produced by ball collisions.