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Effect of the Steam Flow Rate on Syngas Productivity in IGCC Gasifier for a Power Generation (IGCC 발전용 가스화기에서 증기 주입량이 합성가스 생산량에 미치는 영향)

  • Keum, Kyung-Nam;Yoo, Ho-Seon
    • Plant Journal
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    • v.15 no.3
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    • pp.29-34
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    • 2019
  • In the study, the effect of steam injection on syngas productivity was investigated under the constant operating conditions of gasifier oxygen load while the coal feed was fixed and the steam injection flow rate is changed in Taean IGCC plant. The maximum syngas average productivity was found to be at 80 % and 90 % of gasifier oxygen loads with the steam injection flow rate of 0.14 kg/s and 0.15 kg/s per coal burner. Through this study, the syngas productivity was changed by adjusting the steam injection amount and as the steam injection flow rate increased, the syngas productivity increased and then decreased again. The syngas productivity can be increased only by steam injection without supplying additional coal and it is considered that the syngas productivity has different characteristics depending on coal type. Thus it is recommended to operate the gasifier using Carbo-One coal with the steam injection flow rate of about 0.14 kg/s per coal burner when the gasifier oxygen load is 80 % ~ 90 %.

The Permeation Behaviors of $H_2S/CH_4$ using Polyimide Hollow Fiber Membranes (폴리이미드 중공사막을 이용한 $H_2S/CH_4$ 투과거동에 관한 연구)

  • Lee, Hyung-Keun;An, Young-Mo;Kim, Dae-Hoon;Jo, Hang-Dae;Seo, Yong-Seog;Park, Yeong-Seong
    • Membrane Journal
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    • v.19 no.4
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    • pp.261-267
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    • 2009
  • Polyimide which is the glassy polymer has high chemical resistance, thermal stability and high mechanical property. In this study, the polyimide hollow fiber membranes were prepared by the dry-jet wet phase inversion in order to investigate the permeation porperties of the $H_2S$ and $CH_4$. The morphology of prepared hollow fiber membranes and their permeation behaviors of $H_2S$ and $CH_4$ before and after silicon coating were evaluated. The permeance of $H_2S$ and $H_2S/CH_4$ selectivity increased due to plasticization with increasing the feed pressure. The permeance of KSM03b and selectivity of KSM03d were highest among the three type membranes used this experiments. The permeance decreased but the $H_2S/CH_4$ selectivity increased with increasing the air gap. The permeance reduced after silicon coating. However, the selectivity increased and the selectivity of KSM03d was 275 at 7 atm.

Reactive Ceramic Membrane Incorporated with Iron Oxide Nanoparticle for Fouling Control (산화철 나노입자 부착 반응성 세라믹 멤브레인의 막 오염 제어)

  • Park, Hosik;Choi, Heechul
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.2
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    • pp.144-150
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    • 2013
  • Hybrid ceramic membrane (HCM) processes that combined ozonation with a ceramic membrane (CM) or a reactive ceramic membrane (RM), an iron oxide nanoparticles (IONs) incorporated-CM were investigated for membrane fouling control. Alumina disc type microfiltration and ultrafiltration membranes doped with IONs by sintering method were tested under varying mass fraction of IONs. Scanning electron microscope (SEM) images showed that IONs were well-doped on the CM surface and doped IONs were approximately 50 nm in size. Change in the pure water permeability of RM was negligible compared to that of CM. These results indicate that IONs incorporation onto CM had little effect on CM performance in terms of the flux. Natural organic matter (NOM) fouling and fouling recovery patterns during HCM processes confirmed that the RM-ozonation process enhanced the destruction of NOM and reduced the extent of fouling more than the CM-ozonation process by hydroxyl radical formation in the presence of IONs on RM. In addition, analyses of NOM in the feed water and the permeate showed that the efficiency of membrane fouling control results from the NOM degradation during HCM processes; leading to removal and transformation of relatively high contents of aromatic, high molecular weight and hydrophobic NOM fractions.

Effects of Supplemental Vegetable Oils on Ruminal Characteristics, Digestibility and Formation of Fatty Acid Soaps in Sheep (식물성유 첨가가 면양의 반추의 발효특성과 소화율 및 지방산염 형성에 미치는 영향)

  • Kim, D.I.;Choi, J.R.;Cho, S.H.;Lee, D.H.;Chung, T.Y.
    • Journal of Animal Science and Technology
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    • v.46 no.5
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    • pp.783-798
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    • 2004
  • This experiment were conducted to determine the formation of fatty acid soaps, digestibility and ruminal characteristics when vegetable oils were added. Three Corriedale${\times}$ 3 Latin square design. Sheep were fed one of three diets consisting of alfalfa hay and concentrates in a ratio of 70:30. Dietary treatments were 1) no oil, 2) 7% soybean oil and 3) 7% corn oil. At the end of each experimental period, rumen contents from each sheep were collected before feeding and at 1, 3, 6 and 9h after feeding. pH decreased up to the 3 hour after feeding and increased until the end of the collection(p<0.0001). Whereas the concentration of $NH_3$-N showed inverse changes to pH(p<0.0001). Type of oil did not affect the molar concentration of total VFA, acetate, propionate and butyrate. Acetic/propionic acid (A/P) ratio decreased with increasing time(P<0.0001), but the ratio at the end of the experiment became similar to the initial value. No effects were found in the digestibility of dry matter, total-N, crude fiber, ash, NFE, NDF and ADF. The formation of fatty acid soaps(FAS) increased after feeding than 1 hour before feeding(P<0.05) and increased in 7% oils than no oil addition(P<0.05). Long chain fatty acids formed mainly FAS. ince the formation of FAS might decrease negative effects on ruminal haracteristics and total tract digestibility.

Binderless Consolidation of Fine Poly-Si Powders for the Application as Photovoltaic Feedstock (태양전지(太陽電池) 원재료(原材料)로 사용(使用)하기 위한 폴리실리콘 미세분말(微細粉末)의 무점결제(無粘結劑) 성형(成形))

  • Shin, Je-Sik;Kim, Dae-Suk;Kim, Ki-Young;Shon, In-Jin;Moon, Byung-Moon
    • Resources Recycling
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    • v.18 no.1
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    • pp.38-43
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    • 2009
  • In this study, binderless consolidation processes of ultra foe Si powder, by-products of making high purity poly-Si in the current method, were systematically investigated for use as economical solar-grade feedstock. The average diameter of the silicon powder was $7.8{\mu}m$. The main contaminants of the fine silicon powder were $SiO_2$ type oxide and humidity. The chemical pretreatment using the HF solution was observed to be effective for the improvement of the compactability of the silicon powder and the density ratio and the strength of the silicon powder compacts. The yield of the binder-free consolidation process increased by 20% under a vacuum condition. In as-received state, the silicon powder were not pure enough to be used as solar grade feed-stock material. After the dry chemical treatments, a sufficiently high purity above solar-grade was able to be achieved.

Monitoring Anaerobic Reductive Dechlorination of TCE by Biofilm-Type Culture in Continuous-Flow System (연속흐름반응조에서 바이오필름형태의 탈염소화 미생물에 의한 TCE분해 모니터링)

  • Park, Sunhwa;Han, Kyungjin;Hong, Uijeon;Ahn, Hongil;Kim, Namhee;Kim, Hyunkoo;Kim, Taeseung;Kim, Young
    • Journal of Soil and Groundwater Environment
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    • v.17 no.5
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    • pp.49-55
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    • 2012
  • A 1.28 L-batch reactor and continuous-flow stirred tank reactor (CFSTR) fed with formate and trichloroethene (TCE) were operated for 120 days and 56 days, respectively, to study the effect of formate as electron donor on anaerobic reductive dechlorination (ARD) of TCE to cis-1,2-dichloroethylene (c-DCE), vinyl chloride (VC), and ethylene (ETH). In batch reactor, injected 60 ${\mu}mol$ TCE was completely degraded in the presence of 20% hydrogen gas ($H_2$) in less than 8 days by anaerobic dechlorination mixed-culture (300 mg-soluble protein), Evanite Culture with ability to completely degrade tetrachloroethene (PCE) and -TCE to ETH under anaerobic conditions. Once the formate was used as electron donor instead of hydrogen gas in batch or chemostat system, the TCE-dechlorination rate decreased and acetate production rate increased. It indicates that the concentration of hydrogen produced in both systems is possibly more close to threshold for homoacetogenesis process. Soluble protein concentration of Evanite culture during the batch test increased from 300 mg to 688 mg for 120 days. Through the protein monitoring, we confirmed an increase of microbial population during the reactor operation. In CFSTR test, TCE was fed continuously at 9.9 ppm (75.38 ${\mu}mol/L$) and the influent formate feed concentration increased stepwise from 1.3 mmol/L to 14.3 mmol/L. Injected TCE was accumulated at 18 days of HRT, but TCE was completely degraded at 36 days of HRT without accumulation of the injected-TCE during the left of experiment period, getting $H_2$ from fermentative hydrogen production of injected formate. Although c-DCE was also accumulated for 23 days after beginning of CFSTR operation, it reached steady-state in the presence of excessive formate. We also evaluated microbial dynamic of the culture at different chemical state in the reactor by DGGE (denaturing gradient gel electrophoresis).

Vinyl Addition Polymerization Behavior of Poly(5-hexyl-2-norbornene-co-5-methylester-2-norbornene)s Using Cationic ${\eta}^3$-Allyl Palladium Catalyst (양이온성 ${\eta}^3$-알릴 팔라듐 촉매를 사용한 폴리(5-헥실-2-노보넨-co-5-메틸에스터-2-노보넨)의 비닐 부가 중합 거동)

  • 안재철;박기홍
    • Polymer(Korea)
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    • v.28 no.3
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    • pp.245-252
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    • 2004
  • We synthesized the vinyl addition-type polynorbomene copolymers using two monomers [5-hexyl-2-norbornene (HNB) and 5-methyleste-2-norbornene(MES-NB)] by means of a cationic ${\eta}^3$-allyl palladium catalyst system{[(${\eta}^3$-allyl)palladium(tricyclohexylphosphine) trifluoroacetate] and [lithium tetrakis(pentafluorophenyl) borate ${\cdot}$2.5 etherate]}. The molecular weights and yields of copolynorbomenes polymerized in various conditions were measured to investigate an optimum polymerization conditions to obtain highly ester-functionalized polynorbomenes. As a Pd catalyst content increased, the molecular weights (Mw) of polymers decreased while polymer yields increased. Also, as a Li cocatalyst content increased, the Mw’s and yields of polymers increased at the same time. The Mw’s of copolymers were also controlled by chain transfer agents such as 1-hexone, 1-octene and 1-decene, and we found that longer 1-decene and 1-octene were more efficient to reduce the Mw’s of polynorbornenes than 1-hexene. On the other hand, the content of chain transfer agents did not give influence significantly on polymer yields. From the $^1$H-NMR and GPC analysis of HNB/MES-NB(feed ratio of 40/60 mol%) copolymer, we found that this copolymer had an about 25 mol% of ester portion and a high molecular weight of 270,000.

Growth Characteristics and Forage Productivity of New Orchardgrass (Dactylis glomerata L.) Variety, 'Lucky One' (오차드그라스 신품종 '럭키원'의 생육특성과 수량성)

  • Ji, Hee Chung;Che, Hyun Seog;Lee, Song Tea;Hwang, Tae Young;Kim, Ki Yong;Lee, Sang Hun;Lee, Ki Won
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.36 no.1
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    • pp.19-22
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    • 2016
  • 'Lucky one' is a new orchardgrass (Dactylis glomerata L.) variety developed by the National Institute of Animal Science (NIAS) in 2014. Four superior clones were selected and polycrossed for seed production to develope this new variety of orchardgrass. The agronomic growth characteristics and forage productivity of 'Lucky one' were examined at Cheonan from 2010 to 2011. Regional adaption trials were conducted in Cheonan, Hoengseong, Jinju, and Jeju from 2012 to 2014. 'Lucky one' showed growth habit of medium type in fall and spring. It has short flag leaf length with long upper internode. Plant height of 'Lucky one' was 3 cm more than that of control variety, 'Amba'. Its heading date was 2 days later than that of control variety 'Amba'. Characteristics such as waterlogging and disease resistance of 'Lucky one' were stronger or better than those of control variety, 'Amba', Especially, dry matter yield of 'Lucky one' (16,191 kg/ha) was increased 38% compared to that of control variety, 'Amba'(11,778 kg/ha). Nutritive feed values of 'Lucky one' appeared to be similar to those of control variety 'Amba' except in Vitro dry matter digestibility (IVDMD) and crude protein content.

Growth Characteristics and Forage Productivity of New Orchardgrass (Dactylis glomerata L.) Variety, 'Onnuri 2ho' (오차드그라스 신품종 '온누리 2호'의 생육특성과 수량성)

  • Ji, Hee Chung;Che, Hyun Seog;Lee, Song Tea;Hwang, Tae Young;Kim, Ki Yong;Lee, Sang Hun
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.36 no.1
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    • pp.15-18
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    • 2016
  • 'Onnuri 2ho' is a new orchardgrass (Dactylis glomerata L.) variety developed by the National Institute of Animal Science (NIAS) in 2014. Four superior clones were selected and polycrossed for seed production to develop this new variety of orchardgrass. The agronomic growth characteristics and forage productivity of 'Onnuri 2ho' were examined at Cheonan from 2010 to 2011. Regional adaptation trials were conducted in Cheonan, Hoengseong, Jinju and Jeju from 2012 to 2014. 'Onnuri 2ho' showed growth habit of medium type in fall and spring. It is long in length of flag leaf with medium upper internode. Plant height of 'Onnuri 2ho' was 4 cm more than that of control variety, 'Amba'. Its heading date was 4 days later than compared to control variety, 'Amba'. Characteristics such as waterlogging and disease resistance of 'Onnuri 2ho' were stronger or better than those of control variety, 'Amba', Especially, the dry matter yield of 'Onnuri 2ho' (15,814 kg/ha) was increased 34 % compared to that of control variety, Amba (11,778 kg/ha). Nutritive feed values of 'Onnuri 2ho' appeared to be similar to that of control variety 'Amba' except in Vitro dry matter digestibility (IVDMD).

Evaluating the effects of finishing diet and feeding location on sheep performance, carcass characteristics, and internal parasites

  • Ragen, Devon L;Butler, Molly R;Boles, Jane A;Layton, William A;Craig, Thomas M;Hatfield, Patrick G
    • Journal of Animal Science and Technology
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    • v.63 no.3
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    • pp.545-562
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    • 2021
  • A 3 yr experiment was conducted to evaluate the influence of diet and feeding location on animal performance, carcass characteristics, whole blood counts, and internal parasite burden of lambs assigned to 1 of 4 treatments: 1) confinement fed 71% alfalfa, 18% barley pellet, 5% molasses, 0.013% Bovatec, 6.1% vitamin/mineral package diet (CALF), 2) confinement fed 60% barley, 26% alfalfa pellet, 4% molasses, 2.5% soybean-hi pro, 0.016% Bovatec, 7.4% vitamin/mineral package diet (CBAR), 3) field fed 71% alfalfa, 18% barley pellet, 5% molasses, 0.013% Bovatec, 6.1% vitamin/mineral package diet (FALF), and 4) field fed 60% barley, 26% alfalfa pellet, 4% molasses, 2.5% soybean-hi pro, 0.016% Bovatec, 7.4% vitamin/mineral package diet (FBAR). A year × location interaction was detected for ending body weight (BW), average daily gain (ADG), and dry matter intake (DMI); therefore results are presented by year. In all years, cost of gain and DMI were greater for CALF and FALF than for CBAR and FBAR feed treatments (p ≤ 0.03). In yr 2 and 3 field treatments had greater ending BW and ADG than confinement treatments. For all years, diet did not affect ending BW or ADG. In yr 1 dressing percent and rib eye area were greater for field finished lambs than confinement finished (p ≤ 0.02) and Warner-Bratzler shear force was greater for CALF and FALF (p = 0.03). In yr 2 lambs in FALF and FBAR treatments had greater leg scores and conformation than CALF and CBAR (p = 0.09). In yr 1, FALF had a greater small intestine total worm count than all other treatments. In yr 1, ending Trichostrongyle type egg counts were greater for FALF (p = 0.05). In yr 2, ending Nematodirus spp. egg counts were greater for FALF and lowest for CBAR (p < 0.01). Abomasum Teladorsagia circumcinta worm burden was greater in CALF than all other treatments (p = 0.07) in yr 2. While field finishing lambs with a grain- or forage-based diet we conclude that it is possible to produce a quality lamb product without adverse effects to animal performance, carcass quality or increasing parasite burdens.