• Title/Summary/Keyword: FePc

Search Result 107, Processing Time 0.037 seconds

Influence of surface morphology and thickness of molecular thin films on the performance of SubPc-$C_{60}$ photovoltaic devices

  • Kim, Jin-Hyun;Gong, Hye-Jin;Yim, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.02a
    • /
    • pp.336-336
    • /
    • 2011
  • Over the past decades, organic semiconductors have been investigated intensely for their potential in a wide range of optoelectronic device applications since the organic materials have advantages for very light, flexible and low cost device fabrications. In this study, we fabricated small-molecule organic solar cells (OSCs) based on chloro[subphthalocyaninato]boron(III) (SubPc) as an electron donor and $C_{60}$ as an electron acceptor material. Recently SubPc, a cone-shaped molecule with $14{\pi}$-electrons in its aromatic system, has attracted growing attention in small-molecule OSC applications as an electron-donating material for its greater open-circuit voltage (VOC), extinction coefficient and dielectric constant compared to conventional planar metal phthalocyanines. In spite of the power conversion efficiency (PCE) enhancement of small-molecule OSC using SubPc and $C_{60}$, however, the study on the interface between donor-acceptor heterojunction of this system is limited. In this work, SubPc thin films at various thicknesses were deposited by organic molecular beam deposition (OMBD) and the evolution of surface morphology was observed using atomic force microscopy (AFM) and field emission scanning electron microscopy (FE-SEM). We also investigated the influence of film thickness and surface morphology on the PCE of small-molecule OSC devices.

  • PDF

Preparation and characterization of isosorbide based PET/polycarbonate blends (Isosorbide가 함유된 바이오 기반 PET와 polycarbonate 블렌드의 제조 및 특성 연구)

  • Park, Ji-Soo;Nam, Byeong-Uk;Park, Jun-Seo
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.15 no.2
    • /
    • pp.1216-1221
    • /
    • 2014
  • Poly(ethylene-co-isosorbide terephthalate) (PEIT) is interest in polymer which has isosorbide monomer that is renewable resources such as corn. However, there is important drawback which is low mechnical properties as increasing isosorbide contents. In this study, polycarbonate used to make up for drawback of mechanical properties of PEIT. In addition, PEIT used to improve the tensile elongation of polycarbonate because PEIT has good sheet proccessability. The effect of polycarbonate on morphology, thermal and mechanical properties were investigated using FE-SEM, DMA, TGA, UTM, and notched izod impact strength tester. As a result of this study, PEIT/PC blends were in compatible system and polycarbonate can act as an improvement of thermal stability and mechanical properties in the blends.

Synthesis and Characteristic of ${\epsilon}$-type Copper Phthalocyanine Used as Color Filter in LCD Panel (입실론 프탈로시아닌의 합성 및 특성에 대한 연구)

  • Kim, Jae Hwan;Kim, Song Hyuk;Kim, Seong Jin;Hong, Seong-Soo;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
    • /
    • v.23 no.2
    • /
    • pp.138-142
    • /
    • 2012
  • The ${\epsilon}$ type copper phthalocyanine (${\epsilon}$-CuPc), called as a pigment blue 15 : 6, is a significant material to produce a blue pixel in LCD (Liquid Crystal Display) panel. In this study, ${\epsilon}$-CuPc sample was synthesized at various reaction conditions by applying the seed method using ${\epsilon}$-CuPc nanoparticles as a seed. Adequate synthetic conditions of the samples were selected by analyzing and comparing crystalline structure, crystalline purity, microstructure, and synthetic yield of the samples with ${\alpha}$ and ${\beta}$ crystalline CuPc samples. The chemical and crystalline structure of the samples were tested using FT-IR spectrometer and X-ray diffractometry, respectively. The shape of the particle was examined using field emission scanning electiron microscope while the thermal property was tested utilizing thermogravimetric analysis.

Use and Need of Health and Nutrition Information on the Computer among University Students (대학생의 컴퓨터를 통한 건강 및 영양정보의 이용실태 및 요구도)

  • Kang Nam-Mi;Hyun Tai-Sun
    • The Journal of Korean Academic Society of Nursing Education
    • /
    • v.4 no.1
    • /
    • pp.7-14
    • /
    • 1998
  • The use and need of health and nutrition information on the PC communication and internet among university students at Chungbuk area were investigated. The data from 167 students from two different universities were collected and analyzed from March to May, 1998. The results are as follows. 1. Male students were 27.5% and female students were 72.5%. 2. Sixty percent and 74.7% of the students had ever used PC communication and internet, respectively. Higher proportions of male students had experiences in PC communication and internet use than fe male students. The main reasons to use PC communication and internet were 1)to obtain information and knowledge(67.4%) 2)to enjoy(10.5%), 3)to make friends or to talk(5.3%) 3. About 40% of the experienced students of the PC communication of internet obtained health or nutrition information. However, only 25% of the experienced students obtained the nutrition information from the internet. Only 10% of the students agreed that the information from the PC communication and internet was very useful. The reasons not to use the information from the PC communication and internet were 'lack of expertise of the information' and 'long response time'. Many students thought that the information provided through the computer should be improved in terms of variety and applicability to the real situation. 4. Among the 33 topics of the health and nutrition information given on the questionnaire, both male and female students had the greatest interest in stress management. The next topics in which female students had interests were diet for weight control, health problems related to menstration, dietary assessment, and cancer prevention. In male students, dietary assessment, infant nutrition management, hypertention diet were the main interests. On the basis of these results an information system on health and nutrition management during the lifecycle for Korean women will be constructed on the internet.

  • PDF

Hydroxyl radical에 의해 유도된 단백질, 지질의 산화적 손상에 대한 멜라토닌, glutathione, $\alpha$-tocopherol의 방어효과

  • Kim, Seok-Jung
    • Bulletin of Food Technology
    • /
    • v.11 no.4
    • /
    • pp.49-60
    • /
    • 1998
  • Ascorbate-$Fe^3+$-EDTA에 의해 생성된 hydroxyl radical (HO.)을 이용하여 단백질과 지질의 산화적 손상을 유도하였으며, 이 손상에 대한 멜라토닌(melatonin), glutathione, $\alpha$-tocopherol의 방어효과를 분석하였다. 단백질로는 bovine serum albumin (BSA), 지질로는 phosphatidyl-choline (PC) liposome을 이용하였다. 그리고 BSA와 PC liposome의 혼합계에서도 각 항산화제의 효능을 분석하였다. 단백질의 산화적 손상은 carbonyl기의 생성 및 단백질 절단을, 지질산화는 lipid peroxidation (LPO, malondialdehyde 와 4-hydroxyalkenal) 분석을 통하여 조사하였다. 단백질의 산화는 멜라토닌과 glutathione이, 지질산화는 멜라토닌과 $\alpha$-tocopherol이 효과적으로 억제하였다. 그러나 glutathione은 지질, $\alpha$-tocopherol은 단백질의 산화를 억제하지 못하였다. BSA와 PC liposome이 동시에 존재하는 혼합물에서는 수용성과 지용성 특성을 모두 지닌 멜라토닌은 단백질, 지질 모두에 대해 산화방지효과가 있으나 수용성인 glutathione은 단백질에, 지용성인 $\alpha$-tocopherol은 지질에만 주로 효과가 있는 것으로 조사되었다.

  • PDF

Development of reliability test to reduce the field failure rate of PC Monitor (PC 모니터의 시장불량률 감소를 위한 신뢰성 시험법 개발)

  • Kim Jun Hong
    • Proceedings of the Society of Korea Industrial and System Engineering Conference
    • /
    • 2002.05a
    • /
    • pp.37-44
    • /
    • 2002
  • In order to review the failure rate of PC monitor under normal environmental conditions, we experimented for various levels of each factors, e.g Power on/off, DPM mode, using voltage, Incoming Surge, Torque strength etc. According to the results of experiment and SN ratios we investigated that the causes of the failure for the horizontal output TR of monitor are Mode change, dispersion of Torque and $h_{FE}$ and these are critical effect. For the new reliability test we suggested that strengthened part tests In IQC branch, Torque change controls in the TR specification are necessary.

  • PDF

Effect of Synthetic Resin Container on the Stability of FAD Solution (합성수지 용기가 FAD 수용액의 안정성에 미치는 영향)

  • 이계주;유병설
    • YAKHAK HOEJI
    • /
    • v.23 no.3_4
    • /
    • pp.147-152
    • /
    • 1979
  • Experiments were carried out to investigate for the interaction between FAD solution and synthetic resin containers made of polyvinylchloride(PVC), polyethylene(PE), and polycarbonate(PC), and for the effect of glycyrrhizine or malic acid on stabilization of FAD in aqueous solution by accelerated stability analysis. Analysis of FAD was determined by means of spectrometer and by separating by paper chromatography and metal ions were detected by atomic absorption spectrophotometer, which were extracted from containers by means of Food and Additive Regulation Standard. The thermal decomposition of FAD in aqueous solution was pseudo first order reaction and it was inhibited by adding glycyrrhizine or malic into the solution. PVC, PE and PC containers accelerated the decomposition of FAD in solution. It is assumed that bivalent heavy metals in resin containers may catalize the hydrolysis of FAD. The metals detected from the containers were Ca, Zn, Cu, Fe, Pb and Cd. And the total amounts of detected metals from PVC were 6.2mcg/cm$^{2}$, PE, 5.5mcg/cm$^{2}$, and PC, 2.7mcg/cm$^{2}$ which were proportional to the rate constant of FAD decomposition in aqueous solution.

  • PDF

Development of reliability test to reduce the field failure rate of PC Monitor (PC 모니터의 시장불량률 감소를 위한 신뢰성 시험법 개발)

  • 김준홍
    • Journal of Korean Society of Industrial and Systems Engineering
    • /
    • v.24 no.67
    • /
    • pp.69-76
    • /
    • 2001
  • In order to review the failure rate of PC monitor under normal environmental conditions, we experimented for various levels of each factors, e.g. Power on/off, DPM mode, using voltage incoming Surge, Torque strength etc. According to the results of experiment and SN ratios we investigated that the causes of the failure for the horizontal output TR of monitor are Mode change, dispersion of Torque and $h_{FE}$ and these are critical effect. For the new reliability test we suggested that strengthened part tests in IQC branch, Torque change controls in the TR specification are necessary.

  • PDF

Development of Hybrid Panel with C-shaped Steel Beam at Top and Bottom of Precast Concrete Wall (프리캐스트 콘크리트 벽체의 상하부에 C형강 보가 결합된 복합 패널의 개발)

  • Lee, Sang Sup;Park, Keum Sung
    • Journal of Korean Society of Steel Construction
    • /
    • v.29 no.6
    • /
    • pp.435-442
    • /
    • 2017
  • A lateral load resisting system is a necessary structural element for the mid- to high-rise modular buildings and concrete cores are known as the most typical lateral load resisting systems in 10- to 20-story modular buildings. It is difficult to construct a concrete core simultaneously with the installation and finishing work of modular units because concrete placed using wet methods might contaminate or destroy the modular unit. Therefore, we have developed a hybrid PC (precast concrete) panel construction method that can construct a concrete core together with the installation of modular units. The hybrid PC panel is a load-bearing element in which a pair of C-shaped beams are combined at the top and bottom of a concrete wall. Concrete cores can be constructed by dry method to connect the hybrid PC panels with bolts. In this study, the details and connection of hybrid PC panels are improved to have the lateral performance comparable to reinforced concrete structural walls and are verified through FE analysis.