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High Temperature Wear of STD 61 Tool Steels Sliding Against Al-9%Si Coated Steels Used for Hot Press Forming (STD 61 공구강과 상대재인 핫 프레스 가공용 Al-9%Si 코팅강의 고온 미끄럼 마모)

  • Choi, Byung-Young;Kim, Hong-Ki
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.667-674
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    • 2009
  • High temperature wear of STD 61 tool steels sliding against the Al-9%Si coated steels used for hot press forming has been studied in comparison with that of the tool steels sliding against the uncoated steels. Wear tests have been performed using a pin-on-disc configuration under an applied normal load of 50N for 20 min with heating the coated and uncoated steels up to 800$^{\circ}C$. It was found on the worn surface of the STD 61 tool steels sliding against the Al-9%Si coated steels that the formation of the glazed layers containing Al transferred from the coated tribopair may contribute to a reduction of the coefficient of friction, and detachment in part occur due to delamination wear, resulting in higher specific wear rate. On the other hand the Fe-oxide wear debris entrapped on the softer surface of the uncoated steels can act as a tribosurface, leading to decreased adhesive wear of the STD 61 tool steels, resulting in a lower specific wear rate.

Analysis of Microstructure Evolution using Different Powder Metallurgy Process in Ti-X Alloy System (Ti-X계 합금의 분말야금 공정 차이에 따른 미세조직변화 분석)

  • Kwon, Hyeok-Gon;Kim, Doo-Hyeon;Gang, Min;Park, Ji-Hwan;Oh, Myung-Hoon
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.1
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    • pp.17-24
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    • 2021
  • In this study, Ti-X (X=Mn, Fe, Mo) powder alloys were designed and manufactured by both powder metallurgy (PM) and metal powder injection molding (MIM) process to improve strength and formability compared to CP-Ti powder materials. It was found that the lamellar microstructure consisted of α and β phases was formed in PM-processed alloys. However, MIM-processed alloys showed not the lamellar microstucture but the equiaxed α + β microstructure. It was also revealed that the contents of X component and feedstock were not affected to microstructure evolution. The reason why different microstructure was appeared between PM-processed and MIM-processed alloys is not clear yet, but supposed to be the effect of intersticial elements such as C, H and N derived from feedstock during debinding process of MIM.

Axial impact behavior of confined concrete filled square steel tubes using fiber reinforced polymer

  • Zhang, Yitian;Shan, Bo;Kang, Thomas H.K.;Xiao, Yan
    • Steel and Composite Structures
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    • v.38 no.2
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    • pp.165-176
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    • 2021
  • Existing research on confined concrete filled steel tubular (CCFT) columns has been mainly focused on static or cyclic loading. In this paper, square section CCFT and CFT columns were tested under both static and impact loading, using a 10,000 kN capacity compression test machine and a drop weight testing equipment. Research parameters included bonded and unbonded fiber reinforced polymer (FRP) wraps, with carbon, basalt and glass FRPs (or CFRP, BFRP, and GFRP), respectively. Time history curves for impact force and steel strain observed are discussed in detail. Experimental results show that the failure modes of specimens under impact testing were characterized by local buckling of the steel tube and cracking at the corners, for both CCFT and CFT columns, similar to those under static loading. For both static and impact loading, the FRP wraps could improve the behavior and increase the loading capacity. To analyze the dynamic behavior of the composite columns, a finite element, FE, model was established in LS-DYNA. A simplified method that is compared favorably with test results is also proposed to predict the impact load capacity of square CCFT columns.

Parametric study on the structural behaviour of composite slim floors with hollow-core slabs

  • Spavier, Patricia T.S.;Kataoka, Marcela N.;El Debs, Ana Lucia H.C.
    • Computers and Concrete
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    • v.28 no.5
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    • pp.497-506
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    • 2021
  • Steel-concrete composite structures and precast concrete elements have a common prefabrication process and allow fast construction. The use of hollow-core slabs associated with composite floors can be advantageous. However, there are few studies on the subject, impeding the application of such systems. In this paper, a numerical model representing the considered system using the FE (finite element)-based software DIANA is developed. The results of an experimental test were also presented in Souza (2016) and were used to validate the model. Comparisons between the numerical and test results were performed in terms of the load versus displacement, load versus slip, and load versus strain curves, showing satisfactory agreement. In addition, a wide parametric study was performed, evaluating the influence of several parameters on the behaviour of the composite system: The strength of the steel beam, thickness of the web, thickness and width of the bottom flange of the steel beam and concrete cover thickness on top of the beam. The results indicated a great influence of the steel strength and the thickness of the bottom flange of the steel beam on the capacity of the composite floor. The remaining parameters had limited influences on the results.

Compositional Feature Selection and Its Effects on Bandgap Prediction by Machine Learning (기계학습을 이용한 밴드갭 예측과 소재의 조성기반 특성인자의 효과)

  • Chunghee Nam
    • Korean Journal of Materials Research
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    • v.33 no.4
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    • pp.164-174
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    • 2023
  • The bandgap characteristics of semiconductor materials are an important factor when utilizing semiconductor materials for various applications. In this study, based on data provided by AFLOW (Automatic-FLOW for Materials Discovery), the bandgap of a semiconductor material was predicted using only the material's compositional features. The compositional features were generated using the python module of 'Pymatgen' and 'Matminer'. Pearson's correlation coefficients (PCC) between the compositional features were calculated and those with a correlation coefficient value larger than 0.95 were removed in order to avoid overfitting. The bandgap prediction performance was compared using the metrics of R2 score and root-mean-squared error. By predicting the bandgap with randomforest and xgboost as representatives of the ensemble algorithm, it was found that xgboost gave better results after cross-validation and hyper-parameter tuning. To investigate the effect of compositional feature selection on the bandgap prediction of the machine learning model, the prediction performance was studied according to the number of features based on feature importance methods. It was found that there were no significant changes in prediction performance beyond the appropriate feature. Furthermore, artificial neural networks were employed to compare the prediction performance by adjusting the number of features guided by the PCC values, resulting in the best R2 score of 0.811. By comparing and analyzing the bandgap distribution and prediction performance according to the material group containing specific elements (F, N, Yb, Eu, Zn, B, Si, Ge, Fe Al), various information for material design was obtained.

Stress concentration factors in tubular T-joints stiffened with external ring under axial load

  • Hossein Nassiraei;Pooya Rezadoost
    • Ocean Systems Engineering
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    • v.13 no.1
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    • pp.43-55
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    • 2023
  • In this study, the SCFs in tubular T-joints stiffened with external ring under axial load are studied and discussed. After verification of the present numerical model with the results of several available experimental tests, 156 FE models were generated and analyzed to parametrically evaluate the effect of the joint geometry and the ring geometry on the SCFs. Results indicated that the SCF of the stiffened T-joints at crown point can be down to 24% of the SCF of the corresponding un-reinforced joint at the same point. Also, the effect of the ring on the SCF at saddle point is more remarkable than the effect of the ring on the SCF at crown point. Moreover, against un-reinforced joints under axial load, the SCF at saddle point of the stiffened joint is smaller than the SCF at crown point of that stiffened joint. The ring results in the redistribution of stresses in the ring and metal substrate. Also, the effect of the ring thickness on the decrease of the SCFs is slight and can be ignored. In final step, the geometric parameters affecting the SCFs of the stiffened T-joints are analyzed by multiple nonlinear regression analyses. An accurate formula is proposed for determining the SCFs.

Effect of N, P and K Fertilizers Application on Growth, Yield and Mineral Nutrient Content in Platycodon grandiflorum for. duplux

  • Soo-Jeong Kwon;Young-Ho Choi;Hee-Ock Boo;Sun-Hee Woo;Hag-Hyun Kim
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.162-162
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    • 2022
  • This study was carried out to investigate the effects of nitrogen, phosphorus, potassium (three main macro elements of fertilizer) on growth, yield and mineral contents of Platycodon grandiflorum for. duplux and to obtain the basic data of the proper fertilizer application for increasing the yield of P. grandiflorum for. duplux. Plant height showed significantly good results in all fertilization treatments compared to non fertilizer group (the control, T0), and in particular, the highest was 85.7 cm in the complete group (T4). Chlorophyll content showed a high amount in the range of 20.7 to 23.8 against all fertilization treatment groups, except for non fertilizer (T0) and non nitrogen (T1). The fresh weight of roots were higher quantity than other fertilization treatments in the complete group 55.8 g (T4). The mineral nutrient content ofNa, Mg, Cu and Al of the roots of P. grandiflorum for. duplux from T1 group showed the lowest amount compared to other groups. In addition, P from T2 group, Mn from T3 group and Ca, Fe, Zn from T4 group also exhibited the lowest mineral content compared to other groups respectively.

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Structural and Electrical Properties of Nickel Hydroxide Electrode Prepared by Hydrothermal Synthesis on Nickel Foam (니켈 폼(Ni foam)에 수열 합성법으로 제조한 수산화니켈(Ni(OH)2) 전극의 구조적 및 전기적 특성)

  • Hyunjin Cha;Seokhee Lee;Jeonghwan Park;Young-Guk Son;Donghyun Hwang
    • Journal of the Korean institute of surface engineering
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    • v.56 no.5
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    • pp.320-327
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    • 2023
  • In this study, the nickel hydroxide (Ni(OH)2) electrode for supercapacitor was prepared via hydrothermal method. Based on the nickel (Ni) foam, the electrode does not require any additional binder material or post-processing. Nickel nitrate (Ni(NO3)2) and hexamethylenetetramine (C6H12N4) were used for synthesis, and the synthesis condition was 12 hours at 80 ℃. X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) were used to analyze the structural characteristics of the electrode, and it shown that the nickel hydroxide was successfully prepared after only the one-step hydrothermal synthesis. The electrochemical properties were analyzed through the half-cell test. The prepared electrode shown a pair of oxidation/reduction peaks, indicating that the driving method included the redox reaction on the electrode surface. After the charge/discharge test, the specific capacitance was calculated as the value of 438 F/g at 3 A/g.

Effect of Galvanizing Furnace Temperature on Material Property and Galvanized Surface of Hot Rolled Galvanized Steel

  • Jong Chan Jeong;Jae Joong Kim;Seong Ho Han
    • Corrosion Science and Technology
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    • v.23 no.4
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    • pp.278-282
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    • 2024
  • Recently, hot rolled galvanized steel is widely used in automotive parts. As the paradigm of the automotive market has changed from fossil fuel vehicle to electric vehicle, the automotive industry needs more high-strength steels to reduce weights of automobiles. However, because high-strength steel contains high solute carbon, it is expected to have a risk of stretcher-strain on the surface due to dislocation trapping by solute [C] and [N]. Generally, galvanized steel is supposed to pass through a furnace around the temperature of Zinc pot to increase material temperature. Otherwise, the inhibition layer could not be formed. However, solute carbon and nitrogen are volatile enough to move around the furnace temperature. Moreover, the ratio of ferrite phase and precipitated Fe3C can be variable, resulting in yield point elongation related to the stretcher strain. Furthermore, the quality of the galvanized surface can be affected by a high temperature of the furnace. Although a relatively hot rolled galvanizing line furnace has a lower temperature than an annealing line furnace, it can affect various quality aspects. In other words, this paper aims to determine how these phenomena appear concerning furnace temperature.

The Effect of Iron Content on the Atomic Structure of Alkali Silicate Glasses using Solid-state NMR Spectroscopy (비정질 알칼리 규산염 원자구조의 철 함량 효과에 관한 고체 NMR 분광학 연구)

  • Kim, Hyo-Im;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.4
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    • pp.301-312
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    • 2011
  • The study on the atomic structure of iron-bearing silicate glasses has significant geological implications for both diverse igneous processes on Earth surface and ultra-low velocity zones at the core-mantle boundary. Here, we report experimental results on the effect of iron content on the atomic structure in iron-bearing alkali silicate glasses ($Na_2O-Fe_2O_3-SiO_2$ glasses, up to 16.07 wt% $Fe_2O_3$) using $^{29}Si$ and $^{17}O$ solid-state NMR spectroscopy. $^{29}Si$ spin-lattice ($T_1$) relaxation time for the glasses decreases with increasing iron content due to an enhanced interaction between nuclear spin and unpaired electron in iron. $^{29}Si$ MAS NMR spectra for the glasses show a decrease in signal intensity and an increase in peak width with increasing iron content. However, the heterogeneous peak broa-dening in $^{29}Si$ MAS NMR spectra suggests the heterogeneous distribution of $Q^n$ species around iron in iron-bearing silicate glasses. While nonbridging oxygen ($Na-O-Si$) and bridging oxygen (Si-O-Si) peaks are partially resolved in $^{17}O$ MAS NMR spectrum for iron-free silicate glass, it is difficult to distinguish the oxygen clusters in iron-bearing silicate glass. The Lorentzian peak shape for $^{29}Si$ and $^{17}O$ MAS NMR spectra may reflect life-time broadening due to spin-electron interaction. These results demonstrate that solid-state NMR can be an effective probe of the detailed structure in iron-bearing silicate glasses.