• Proceedings of the Korean Magnestics Society Conference
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• 2001.10a
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• pp.90-91
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• 2001

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.467-471
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• 2011

Spin exchange interactions of $(C_2N_2H_{10})[Fe(HPO_3)F_3]$ were examined by performing a spin dimer analysis based on extended Huckel tight binding method and a mapping analysis based on first principles density functional theory. Spin exchange interactions occur through the super-superexchange paths $J_1$ and $J_2$ in $(C_2N_2H_{10})[Fe(HPO_3)F_3]$. In the super-superexchange path $J_2$ magnetic orbital interactions between eg-block levels are much stronger than those from $t_{2g}$-block levels. Both electronic structure calculations show that the spin exchange interaction through the super-superexchange path $J_2$ is much stronger than that of $J_1$.

• Korean Journal of Materials Research
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• v.16 no.2
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• pp.85-91
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• 2006

The fraction of $\varepsilon\;and\;\gamma$'-iron nitride in compound layer is predicted by x-ray diffraction using direct comparison method. The validity of formulation models was checked by comparing calculated results with metallographic analysis of iron nitride compound layer grown on steel S45C by gas nitriding. The fraction of $\varepsilon$ calculated by the three phase model, porous-$Fe_3N$/ dense-$Fe_3N$/ mixed layer with $Fe_3N\;and\;Fe_4N$, is 80 percent of that analyzed by etching technique. The $\varepsilon$ fraction predicted by mixed layer model is 122 percent of that measured by microscope.

• Journal of the Korean institute of surface engineering
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• v.47 no.6
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• pp.282-286
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• 2014

Wear characteristic of the nitrided SKD61 which is a typical mold material using for the extrusion of Al6061 alloy was investigated. The surface of SKD61 was nitrided by salt bath and plasma processes. The thickness of surface nitride layer was about $8.9{\mu}m{\sim}21.3{\mu}m$. Reciprocating friction wear test conducted using pin on disk type indicated the plasma treatment followed salt bath has a lower friction coefficient and a smaller adhesive wear with Al6061 alloy. That was identified by the $Fe_4N$ which has a better wear resistance than FeN mainly formed by plasma nitriding.

• Proceedings of the Korean Magnestics Society Conference
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• 1999.10a
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• pp.42-43
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• 1999

• Journal of the Korean Magnetics Society
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• v.5 no.5
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• pp.636-640
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• 1995

FeN thin films were deposited on glass by RF diode reactive sputtering. The films were annealed in the air and in vacuum. The film annealed in the air showed sharp decrease of saturation magnetization and change of easy axis direction to hard axis direction and vice versa after $300^{\circ}C$ anneal. The coercivity decreased down to 0.5 Oe after $400^{\circ}C$ anneal. After $450^{\circ}C$ anneal, the film showed ${\varepsilon}-Fe_{2-3}N$ phase. The films annealed in vacuum showed coercivity increase after $300^{\circ}C$ anneal for the film deposited with initial substrate temperature of $35^{\circ}C$ and after $400^{\circ}C$ anneal for the film deposited with initial substrate temperatue of $170^{\circ}C$. These films showed $Fe_{16}N_{2}$ X-ray peaks after $450^{\circ}C$ anneal.

• Journal of the Korean Magnetics Society
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• v.13 no.5
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• pp.187-192
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• 2003

The magnetic and thermal properties of NiFe/[IrMn-Mn]/CoFe with Mn additions have been studied. As-deposited CoFe pinned layers with [IrMn-Mn]layer had dominantly larger exchange biasing field ( $H_{ex}$) and blocking temperature ( $T_{b}$) than those with pure I $r_{22}$M $n_{78}$ used. The $H_{ex}$ and $T_{b}$ improved with 76.8-78.1 vol% Mn, but those of the NiFe/IrMn/CoFe dropped considerably with more addition of 0.6 vol % Mn. The average x-ray diffraction peak ratios of fcc [(111)CoFe, NiFe]/(111)IrM $n_3$ textures for the Mn inserted total vol of 75.5, 77.5, and 79.3% were about 1.4, 0.8, and 0.6, respectively. For the sample without Mn inserted layer, the $H_{ex}$ between IrMn and CoFe layers was almost zero, but it increased to 100 Oe after annealing of 250 $^{\circ}C$. For as-grown two multilayers samples with ultra-thin Mn layers of 77.5 and 78.7 vol %, the $H_{ex}$s were 259 and 150 Oe, respectively. In case of IrMn with 77.5 vol% Mn, the $H_{ex}$ was increased up to 475 Oe at 350 $^{\circ}C$ but decreased to 200 Oe at 450 $^{\circ}C$, respectively. The magnetic properties and thermal stabilities of NiFe/[IrMn-Mn]/CoFe multilayer were enhanced with Mn additions. In applications where higher $H_{ex}$ and $T_{b}$ are required, proper contents of Mn can be used. be used. used.

• KSBB Journal
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• v.18 no.2
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• pp.140-144
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• 2003

The artificial sewage was treated using a vertical flow zeolite-filled reed bed. The artificial sewage was fec into the reed bed for 10 minutes every 6 hours at the hydraulic load 314 L/$m^2$ \ulcorner day. The filtering height of the reed bed was 100 cm and the zeolite mixture was filled in the reed bed. The mixture consisted of the same volume of two types of zeolites ; 0.5~1 mm and 1~3 mm in diameter. Annual average removal efficiency was CO$D_{Cr}$ 95.1%, T-N 49.5%, $NH{_4^+}$-N 99.4% and T-9 56.4%. T-N removal efficiency decreaced remarkably from 73 to 27% with the operating time. Most of T-P was adsorbed in the uper area of the reed bed. The major portion of adsorbed phosphorus was composed of Fe-, Ca- and reductant selubele Fe-P.

• Journal of Soil and Groundwater Environment
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• v.16 no.6
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• pp.19-26
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• 2011

In this research, soil analysis and adsorption were conducted, and compared with the water quality of bank filtration and river in terms of TS, TDS, SS, $NH_4$-N, $NO_3$-N, $NO_2$-N, Fe, Mn, BOD and $KMnO_4$ consumption for the development of bank filtration in Gimhae city. Analysis of soil showed high levels of Fe (470 mg/kg), Mn (80 mg/kg) and $NH_4$-N (15 mg/kg). Also, adsorption coefficient values (k and 1/n) were 0.00159 and 0.8714, respectively. This implies that the adsorption of the soil depends on organic matter. Water qualitiy of the river and the bank filtration revealed that the concentrations of TS and TDS almost didn't change but the concentration of SS decreased 84% through the bank filtration. $NH_4$-N in the bank filtration was detected more than 1 mg/L which might be due to agricultural activities in the research area. $NO_3$-N was close to the detection limit owing to the removal by the adsorption. $KMnO_4$ consumption and BOD of the river were decreased by the bank filtration 250% and 350%, respectively, while Fe and Mn were significantly increased by the bank filtration.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.679-684
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• 2017

The influence of catalytic activity on Fe loading methods over Fe/BEA zeolite catalyst in the simultaneous reduction of $N_2O/NO$ has been studied. The Fe/BEA zeolite catalysts were prepared by ion exchange and impregnation. Catalytic tests were carried out in the selective catalytic reduction using ammonia as a reductant to identify the activity of prepared catalysts. The results show that the ion exchanged catalyst exhibited higher NO and $N_2O$ conversions than the impregnated catalysts did. To investigate the difference in catalytic activity, we performed various analyses such as XRD, $H_2-TPR$, $O_2-TPD$ and XPS. It is considered that the increase in the activity of the ion exchange catalyst is due to improved reducibility and increased oxygen desorption rate. In addition, the ion exchange catalyst was found through the XPS analysis that $Fe^{2+}$, which is related to the catalytic activity, is formed about 1.6 times more than the impregnated catalyst.