• Title/Summary/Keyword: FeMo-co

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Study on the Effect of Austenite Grain Size and Mn Content on Hardenability in Boron-added Low Carbon alloys Steels (보론 첨가 저탄소합금강에서 Mn함량과 오스테나이트 결정입도가 경화능에 미치는 영향에 관한 연구)

  • Huh, U.Y.;Rho, Y.S.;Choi, M.S.;Kim, Y.H.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.3 no.4
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    • pp.23-40
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    • 1990
  • This study has been carried out to investigate into some effects of Mn content with varying amounts and austenite grain size on hardenability in boron-added Fe-C-Cr-Mo alloy systems. (1) Austenite grains have been found to hardly grow in the temperature range of $900^{\circ}C$ to $950^{\circ}C$, whereas they grow rapidly in the temperature range of $975^{\circ}C$ to $1100^{\circ}C$. (2) Austenite grain growth is considerably small with increasing holding time at a given austenitizing temperature and is, in particular, hardly found to occur at a temperature of $900^{\circ}C$. (3) The hardenability improves ramarkably as Mn content is increased at three different austenitizing temperatures $900^{\circ}C$, $1000^{\circ}C$ and $1100^{\circ}C$. (4) The maximum hardenability is obtained from steels A, B and C austenitized at the $900^{\circ}C$, although Mn content is varied in each specimen.

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Effects of NaF evaporation rate on the properties of $CuInSe_2$ thin-film solar cells

  • Park, Sun-Yong;Lee, Eun-U;Lee, Sang-Hwan;Park, Sang-Uk;Jeong, U-Jin;Kim, U-Nam;Jeon, Chan-Uk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.36.2-36.2
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    • 2010
  • A small amount of Na incorporated in $CuInSe_2$ (CIS) absorption layer has become widely accepted as a requirement for efficient polycrystalline CIS solar cells. However, there is ongoing argument on the role of sodium incorporated in the absorber. In this paper, CIS absorption layers have been deposited using the three-stage co-evaporation process on Mo coated non-Alkali glass substrates. The NaF was evaporated during the second-stage with various fluxes. This paper is focusing on differences of micro-structure and composition ratio of the absorber realized with different Na contents and the variation of electrical properties of the cells with the corresponding absorbers. The analytical results of x-ray diffraction (XRD) patterns, field emission scanning electron microscope (FE-SEM), energy dispersive spectroscopy (EDS) and current-voltage characteristics will be discussed to investigate the effect of NaF flux on the CIS absorber formation and its cell performance.

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Characterization of CIGS Solar Cell for Flexible Steel Substrate by Surface Roughness (유연 철강기판 표면조도에 따른 CIGS 태양전지의 특성 분석)

  • Kim, Daesung;Hwang, Moonsick;Kim, Daekyong;Lee, Duckhoon;Kim, Taesung
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.58.1-58.1
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    • 2011
  • CIS(CuInSe2)계 화합물 태양전지는 높은 광흡수계수와 열적 안정성으로 고효율 태양전지 제조가 가능하여 태양전지용 광흡수층으로 매우 이상적이다. 미국 NREL에서는 이러한 CIGS 태양전지를 Co-evaporation 방법으로 제조 20%이상의 에너지 변환 효율을 달성하였다고 보고하였다. CIGS 태양전지의 경우 기존의 유리 기판 대신 유연한 철강 기판을 사용해 태양 전지를 flexible하게 제조 할 수 있다는 장점이 있다. 이러한 flexible 태양전지의 경우 기존의 rigid 태양전지의 적용분야 뿐만 아니라 BIPV, 선박, 장난감, 군용, 자동차등 더욱 더 많은 분야에 활용이 가능하다. 본 연구에서는 기존의 rigid한 기판인 soda lime glass와 flexible 기판인 stainless steel 기판으로 소자를 제조하여 효율을 비교 분석 및 stainless steel 기판의 표면 처리 방법에 따라서 표면 조도의 특성을 분석하여 stainless steel 기판별 효율 특성도 비교 분석 하였다. 후면전극으로는 약 $1{\mu}m$의 Mo를 DC Sputtering 방법을 이용하여 증착하였고, CIGS 광흡수층은 약 $2.5{\mu}m$의 두께로 미국의 NREL과 같은 3 stage 방식을 이용하여 광흡수층을 Co-Evaporation 방법으로 제조하였고, 버퍼층인CdS는 약 50nm의 두께로 CBD 방법으로 제조 하였으며, 창층인 ZnO는 약 500nm 두께로 RF Sputtering 방법으로 제조 하였고, 마지막으로 약 $1{\mu}m$ 두께의 Al 전면전극은 Thermal Evaporation 방법으로 제조 하였다. 소자의 물리적, 전기적 특성을 분석하기위해 FE-SEM, AFM, Solar Cell Simulator 분석을 실시하였다.

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Studies on Geology and Mineral Resources of the Okcheon Belts -Mineralization in the Vicinity of the Muamsa Granite Stock- (옥천대(沃川帶)의 지질(地質) 및 광물자원(鑛物資源)에 관(關)한 연구(硏究) -무암사화강암(務岩寺花崗岩) 주위에서의 광화작용(鑛化作用)에 관(關)하여-)

  • Yun, Suckew;Kim, Kyu Han;Woo, Jong Sang
    • Economic and Environmental Geology
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    • v.19 no.spc
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    • pp.3-17
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    • 1986
  • Hundred mineral deposits including W-Mo, Pb-Zn-Cu, fluorite and talc occur in the Cambre-Ordovician limestone contacting with the Cretaceous Muamsa and Wolak granitoids in the Susanri-Hwanggangri mineralized zone. In most mineral deposits characterized by metasomatic replacement, skarn and hydrothermal vein types, two distinct tendencies were found as W-Mo mineralization in or/and near granitoid batholith and ($Pb-Zn-Cu(CaF_2)$) mineralization which is gradually increased toward the batholith. W-Mo veins of extensive vein system occupy northly striking fractures whilst $Pb-Zn-Cu-CaF_2$ veins strike northeast or northwest. In this work, three representative lead-zinc-copper deposits choosing the Dangdu, Useog and Eoksu mines were dealt with in detail. Skarn ore bodies in the Dangdu mine were grouped into early diopside rich clinopyoxene-garnet, barren skarn and ore bearing late hedenbergite rich clinopyroxene-garnet skarn. Temperature and $X_{CO_2}$, obtained from hedenbergite-andradite-calcite-quartz mineral equilibria in the Dangdu ore deposits were $580{\sim}650^{\circ}C$ and 0.15~0.3, respectively. Fluid inclusien evidence in the Useog mine indicates that main stage mineralization temperature ranges from 224 to $389^{\circ}C$ with a salinity of 2~17 equivalent wt. percent NaCl. Sphalerites from the Dangdu and Useog mines have 16~17.7 mole percent in FeS which is relatively consistent to those of some other lend-zinc ore deposits in South Korea. Filling tcmjCerature of fluid inclusion frem the Eoksu mine shows deposition of ore within the temperature ranges from 237 to $347^{\circ}C$ and within the salinity ranges from 2.6 to 10.77 equivalent wt. percent NaCl.

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Electrochemical Properties of 0.3Li2MnO3·0.7LiMn0.55Ni0.30Co0.15O2 Electrode Containing VGCF for Lithium Ion Battery

  • Kim, Jeong-Min;Jeong, Minchan;Jin, Bong-Soo;Kim, Hyun-Soo
    • Journal of Electrochemical Science and Technology
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    • v.5 no.1
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    • pp.32-36
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    • 2014
  • The $0.3Li_2MnO_3{\cdot}0.7LiMn_{0.55}Ni_{0.30}Co_{0.15}O_2$ cathode material was prepared via a co-precipitation method. The vapor grown carbon fiber (VGCF) was used as a conductive material and its effects on electrochemical properties of the $0.3Li_2MnO_3{\cdot}0.7LiMn_{0.55}Ni_{0.30}Co_{0.15}O_2$ cathode material were investigated. From the XRD pattern, the typical complex layered structure was confirmed and a solid solution between $Li_2MnO_3$ and $LiMO_2$ (M = Ni, Co and Mn) was formed without any secondary phases. The VGCF was properly distributed between cathode materials and conductive sources by a FE-SEM. In voltage profiles, the electrode with VGCF showed higher discharge capacity than the pristine electrode. At a 5C rate, 146 mAh/g was obtained compared with 232 mAh/g at initial discharge in the electrode with VGCF. Furthermore, the impedance of the electrode with VGCF did not changed much around $9-10{\Omega}$ while the pristine electrode increased from 21.5${\Omega}$ to $46.3{\Omega}$ after the $30^{th}$ charge/discharge cycling.

Heavy Metal Contents of the Surface Water and Stream Sedi-ments from the Talc Mine Area, Western Part of Chungneam (충남 서부 활석광산 주변의 지표수 및 하상 퇴적물의 중금속 함량)

  • 송석환;김명희;민일식
    • Korean Journal of Environment and Ecology
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    • v.15 no.2
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    • pp.139-152
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    • 2001
  • 충남 서부 활석광산 주변의 수계에 대한 원소 함량특성에 대해 알아보고자 대흥 및 광천광산에 대해 수질 및 하상 퇴적물 시료와 함께 광산 주변 토양 및 모암 시료를 채취, 비교하였다. 대흥지역 퇴적물은 대부분 원소에서 SP가 GN에 비해 높았는데 이는 퇴적물 내 유색 및 무색광물 함량 차이로 판단된다. 절대 함량 비교에서 광물 결정구조 내 쉽게 Mg와 치환하는 원소는 낮은비율을, Fe와 치환하는 원소는 높은 비율을 보였는데 이는 퇴적물 내 주 구성광물내 원소 치환특성을 반영하기 때문으로 판단된다. 절대 함량의 감소 순서와 타원소들과 높은 상관관계(>0.85)의 빈도를 보이는 원소들 사이의 차이는 퇴적물 화학조성에 이차광물과 비정질 광물등의 조성도 반영되었음을 암시한다. 대흥지역 지표수는 대부분 원소에서 MSP가 SP와 GN의 중간값을, MSG는 LGN과 MSP의 중간값을 조여 수계의 혼합특성을반영하는 것으로 판단된다. 절대 함량관계에서는 SP는 GW1과 유사했고, GN은 LGN과 유사했으며, 절대함량은(Mg, Fe), (As, Sc), (Mo, V, Se) 순서로 낮아졌다. 광천지역은 갱내수가 천부 지하수에 비해 대부분 원소에서 높은 함량을 보였는데, 이는 갱내수가 더욱더 많은 물-암석반응을 거친 때문으로 판단된다. 절대 함량은 Mg, Br, Fe, (Sc, Cr), (An, Ni, V)순서로 감소하였다. 갱냉수의 지역간 원소 함량 차이는 사문암화가 우세한 광천지역과 활석화가 우세한 대흥지역 모암들 사이의물-암석 상화반응의 차이를 보여주는 것으로 판단된다 두 지역의 상부 토양 및 모암 조성에서 SP가 GN에 비해 높은 Mg 비, Ni, Cr, Co 등 함량을 보였는데, 이는 사문암 지역 내 Mg, Ni, Cr 등이 풍부한 광물들 탓으로 판단된다. 퇴적물과 수질 사이에서는 함량 경향을 뚜렷하지 않았고 원소에 따라 서로 다른 힘량 차이를 보였는데, 이는 퇴적물 원소 함량이 수계 조성을 반영하는 것이 아님을 나타낸다. 상부-토양-암석-수계의 조성관계에서 대흥지역 지표수 중 SP 조성이, 광천지역은 갱냉수가 지하수의 조성에 가까웠다.

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On-site Investigation of Hazardous Substances in Floor Dust of Several Primary Schools (일부 초등학교 바닥 먼지내 포함하고 있는 유해물질 성분에 대한 현장 평가)

  • Kim, Ki Youn;Kim, Hyeon Tae;Lee, Kwon Seob
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.4
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    • pp.478-483
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    • 2014
  • Objectives: The main objective of this study is to assess the levels of hazardous substances in floor dust in primary schools located in the city of Busan in Korea. Materials and Methods: An on-site investigation of three primary schools was performed between April and May 2013. The hazardous substances measured in this study were 14 heavy metals (Cu, Fe, Pb, Mn, Ni, Zn, Cr, Cd, As, Al, Sn, Co, Mo and Si) and the biological agents were bacteria, fungi and endotoxin). Results: Among the heavy metals, Cd, Co, Pb and Cr were not detected in the floor dust from the three primary schools. The mean levels of other heavy metals were as follows: $20({\pm}10)ng/cm^2$ for As, $30({\pm}20)ng/cm^2$ for Al, $5({\pm}4)ng/cm^2$ for Sn, $20({\pm}20)ng/cm^2$ for Mo, $1,340({\pm}620)ng/cm^2$ for Si, $110({\pm}100)ng/cm^2$ for Cu, $240({\pm}50)ng/cm^2$ for Fe, $30({\pm}30)ng/cm^2$ for Mn, $10({\pm}10)ng/cm^2$ for Ni, and $50({\pm}30)ng/cm^2$ for Zn. It was found that mean concentrations of bacteria, fungi and endotoxin in the floor dust of primary schools were $4.7{\time}10^7({\pm}2.2{\time}10^7)cfu/cm^2$, $6.3{\time}10^6({\pm}6.4{\time}10^6)cfu/cm^2$, and $8,140({\pm}5,801)EU/cm^2$, respectively. The predominant species identified in the floor dust of the primary schools were Pseudomonas spp. for bacteria and Penicillium spp.,Cladosporidium spp.,and Aspergillus spp. for fungi, which would be somewhat similar to the microbial distribution pattern of other general environments. Conclusions: Based on the results obtained from this study, the levels of heavy metals, microbes and endotoxin distributed in the floor dust of primary school were higher than those reported for other general facilities. Thus, preventive measures should be prepared for the health care of children.

Effect of Hot Spring Water on Dough Fermentation and Quality of Bread (온천수가 반죽의 발효와 품질에 미치는 영향)

  • 이예경;김순동
    • Journal of the East Asian Society of Dietary Life
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    • v.13 no.1
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    • pp.56-63
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    • 2003
  • The dough fermentation and the quality of bread prepared with different kinds of water such as distilled water, tap water and diluted hot spring water(SW) from Gyungsan Sipan hot spring were investigated. Content of total soluble solid in the hot spring water was 8,765 ppm and contents of Na, Ca, Mg and K as major elements was 2,296, 287, 65 and 8 ppm, respectively. Content of Fe, Cu, Co, F, Zn, Al, S, Mo, Se and Si as minor elements was in the range of 0.002~5.2 ppm. The pH(6.95~7.68) of the dough prepared with diluted hot spring water(I, 55 times; II, 4 times; III, 2 times) was higher than that of distilled water. The dough volume after the 1st fermentation was expecially lower in the III, but the volume of the dough prepared with III adjusted pH to 5.5 was higher than that of the control. The hardness and the strength were higher than those of the control, but the scores were love. than those of the control in case of pH adjustment(pH 5.5). The cohesiveness was also lower than that of the control in the bread with diluted hot spring water. Softness and stickiness of the bread(III) were hisher than those of the control. But overall acceptability was the highest in the II.

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The Medium Optimization through Continuous Culture of an Methanol Utilizing Bacterium for SCP Production (SCP 생산용 메탄올 자화균주의 연속배양에 의한 배지 최적화)

  • 김창호;김태진홍석인
    • KSBB Journal
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    • v.5 no.4
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    • pp.355-363
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    • 1990
  • Methanol-utilizing bacterium isolated from sewage samples in Seoul showed optimal temperature and pH of $33^{\circ}C$ and 7.1 for growth, respectively. The maximum specific growth rate was $0.42hr^{-1}$. The minimum medium composition was reconstituted depending on the surplus and the deficit of each component in the basal medium at steady state. The optimal composition was given as(g/l); Methanol 40, $(NH_4)_2\;SO_42, \;KH_2PO_4\;1.5, \;K_2HPO_4\;0.2, \;H_3PO_4\;0.79, \;Na_2HPO_4{\cdot}12H_2O\;0.15, \;MgSO_4{\cdot}7H_2O\;1.5, \;FeSO_4{\cdot}7H_2O\;0.034, \;MnSO_4{\cdot}4H_2O\;0.005, \;CuSO_4{\cdot}5H_2O\;0.0027, \;CaCl_2{\cdot}2H_2O\;0.25, \;ZnSO_4{\cdot}7H_2O\;0.007, \;(NH_4)_6\;Mo_7O_{24}{\cdot}4H_2O\;0.00048, \;H_3BO_3\;0.00068, \;CoCl_2\; 0.00024$ Under the continuous culture with optimum medium the maximum cell productivity was 3.8g/1/hr at dilution rate $0.23hr^{-1}$. Maximum cell concentration and its protein content were 19.5g/l and 70% at dilution rate of $0.1hr^{-1}$, respectively.

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Sedimentary type Non-Metallic Mineral Potential Analysis using GIS and Weight of Evidence Model in the Gangreung Area (지리정보시스템(GIS) 및 Weight of Evidence 기법을 이용한 강릉지역의 퇴적기원의 비금속 광상부존가능성 분석)

  • Lee Sa-Ro;Oh Hyun-Joo;Min Kyung-Duck
    • Spatial Information Research
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    • v.14 no.1 s.36
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    • pp.129-150
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    • 2006
  • Mineral potential mapping is an important procedure in mineral resource assessment. The purpose of this study is to analyze mineral potential using weight of evidence model and a Geographic Information System (GIS) environment to identify areas that have not been subjected to the same degree of exploration. For this, a variety of spatial geological data were compiled, evaluated and integrated to produce a map of potential mineral in the Gangreung area, Korea. for this, a spatial database considering mineral deposit, topographic, geologic, geophysical and geochemical data was constructed for the study area using a GIS. The used mineral deposits were non-metallic(Kaolin, Porcelainstone, Silicastone, Mica, Nephrite, Limestone and Pyrophyllite) deposits of sedimentary type. The factors relating to mineral deposits were the geological data such as lithology and fault structure, geochemical data, including the abundance of Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Si, Sr, V, Zn, $Cl^-,\;F^-,\;{PO_4}^{3-},\;{NO_2}^-,\;{NO_3}^-,\;SO_{42-}$, Eh, PH and conductivity and geophysical data, including the Bouguer and magnetic anomalies. These factors were used with weight of evidence model to analyze mineral potential. Probability models using the weight of evidence were applied to extract the relationship between mineral deposits and related factors, and the ratio were calculated. Then the potential indices were calculated by summation of the likelihood ratio and mineral potential maps were constructed from Geographic Information System (GIS). The mineral potential maps were then verified by comparison with the known mineral deposit areas. The result showed the 85.66% in prediction accuracy.

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