• Title/Summary/Keyword: FeMo-co

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Spark Plasma Sintering of Fe-Ni-Cu-Mo-C Low Alloy Steel Powder

  • Nguyen, Hong-Hai;Nguyen, Minh-Thuyet;Kim, Won Joo;Kim, Ho Yoon;Park, Sung Gye;Kim, Jin-Chun
    • Journal of Powder Materials
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    • v.23 no.3
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    • pp.207-212
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    • 2016
  • In this study, Fe-Cu-Ni-Mo-C low alloy steel powder is consolidated by spark plasma sintering (SPS) process. The internal structure and the surface fracture behavior are studied using field-emission scanning electron microscopy and optical microscopy techniques. The bulk samples are polished and etched in order to observe the internal structure. The sample sintered at $900^{\circ}C$ with holding time of 10 minutes achieves nearly full density of 98.9% while the density of the as-received conventionally sintered product is 90.3%. The fracture microstructures indicate that the sample prepared at $900^{\circ}C$ by the SPS process is hard to break out because of the presence of both grain boundaries and internal particle fractures. Moreover, the lamellar pearlite structure is also observed in this sample. The samples sintered at 1000 and $1100^{\circ}C$ exhibit a large number of tiny particles and pores due to the melting of Cu and aggregation of the alloy elements during the SPS process. The highest hardness value of 296.52 HV is observed for the sample sintered at $900^{\circ}C$ with holding time of 10 minutes.

Geochemical Behavior, Dispersion and Enrichment of Environmental Toxic Elements in Coaly Metapelites and Stream Sediments at the Hoenam Area, up the Taecheong Lake, Korea (대청호 상류, 회남일대에 분포하는 탄질 변성니질암과 하상 퇴적물의 환경유해원소에 관한 지화학적 거동, 분산 및 부화)

  • Lee, Chan Hee;Lee, Hyun Koo
    • Economic and Environmental Geology
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    • v.30 no.3
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    • pp.209-222
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    • 1997
  • The Hoenam area, up the Taecheong lake, composed mainly of low grade coal-bearing metapelites within the Ogcheon Supergroup. These coal formations are developed discontinuously several hundred meters and swelling from 10 to 300 cm along the host metapelites. Although the formations have been mined for coal, but already mined out, and the formations were higher content (mean value of 42 samples) of environmental toxic elements as As (13 ppm). Ba (1.81 wt. %), Cd (2 ppm), Cr (188 ppm), Cu (87 ppm), Mo (214 ppm), Pb (25 ppm), Sb (3 ppm), Se (12 ppm), U (55 ppm), V (2124 ppm) and Zn (234 ppm) than the host metapelites and the NASC. The Al, Ti, Mg, K and Na contents in stream sediments derived from the Hando and Bugook mine area were highly concentrations than the samples from the Samseongjeil mine area. The mean value (wt. %) of Fe (10.07), Mn (0.15), Ca (0.84), P (0.18) and Ba (0.77) influenced by the Samseongjeil mine were higher than the other mine drainage sediments. The mean content (ppm) of environmental toxic elements in drainage sediments from the Samseongjeil mine were taken As (2083), Cu (447), Mo (202), Ni (720), Pb (42), U (250), V (1070) and Zn (2632), which are extremely high concentrations against NASC and EPA. Characteristics of elemental behavior and dispersion of the all toxic elements are the same as increased with increasing U, V, and Cu. Rare earth elements in the sediments are enriched with LREE (La, Ce and Nd) from the drainage on strong concentration of toxic elements. The pH of stream water is neutral, but pH of the sediments ranged from 4.92 to 6.93 (mean 6.22), those are slightly acid in the Hando mine area. Major elements in the host rocks at the Hoenam area are mostly depleted especially Ca, excepting Ti and Ba, normalized with NASC. The sediments were highly enriched of Ti, Fe, Mg, Mn and Ba, but depleted of Al, K, Ca, Na and P on the basis of host rocks and NASC. Minor and environmental toxic elements in the host rocks were strongly enriched all elements (As, Cd, Mo, Se, D, V and Zn), excepting Co, Ni and Sr. Enrichment index (mean value) about toxic elements (As, Cr, Cu, Fe, Ni, Pb and Zn) of the sediments in this area have taken 41.35 (Hando mine drainage; 2.73, Samseongjeil mine drainage; 113.14 and Bugook mine drainage; 8.19), those are seriously contaminated by environmental toxic elements.

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Synthesis of Sr-Ferrite by a Molten Salt Flux and Its Magnetic Properties (염을 이용한 Sr 페라이트의 분말합성과 그의 자성특성)

  • Kim, Jung-Sik;Kim, Si-Dong
    • Journal of the Korean Ceramic Society
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    • v.42 no.10 s.281
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    • pp.672-677
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    • 2005
  • In this study we prepared the Sr-ferrite powders and magnet by a molten salt method using the (NaCl+KCl) salt mixture. Starting materials of $Fe_{2}$$O_{3}$ and Sr$Co_{3}$ were mixed as the molar ratio of 5.70:1, and 0.08 mol$ \% $ $Al_{2}$$O_{3}$, 0.10 mo1$ \% $ Si$O_{2}$ and 0.12 mo1$ \% $ CaO were added as additives. Sr-ferrite powders synthesized at the reaction temperatures of 800$\∼$1200$ ^{\circ}C $ showed the typical M-type hexagonal ferrite phase, and hexagonal plate-like morphology with uniform distribution of 1$\∼$3 $\mu$m particle size. The bulk density of the sintered Sr-ferrite magnet prepared with powders by the molten salt method showed the maximum density of 4.82 g/$cm^{3}$ at the sintering temperature of 1200$^{\circ}C $. The maxima of remanent flux density (Br, 45 emu/g) and coercive force (iHc, 3.75 kOe) occurred at the sintering temperatures of 1150$ ^{\circ}C$ and 1200$^{\circ}C $.

Geology and Mineral Resources of Colombia (콜롬비아 지질 및 광물자원 현황)

  • Koh, Sang-Mo;Lee, Gill-Gae;You, Byoung-Woon
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.3
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    • pp.245-252
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    • 2011
  • 콜롬비아는 안데스 산맥의 북단에 위치하며 NS 방향의 단층대를 기준으로 지질 환경의 차이가 크다. 단층대를 기준으로 동부지역은 원생대 변성암류와 이를 피복하는 고생대 변성퇴적암류가 주로 분포하며, 서부 지역은 고생대 퇴적암류, 중생대 화성암류, 제 3 기 화산양류 및 퇴적암류가 주로 분포한다. 지화학이상대는 6개 그룹으로 분류되며, 철 (Fe), 귀금속(Au, Ag, Pt), 기초금속(Cu, Pb, Zn), 희유금속(Sn, Cr, Co, Mn, Mo, Ni, Nb, W, V, Mg, Ti, Be, REE, Ga, Zr, Hf, Se, Te, Ta, Cd, In, Li 등) 빛 핵원료자원인 U 이상대로 구성된다. 콜롬비아의 주요 부존자원은 석탄, 니켈, 금 및 에메랄드이다. 에메랄드, 석탄 및 니켈은 세계적인 매장규모와 생산량을 보인다. 콜롬비아는 탐사가 거의 수행되지 않은 지역이 전 국토의 49%에 달해 광물부존 잠재성은 현재보다 크게 높을 것으로 보인다. 따라서 최근 콜롬비아와의 광물자원 협력이 강화되고 있는 시점에서 미탐사 지역을 대상한 공동탐사를 지화학 이상대가 확인된 지역을 중심으로 수행하여 신규광체를 확보하고, 광물자원 협력을 강화함으로써 공동개발 여건을 마련할 필요가 있다고 판단된다.

The Evaluation of Trace Minerals Levels of Pasture Soils and Forages in Jeju (제주지역 목장 토양 및 조사료 자원의 미량광물질 함량 평가)

  • Lee, Chong-Eon;Park, Myung-Hee;Park, Nam-Keon;Park, Hyung-Soo;Oh, Woon-Yong
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.27 no.1
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    • pp.29-36
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    • 2007
  • A study was conducted to determine the trace minerals (Cu, Fe, Cd, Zn, Mo, Se, Mn, Cr, Co, Ni) levels in pasture soils and forages collected in Jeju area. Chemical characteristics and total or soluble trace minerals levels in 187 pasture soil samples (76 very dark brown and 111 black soils) were measured. Total trace minerals contents in hay samples of 60 Italian ryegrass, alfalfa and mixture grasses each were assessed. The pasture soils of Jeju were characterized to have low pH (5.1) and to contain low levels of available $P_2O_5$ (20.5 mg/kg) and exchangeable Ca, Mg, K, Na (2.6, 0.9, 0.5, 0.2 cmol+/kg, respectively) when comparing to upland soils of Jeju or Korean mainland. All trace elements in total or soluble analysis of pasture soils were detected, and there was a big difference between total and soluble levels. The pasture soils tended to have the higher total Fe, Mn, Ni and Zn contents. Cr in all forages was not detected, but other trace minerals levels showed normal range. The hay samples of Italian ryegrass and mixture grasses produced in Jeju tended to contain higher Mn (105 vs 23 mg/kg) and lower Mo (2.7 vs 4.9 mg/kg) than those of alfalfa hay imported from USA. Results show that trace minerals of pasture soils and forages in Jeju seem to be not deficient, indicating that supplementation of some trace minerals are not always necessary in diets for grazing animals and should be done after careful evaluation of diets with regard to concentrations and biological availability of essential elements.

Design Validation and Improvement of District Heating Pipe Using FE Simulation (유한요소 시뮬레이션을 통한 지역난방열배관 특성 평가 및 강화이형관의 제안)

  • Kim, Joo-Yong;Kim, Ho-Bum;Ko, Hyun-Il;An, Yong-Mo;Cho, Chong-Du
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.4
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    • pp.337-345
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    • 2009
  • This paper investigates the reliability of district heating pipes at thermo-elastic fatigue loading. District heating pipes, subjected to $120^{\circ}C$ and $16kg_f/cm^2$ due to water distributing service through inside the pipes, should endure long term cyclic thermal-mechanical loadings. The heating pipes are the co-centric tubes of steel pipe, poly urethane(PUR) insulator, and high density poly ethylene(HDPE) case. On installation, foam pad is externally wrapped for accommodating stress reduction near the bend sections of pipes. However, there have been frequent reports on the failures of bend sections in the middle of long term service. This study scrutinizes the observed failures near the bend sections through applying the finite element methods. Specially in this study, heating pipes are studied on the influence of foam padding on failures and proposed new designs for reinforced bend without foam pad.

Screening of Anti-thrombotic Activity of Herbal Extracts in Ferric Chloride-induced Thrombosis Model (경동맥 혈전 유발 동물모델을 이용한 한약재 추출물의 효능 검색)

  • Park, In Sil;Lee, Ki Mo;Lee, In Sun;Han, Jae Il;Jeon, Won Kyung
    • The Korea Journal of Herbology
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    • v.28 no.5
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    • pp.33-38
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    • 2013
  • Objectives : The aim of this study was to examine anti-thrombotic effect of traditional herbal extracts in a rat model of ferric chloride ($FeCl_3$)-induced carotid arterial thrombosis. Methods : Thirty minutes prior to a 35% $FeCl_3$ application, Sprague Dawley(SD) rats were injected with the 10 types of traditional herbal extracts (100mg/kg, intraperitoneal injection), respectively. The effect of these herbal extracts was examined for time to occlusion(TTO) using the Laser doppler flow meter and measured for thrombus weight (TW) in $FeCl_3$-induced thrombosis model. Results : In the TTO, Salvia miltiorrhiza (Sm, $2.30{\pm}0.28$ min, p<0.001) and Santalum album (Sa, $2.19{\pm}0.19$ min, p<0.001) showed significantly delayed TTO more than twice compared with Saline-treated group. Cnidium officinale (Co), Psoralea corylifolia (Pc), Scutellatia baicalensis (Sba), Panax notoginseng (Pn), Angelica tenuissima (At), Scrophularia buergeriana (Sbu), Rhus verniciflua (Rv) and Picrasma quassioides (Pq), except for Rhus verniciflua (Rv) also meaningfully impeded TTO more than one fold. In addition, Salvia miltiorrhiza, Santalum album, Cnidium officinale, Psoralea corylifolia and Scutellatia baicalensis significantly reduced TW more than 10% compared with Saline-treated group. Especially, Salvia miltiorrhiza and Santalum album showed the most excellent anti-thrombotic effect among the 10 herbal extracts tested on the restoration of altered TTO and TW. Conclusions : These results suggest that Sm and Sa extracts have outstanding anti-thrombotic effect in $FeCl_3$-induced thrombosis model and is potentially useful as herbal medicines for the treatment and prevention of thrombosis.

Chlorella 대량 배양을 위한 농업용 비료에 trace element의 첨가 효과

  • 배진희;이계안;허성범
    • Proceedings of the Korean Aquaculture Society Conference
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    • 2003.10a
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    • pp.88-89
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    • 2003
  • Rotifer의 먹이 생물로 이용되는 Chlorella의 대량 배양에는 농업용 비료가 널리 이용되고 있다. 그러나 농업용 비료만을 사용할 경우 f/2배지에 비해 성장이 낮은 단점이 있다. 따라서 본 연구는 농업용 비료 배지에 여러 가지 미량 성분을 첨가하여 그 성장 변화를 측정하고, 고밀도 대량 배양에 필요한 미량 원소 성분을 파악하고자 하였다. 먼저 Chlorella의 대량 배양에 이용되는 농업용 비료 배지(복합, 요소비료)에 실내 배양에 주로 이용되는 f/2배지의 trace element 성분 중 코발트(Co), 구리(Cu), 아연(Zn) 및 몰리브덴(Mo)를 f/2배지의 함량을 기준으로 각각 0.5, 1.0, 1.5 및 2.0배로 첨가하여 $25^{\circ}C$, 5,000 lux 연속조명, 15$\textperthousand$에서 배양한 결과 각 미량 원소의 첨가 함량이 높을수록 Chlorella의 성장은 높게 나타났다. 전체 실험구 중에서 아연 2.0배, 구리 2.0배를 첨가한 비료 배지에서 S.G.R.이 각각 0.3598, 0.3599의 성장을 나타내었으며, 아연과 구리 성분을 첨가한 Chlorella에서 높은 성장률을 보였다. 위의 실험에서 첨가효과가 좋은 Cu와 Zn 2.0배와 철(Fe)과 망간(Mn)을 같은 비율(0.5~2.0배)로, 다시 배양한 결과, Cu 2.0배와 Zn 2.0배는 S.G.R.이 각각 0.6283과 0.6231로 가장 높았으며, Fe 2.0배, Mn 2.0배와 1.5배에서 S.G.R이 각각 0.6210, 0.6200, 0.6183의 높은 성장률을 나타내었다. 위의 실험에서 농업용 비료에 첨가된 모든 trace element 중에서 가장 좋은 성장을 나타낸 구리(Cu) 성분의 정확한 공급 농도를 파악하기 위하여 농업용 비료에 2, 3, 4 및 5배를 첨가하여 $25^{\circ}C$, 5,000 lux, 15$\textperthousand$에서 배양한 결과, S.G.R.이 CU 함량을 3배로 첨가하였을 경우 2716$\times$$10^4$cells/$m\ell$로 가장 높은 세포 밀도를 나타내었다. 또한 5종의 trace element (Fe, Mn, Zn, Cu, Co)를 혼합하여 비료 배지(1.25배)에 첨가하여 미량 원소간의 상호 작용에 대해서 알아 본 결과, Fe와 Mn 두가지 성분만을 농업용 비료 배지에 혼합하였을 경우 세포수가 2720$\times$$10^4$cells/$m\ell$로서 높은 성장을 나타내었다. 다음으로 Fe, Mn, Zn 및 Cu 4종을 모두 혼합하여 첨가한 실험구가 2608$\times$$10^4$ cells/$m\ell$ 높은 세포 밀도를 나타내었다. 이러한 결과로서 옥외에서 농업용 비료배지에 구리(Cu, f/2배지 기준 3.0배)성분을 첨가함으로써 Chlorella의 성장을 효율적으로 향상시킬 수 있을 것으로 판단된다.

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