• 한국재료학회:학술대회논문집
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• 한국재료학회 1997년도 한국재료학회 춘계학술발표회
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• pp.39-39
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• 1997

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2008년도 Asian Magnetics Conference
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• pp.193.2-193.2
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• 2008

• 한국재료학회지
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• 제4권5호
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• pp.535-540
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• 1994

Thin film magnet was fabricated by radio frequency magnetron sputtering using $Nd_13/(Fe.Co)_{70}B_{17}$ alloy target and magnetic properties were investigated according to sputtering conditions from the metallurgical point of view. we could obtain the best preferred orientation of $Nd_2Fe_{14}B$ phase at substrate temperatures between $450^{\circ}C$ and $460^{\circ}C$ with the input power 150W, and thin films had the anisotropic magnetic properties. But, as the thickness of thin film increased, the c-axis orientation gradually tended to be disordered and magnetic properties also become isotropic. Just like Nd-Fe-B meltspun ribbon, the microstructure of thin film magnet was consisted of very find cell shaped $Nd_2Fe_{14}B$ phase and the second phase along grain boundary. While, domain structure showed maze patterns whose magnetic easy axis was was perpendicular to film plane of thin film. It was concluded from these results that the perpendicualr anisotropy in magnetization was attributed to the perpendicular alignment of very find $Nd_2Fe_{14}B$ grains in thin film.

• 열처리공학회지
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• 제37권1호
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• pp.9-15
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• 2024

Nd-Fe-B permanent magnets have been utilized on various industrial fields such as electric vehicles, generator, robots with actuator, etc, due to their outstanding magnetic properties even 10 times better than conventional magnets. Recently, there are many researches that report magnetic properties improved by controlling microstructure through adjusting alloying elements or conducting various processing. Especially, post-sintering annealing (PSA) can significantly improve the coercivity by modifying the distribution and morphology of Nd-rich phase which formed at grain boundaries. In this study, Nd-Fe-B sintered magnets were subjected to primary heat treatment followed by secondary heat treatment at 460℃, 500℃, and 540℃ to investigate the changes in microstructure and magnetic properties with the secondary heat treatment temperature. EBSD analysis was conducted to compare anisotropic characteristics. Through the SEM and TEM observation for analyzing the morphology and distribution of Nd-rich phase, we investigated the relationship between microstructure and magnetic properties of sintered Nd-Fe-B magnets.

• 한국분말재료학회지
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• 제23권4호
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• pp.282-286
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• 2016

A sintered body of $TiB_2$-reinforced iron matrix composite ($Fe-TiB_2$) is fabricated by pressureless-sintering of a mixture of titanium hydride ($TiH_2$) and iron boride (FeB) powders. The powder mixture is prepared in a planetary ball-mill at 700 rpm for 3 h and then pressurelessly sintered at 1300, 1350 and $1400^{\circ}C$ for 0-2 h. The optimal sintering temperature for high densities (above 95% relative density) is between 1350 and $1400^{\circ}C$, where the holding time can be varied from 0.25 to 2 h. A maximum relative density of 96.0% is obtained from the ($FeB+TiH_2$) powder compacts sintered at $1400^{\circ}C$ for 2 h. Sintered compacts have two main phases of Fe and $TiB_2$ along with traces of TiB, which seems to be formed through the reaction of TiB2 formed at lower temperatures during the heating stage with the excess Ti that is intentionally added to complete the reaction for $TiB_2$ formation. Nearly fully densified sintered compacts show a homogeneous microstructure composed of fine $TiB_2$ particulates with submicron sizes and an Fe-matrix. A maximum hardness of 71.2 HRC is obtained from the specimen sintered at $1400^{\circ}C$ for 0.5 h, which is nearly equivalent to the HRC of conventional WC-Co hardmetals containing 20 wt% Co.

• 대한치과보철학회지
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• 제44권5호
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• pp.628-641
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• 2006

Statement of problem: Dental magnetic materials have been applied to removable prosthetic appliances, maxillofacial prostheses, obturator and dental implant but they still have some problems such as low corrosion resistance in oral environments. Purpose: To increase the corrosion resistance of dental magnetic materials, surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels. Materials and methods : Surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels, and then three kinds of electrochemical corrosion test were performed in 0.9% NaCl solution; potentiodynamic, potentiostatic, and electrochemical impedance test. From this study, corrosion behavior, amount of elements released, mean average surface roughness values, the changing of retention force, and magnetic force values were measured comparing with control group of non-coated magnetic materials. Results: The values of surface roughness of TiN coated Sm-Co and TiN coated Nd-Fe-B based magnetic materials were lower than those of non coated Sm-Co and Nd-Fe-B alloy. From results of potentiodynamic test, the passive current density of TiN coated Sm-Co alloy were smaller than those of TiN coated Nd-Fe-B alloy and non coated alloys in 0.9% NaCl solution. From results of potentiostatic and electrochemical impedance test, the surface stability of the TiN coated Sm-Co alloy was more drastically increased than that of the TiN coated Nd-Fe-B alloy and non-coated alloy. The retention and magnetic force after and before corrosion test did not change in the case of TiN coated magnetic alloy sealed with stainless steel. Conclusion: It is considered that the corrosion problem and improvement for surface stability of dental magnetic materials could be solved by ion plating with TiN on the surface of dental magnetic materials and by sealing with stainless steels.

• 한국분말재료학회지
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• 제22권3호
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• pp.208-215
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• 2015

Fe-TiC composite powders were fabricated by planetary ball mill processing. Two kinds of powder mixtures were prepared from the starting materials of (a) (Fe, TiC) powders and (b) (Fe, $TiH_2$, Carbon) powders, respectively. Milling speed (300, 500 and 700 rpm) and time (1, 2, and 3 h) were varied. For (Fe, $TiH_2$, Carbon) powders, an in situ reaction synthesis of TiC after the planetary ball mill processing was added to obtain a homogeneous distribution of ultrafine TiC particulates in Fe matrix. Powder characteristics such as particle size, size distribution, shape, and mixing homogeneity were investigated.

• 한국자기학회지
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• 제1권2호
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• pp.55-59
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• 1991

희토류-3d 천이원소인 비정질${[{(Fe_{80}CO_{20})}_{0.98}RE_{0.02}]}_{80}B_{20}(RE=Nd,\;Sm,\;Gd,\;Tb)$ 합금 리본시료에 대한 자기적 성질을 조사하기 위하여 시료진동형 자력계(vibrating sample magnetometor)를 이용하여 77 K부터 900 K까지의 온도 영역에서 포화자화 값을 온도의 함수로 측정 한후, Curie 온도 ($T_{c}$)와 Bloch 상수등을 추정하였다. 이들로 부터 spin wave stiffness 상수, 교환상호작용(exchange interaction)의 범위와 평균자승거리($$)등을 계산하였으며 각 희토류 원소에 대한 치환효과를 비교 분석하였다.

• 한국자기학회지
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• 제7권3호
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• pp.134-139
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• 1997

비정질 $Co_{66}$Fe$_{4}$NiB$_{14}$Si$_{15}$에서 리본의 종방향에 대하여 여러 가지 각도를 갖는 시편을 식각법으로 제작하여 100 kHz의 교류전류에서 4 단자법으로 MI 신호를 측정하였다. H=0 근처에서 30 .deg. 시편부터 dip이 나타났으며, 그 크기는 각도에 따라 단조증가하였다. 자기장 크기에 따라 Mi 신호는 증가하였고, 일정한 자기장에서 식각각도에 따라 MI 신호는 증가하다가 90 .deg. 시편에서 감소하였다.

• Journal of Magnetics
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• 제14권1호
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• pp.11-14
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• 2009

We investigated the I-V curves and differential tunneling conductance of two, CoFeB/MgO/CoFeB-based, magnetic tunnel junctions (MTJs): one with a low tunneling magnetoresistance (TMR; 22%) and the other with a high TMR (352%). This huge TMR difference was achieved by different MgO sputter conditions rather than by different annealing or deposition temperature. In addition to the TMR difference, the junction resistances were much higher in the low-TMR MTJ than in the high-TMR MTJ. The low-TMR MTJ showed a clear parabolic behavior in the dI/dV-V curve. This high resistance and parabolic behavior were well explained by the Simmons' simple barrier model. However, the tunneling properties of the high-TMR MTJ could not be explained by this model. The characteristic tunneling properties of the high-TMR MTJ were a relatively low junction resistance, a linear relation in the I-V curve, and conduction dips in the differential tunneling conductance. We explained these features by applying the coherent tunneling model.