• Title/Summary/Keyword: Fe-Pt

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Synergy Effect of Fe/ZSM-5 and Co-Pt/ZSM-5 for NOx removal (NOx제거를 위한 Fe/ZSM-5와 Co-Pt/ZSM-5의 상승 효과)

  • Kim, Jin-Gul;Yoo, Seung-Joon;Kim, Seong-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.9
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    • pp.2390-2395
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    • 2009
  • In the condition of GHSV=$30000\;hr^{-1}$, $NO_x$ removal yield was higher as mole ratio of $SiO_2/Al_2O_3$ for Fe/ZSM-5 was lower regardless of preparation method such as CVD (chemical vapor deposition) and dry impregnation. In addition to this, Fe/ZSM-5 catalyst showed about 50% $NO_x$ removal yield between $350^{\circ}C$ - $400^{\circ}C$ while CO formed significantly. To remove newly formed CO over Fe/ZSM-5, Co-Pt/ZSM-5 was used in conjunction with Fe/ZSM-5 in the series and this demonstrated over 90% removal yield of both NOx and CO at $250^{\circ}C$ and GHSV=$30000\;hr^{-1}$.

Memory Characteristics of High Density Self-assembled FePt Nano-dots Floating Gate with High-k $Al_2O_3$ Blocking Oxide

  • Lee, Gae-Hun;Lee, Jung-Min;Yang, Hyung-Jun;Kim, Kyoung-Rok;Song, Yun-Heub
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.388-388
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    • 2012
  • In this letter, We have investigated cell characteristics of the alloy FePt-NDs charge trapping memory capacitors with high-k $Al_2O_3$ dielectrics as a blocking oxide. The capacitance versus voltage (C-V) curves obtained from a representative MOS capacitor embedded with FePt-NDs synthesized by the post deposition annealing (PDA) treatment process exhibit the window of flat-band voltage shift, which indicates the presence of charge storages in the FePt-NDs. It is shown that NDs memory with high-k $Al_2O_3$ as a blocking oxide has performance in large memory window and low leakage current when the diameter of ND is below 2 nm. Moreover, high-k $Al_2O_3$ as a blocking oxide increases the electric field across the tunnel oxide, while reducing the electric field across the blocking layer. From this result, this device can achieve lower P/E voltage and lower leakage current. As a result, a FePt-NDs device with high-k $Al_2O_3$ as a blocking oxide obtained a~7V reduction in the programming voltages with 7.8 V memory.

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Crystallization of FePt/MgO(100) magnetic thin films (FePt/MgO(100) 자성박막의 결정화 연구)

  • Jeung, Ji-Wook;Cho, Tae-Sik;Yi, Min-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.278-279
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    • 2005
  • The crystallization of FePt/MgO(100) magnetic thin films of various thicknesses has been studied using synchrotron x-ray scattering, atomic force microscope, and vibrating sample magnetometer. In film with a 500-${\AA}$-thick, ordered (fct) FePt phase was dominantly crystallized into perpendicular (001) grains keeping the magnetically easy c-axis normal to the film plane during annealing. In film with a 812-${\AA}$-thick, however, longitudinal (110) grains keeping the c-axis parallel to the film plane were grown on top of the perpendicular (001) grains. The behavior of the magnetic properties was consistent with the thickness dependence of the crystallization. We attribute the thickness dependence of the crystallization to the substrate effect, which prefers the growth of the c-axis oriented perpendicular grains near the film/substrate interfacial area.

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Synthesis and Characteristics of FePt Nanopowder by Chemical Vapor Condensation Process

  • Yu, Ji-Hun;Lee, Dong-Won;Kim, Byoung-Kee;Jang, Tae-Suk
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1196-1197
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    • 2006
  • FePt binary-alloy nanopowder has been successfully synthesized by chemical vapor condensation process with two metal organic precursors, i.e., iron pentacarbonyl and platinum acetylacetonate. Average particle size of the powder was less than 50 nm with very narrow size distribution, revealing high dispersion capability. Characteristics of the powder could be controlled by changing process parameters such as reaction temperature, chamber pressure, as well as gas flow rate. Magnetic properties of the synthesized FePt nanopowder were investigated and analyzed in terms of the powder characteristics.

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Preperation of catalyst having high activity on oxygen reduction (저온형 연료전지용 산소의 고활성 환원 촉매 제조)

  • 김영우;김형진;이주성
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1992.11a
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    • pp.39-40
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    • 1992
  • This paper dealt with the manufacturing of binary alloy catalyst and showed simple electrochemical method for determing catalytic activity of oxygen reduction in acid or alkaline electrolyte. The catalyst was prepared by impregnating transition metal salts on platinum or silver particles adsorbed before on carbon paper substrate. The electrochemical characteristics of the catalysts was investigated with carbon paper electrode or PTFE-boned porous electrode and then cathodic current densities and tafel slopes were compared. As a result, of all binary catalysts utilized in this work, Pt-Fe, Pt-Mo showed better oxygen reduction activity than pure platinum catalyst in acid electrolyte and Ag-Fe, Ag-Pt, and Ag-Ni-Bi-Ti catalyst did than pure silver catalyst in alkaline electrolyte. The current density of Pt-Fe electrode in acid electrolyte was one and half times higher than that of Pt electrode(~500mA/$\textrm{cm}^2$ at 0.7VvsNHE).

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