• 제목/요약/키워드: Fe-Pt

검색결과 440건 처리시간 0.03초

폴리피롤에 빛을 쪼일 때 증가되는 전류의 특성 (Characteristics of Enhanced Current by Polypyrrole under Illumination)

  • 채원석;장예석;이범규;김강진
    • 대한화학회지
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    • 제39권4호
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    • pp.294-300
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    • 1995
  • 빛에 대한 폴리피롤(PPy)의 광전기화학적인 거동을 $Fe(CN)_6^{4-}/Fe(CN)_6^{3-}$$I^-/I_2$를 산화환원종으로 수용액에서 관찰하였다. PPy은 정전압법으로 Pt와 glassy-C 그리고 ITO에 각각 중합하였으며 PPy막을 입힌 전극에 빛이 쪼여졌을 때 산화환원종의 산화환원 전위에서 전류의 증가를 얻었다. 증가된 전류는 PPy이 갖는 반도체 특성과 빛에 의한 전극표면에서의 산화환원 광열촉진에 기인하며, PPy 중합시 사용한 지지전해질의 음이온(dopants)과 산화환원종, 용액의 pH에 의존하였다.

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Exchange Coupling in FePt-FePt3 Nanocomposite Films

  • Lin, K.W.;Guo, J.Y.;Liu, C.Y.;Ouyang, H.;Lierop, J. Van;Phuoc, N.N.;Suzuki, T.
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2007년도 The 1st International Symposium on Advanced Magnetic Materials
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    • pp.155.2-155.2
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    • 2007
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X-RAY DIFFUSE SCATTERINGS IN A Fe-Pt INVAR ALLOY

  • Ono, F.;Maeta, H.;Bang, L.
    • 한국자기학회지
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    • 제5권5호
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    • pp.354-357
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    • 1995
  • Measurements of X-ray diffuse scatterings were made in disordered single crystal of Fe-28.3 at%Pt Invar alloy around a 200-Bragg peak in a wide temperature range between 15 K and 300 K. Observed diffuse scatterings were almost spherical, suggesting a homogeneous disordered alloy. However, the qdependence of the observed thermal diffuse scattering was different from the usual type, indicating a possibility of existence of local distortion of lattice accompanied by a large gradient of stress.

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Reactivity of [Pt(dppf)Cl2] toward Simple Organic Thiolates: Preparation and Structure of [Pt(dppf)(SPh)2], [Pt(dppf)(S-n-Pr)2], and [Pt(dppf)(SCH2CH2CH2S)] (dppf = Fe(η5-C5H4PPh2)2)

  • Han, Won-Seok;Kim, Yong-Joo;Lee, Soon W.
    • Bulletin of the Korean Chemical Society
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    • 제24권1호
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    • pp.60-64
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    • 2003
  • The reactions of $[Pt(dppf)Cl_2]$ with thiophenol (PhSH), 1-propanethiol (n-PrSH), and 1,3-propanedithiol $(HSCH_2CH_2CH_2SH)$ gave the corresponding Pt-dppf-di(thiolato) compounds, $[Pt(dppf)(SPh)_2]\;(1),\;[Pt(dppf)(S-n-Pr)_2]\;(2),\;and [Pt(dppf)(SCH_2CH_2CH_2S)]\;(3)$, respectively. All products are monomeric and 4-coordinate square-planar compounds and were structurally characterized by X-ray diffraction. Electrochemical measurements (cyclovoltammograms) revealed that the oxidation potential of the dppf ligand appears to depend on the type of the group on the thiolato ligand.

The Doping and Plasma Effects on Gas Sensing Properties of α-Fe2O3 Thin Film

  • Choi, J.Y.;Jang, G.E.
    • Transactions on Electrical and Electronic Materials
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    • 제5권5호
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    • pp.189-193
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    • 2004
  • Pure and Sn or Pt doped $\alpha-Fe_2O_3$ thin films were prepared on $Al_2O_3$ substrates by RF-magnetron sputtering method and the sensitivities were compared. It was found that pure $\alpha-Fe_2O_3$ thin films did not exhibit much selectivity in CO and $i-C_4H_{10}$ gases while it showed the high sensitivity in proportion to the gas concentration of $C_2H_{5}OH$ gas. Pt-doped $\alpha-Fe_2O_3$ showed to be alike sensing properties as pure $\alpha-Fe_2O_3$ thin film in $C_2H_{5}OH$ gas. However, Sn-doped $\alpha-Fe_2O_3$ thin films exhibited the excellent sensitivity and selectivity in Hz gas. After microstructure modification by plasma etching on pure $\alpha-Fe_2O_3$ thin films, the gas sensing characteristics were dramatically changed.

염료감응형 태양전지용 나노두께 Pt와 Ru 상대전극의 물성 (Property of Counter Electrode with Pt and Ru Catalyst Films for Dye-Sensitized Solar Cell)

  • 노윤영;유병관;유기천;고민재;송오성
    • 대한금속재료학회지
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    • 제50권3호
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    • pp.243-247
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    • 2012
  • A ruthenium (Ru) catalytic layer and a conventional Pt layer were assessed as counter electrodes (CE) for dye sensitized solar cells (DSSCs). Ru films with different thicknesses of 34, 46, and 90 nm were deposited by atomic layer deposition (ALD). Pt layers with the same thicknesses were prepared by sputtering. $0.45cm^2$ DSSCs were prepared and their properties were characterized by FE-SEM, cyclic voltammetry (CV), impedance spectroscopy (EIS), and current-voltage (I-V). FE-SEM revealed that the crystallized Ru films and Pt films had been deposited quite conformally. CV showed that the catalytic activity of Pt was much greater than that of Ru. In addition, although the catalytic activity of Pt did not depend on the thickness, that of Ru showed an increase with increasing thickness. Impedance analysis revealed high charge transfer resistance at the Ru interface and a decrease with increasing Ru thickness, whereas Pt showed low resistance with no thickness dependence. Despite the relatively small catalytic activity of Ru, the I-V result revealed the average energy conversion efficiency of Ru and Pt to be 2.98% and 6.57%, respectively. These results suggest that Ru can be used as counter electrodes in DSSCs due to its extremely low temperature process compatibility.

펄스레이져 증착법을 이용한 자기커패시터용 Pt/CoNiFe/$BaTiO_3$/CoNiFe 박막 제조 및 전.자기 특성 연구

  • 나여진;윤성욱;김철성;심인보
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.240.1-240.1
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    • 2011
  • 본 연구에서는 펄스레이져 박막 증착법(Pulsed Laser Deposition;PLD)을 이용하여 연자성의 CoNiFe (CNF) 물질과 강유전 특성의$BaTiO_3$ (BTO) 물질을 다층박막 구조로 제작하여 약자장(H=200 Oe)에 의해 에너지를 집적 시키거나 유전상수를 조절하여 박막의 구조 변화에 따른 커패시턴스 변화를 연구하였다. 다양한 구조의 다층 박막은 Si/$SiO_2$/Ti/Pt(111) 기판상에 PLD을 이용하여 증착하였으며, Phillp's X-선 회절기 (XRD)를 이용하여 결정구조와 격자 상수를 결정하였다. FE-SEM, TEM, AFM 및 EDS를 이용하여 박막 표면/단면의 미세구조 및 물질에 따른 조성비를 확인하였다. 자기적 특성을 위해Vibrating Sample Magnetometer (VSM)를 측정하였고, 전기적 특성은 LCR meter를 이용하여 측정하였다.

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