• Title/Summary/Keyword: Fe-Ni steel

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Fabrication of Graded-Boundary Ni/steel Material by Electron Beam (전자빔에 의한 조성구배계면 Ni/Steel 합금재료의 개발)

  • 김병철;김도훈
    • Laser Solutions
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    • v.2 no.2
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    • pp.27-33
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    • 1999
  • Electron beam was applied on the low carbon steel in order to fabricate Metal/Metal GBM(Graded Boundary Material). Ni sheet was placed on the steel substrate. The electron beam was irradiated on the surface and produced a homogeous alloyed layer. Sequential repetition of electron beam treatments for 4 times resulted in 8mm thick graded layer. To determine each layers property, optical microscopy, XRD, microhardness tester and EDS were used. The residual stress was measured by the low angle x-ray diffraction method. The graded boundary layer was stepwise profile, but Ni content incresed up to 80 wt% and Fe content decreased 20 wt% near surface. Each layers microstructure and hardness varied by different Fe/Ni composition. The compressive residual stress was induced by martensite transformation in the 1st and End layers and the shrinkage cracks were formed in graded layer by rapid cooling.

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High Temperature SO2-gas Corrosion of Fe-18%Cr-10%Ni Steels for Coal-fired Power Plant (화력발전소용 Fe-18%Cr-10%Ni 강의 고온 SO2 가스 부식)

  • Lee, Dong-Bok
    • Journal of the Korean institute of surface engineering
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    • v.40 no.5
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    • pp.219-224
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    • 2007
  • The corrosion characteristics of Fe-18Cr-10Ni steels were studied between $600^{\circ}C$ and $1000^{\circ}C$ in Ar+(0.2, 1)%$SG_2$ gas for up to 300 hr in order to employ Fe-18Cr-10Ni steels in the coal-fired power plants. The corrosion resistance of Fe-18Cr-10Ni steels was good due mainly to the high amount of Cr, which formed $Cr_2O_3$ from the initial corrosion stage. Fe in the steels corroded to mainly $Fe_2O_3$ and $Fe_3O_4$. Ni was not susceptible to corrosion under the current corrosion condition. Relatively thin, single-layered scales formed.

Fabrication and characterization of fe-Ni Invar alloy thin films (Fe-Ni Invar 합금 박막의 증착 및 박막 특성 평가)

  • 김상섭;고영호;최장현;김병일;박용범
    • Journal of the Korean Vacuum Society
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    • v.8 no.2
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    • pp.116-120
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    • 1999
  • Fe-Ni alloy thin films with about 3.5 $\mu\textrm{m}$ thickness were successfully grown on Al-killed steel substrates employing DC magnetron sputtering method, and then the4 film properties were characterized. The deposited film exhibited a fibre texture structure with the relationship of ${110}_\textrm{film}//{111}_\textrm{substrate}$. We found that the adhesion between the film and the substrate was fairly good considering no debonding behavior after the thermal cyclic test of 5,000 times from room temperature to $200^{\circ}C$. Also we found that the Fe-Ni alloy deposition induced a significant decrease of thermal expansion in the film processing, a new material system with much lower thermal expansion coefficient which can be applied more as shadow mask materials than an Al-killed steel sheet.

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A Study on Optimization of Alumina and Catalysts Coating on Tube Reactor for Endothermic Reaction of n-Dodecane Under Supercritical Conditions (고온, 고압 조건에서 n-dodecane 액체연료의 흡열분해를 위한 관벽 내 알루미나 및 촉매 코팅 최적화 연구)

  • Kim, Sung Su;Lee, Sang Moon;Lee, Ye Hwan;Lee, Dong Yoon;Gwak, Ji-Yeong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.3
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    • pp.56-61
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    • 2021
  • In this study, Al2O3 and H-ZSM-5 were coated on the inner wall of the stainless steel tube for the stable use of liquid hydrocarbon fuel and an endothermic catalyst used as coolant for hypersonic flying vehicles. Coke production is inevitable by the endothermic decomposition reaction of the liquid hydrocarbon fuel, and Fe, Ni metals induce the production of the filamentous coke by using a stainless steel tube reactor as a cooling channel. By coating the stainless steel with H-ZSM-5, Fe and Ni metals are prevented from being directly exposed to the liquid hydrocarbon fuel, and the formation of the filamentous coke is inhibited. In addition, Al2O3 is coated between the stainless steel and H-ZSM-5 to enhance adhesion bond strength.

Atmospheric Corrosion Process for Weathering Steel

  • Nagano, Hiroo;Yamashita, Masato
    • Corrosion Science and Technology
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    • v.7 no.2
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    • pp.119-124
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    • 2008
  • Steel is generally not corrosion resistant to water with formation of non protective rusts on its surface. Rusts are composed of iron oxides such as $Fe_3O_4$, $\alpha-$, $\beta-$, $\gamma-$and ${\delta}-FeOOH$. However, steel, particularly weathering steel containing small amounts of Cu, Ni and Cr etc., shows good corrosion resistance against rural, industrial or marine environment. Its corrosion rate is exceedingly small as compared with that of carbon steel. According to the exposure test results undertaken in outdoor environments, the atmospheric corrosion rate for weathering steel is only 1 mm for a century. Atmospheric corrosion for steels proceeds under alternate dry and wet conditions. Dry condition is encountered on steel surface on fine or cloudy days, and wet condition is on rainy or snowy days. The reason why weathering steel shows superior atmospheric corrosion resistance is due to formation of corrosion protective rusts on its surface under very thin water layer. The protective rusts are usually composed of two layer rusts; the upper layer is ${\gamma}-FeOOH$ termed as lepidocrocite, and inner layer is nano-particle ${\alpha}-FeOOH$ termed as goethite. This paper is aimed at elucidating the atmospheric corrosion mechanism for steel in comparison with corrosion in bulky water environment by use of empirical data.The summary is as follows: 1. No corrosion protective rusts are formed on steel in bulky water. 2. Atmospheric corrosion for steel is the corrosion under wetting and drying conditions. Corrosion and passivation occur alternately on steel surface. Steel, particularly weathering steel with small amounts of alloying elements such as Cu, Ni and Cr etc. enhances forming corrosion protective rusts by passivation.